Nickel(II) pincer complexes demonstrate that the remote substituent controls catalytic carbon dioxide reduction: Difference between revisions

From ChemWiki
publication
About
DOI 10.1039/c7cc09507d
Authors Dalton B. Burks, Shakeyia Davis, Robert W. Lamb, Xuan Liu, Roberta R. Rodrigues, Nalaka P. Liyanage, Yujie Sun, Charles Edwin Webster, Jared H. Delcamp, Elizabeth T. Papish,
Submitted 13.03.2018
Published online 2018
Licenses http://rsc.li/journals-terms-of-use#chorus,
Subjects Materials Chemistry, Metals and Alloys, Surfaces, Coatings and Films, General Chemistry, Ceramics and Composites, Electronic, Optical and Magnetic Materials, Catalysis
Go to literature page
No edit summary
No edit summary
Line 4: Line 4:
===Catalyst===
===Catalyst===
{{#moleculelink:|link=UDPGSTPOVCEDJN-UHFFFAOYSA-L|image=true}}
{{#moleculelink:|link=UDPGSTPOVCEDJN-UHFFFAOYSA-L|image=true}}
<chemform smiles="C1C2N3C=CN(C)C3[Ni](N#CC)3C4N(C(N=23)=CC=1)C=CN4C" inchi="1S/C13H17N5.C2H3N.Ni/c1-15-6-8-17(10-15)12-4-3-5-13(14-12)18-9-7-16(2)11-18;1-2-3;/h3-9H,10-11H2,1-2H3;1H3;" inchikey="WWQONKLZHTWXPP-UHFFFAOYSA-N" height="200px" width="300px" float="none">
<chemform smiles="C1C2N3C=CN(C)C3[Ni+2](N#CC)3C4N(C(N=23)=CC=1)C=CN4C.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F" inchi="1S/C13H17N5.C2H3N.2F6P.Ni/c1-15-6-8-17(10-15)12-4-3-5-13(14-12)18-9-7-16(2)11-18;1-2-3;2*1-7(2,3,4,5)6;/h3-9H,10-11H2,1-2H3;1H3;;;/q;;2*-1;+2" inchikey="XLAXHWSGDXWDSW-UHFFFAOYSA-N" height="200px" width="300px" float="none">
   -INDIGO-01272314332D
   -INDIGO-11282314472D


   0  0  0  0  0  0  0  0  0  0  0 V3000
   0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 BEGIN CTAB
M  V30 COUNTS 22 26 0 0 0
M  V30 COUNTS 36 38 0 0 0
M  V30 BEGIN ATOM
M  V30 BEGIN ATOM
M  V30 1 C 6.95985 -3.47507 0.0 0
M  V30 1 C 6.95985 -3.47507 0.0 0
Line 29: Line 29:
M  V30 17 C 5.13549 -7.55911 0.0 0
M  V30 17 C 5.13549 -7.55911 0.0 0
M  V30 18 C 10.5145 -7.58411 0.0 0
M  V30 18 C 10.5145 -7.58411 0.0 0
M  V30 19 Ni 7.85 -6.225 0.0 0
M  V30 19 Ni 7.85 -6.225 0.0 0 CHG=2
M  V30 20 N 7.85 -7.225 0.0 0
M  V30 20 N 7.85 -7.75 0.0 0
M  V30 21 C 7.85 -8.225 0.0 0
M  V30 21 C 7.85 -8.75 0.0 0
M  V30 22 C 7.85 -9.225 0.0 0
M  V30 22 C 7.85 -9.75 0.0 0
M  V30 23 F 12.092 -4.675 0.0 0
M  V30 24 P 12.958 -4.175 0.0 0 CHG=-1
M  V30 25 F 13.824 -4.675 0.0 0
M  V30 26 F 12.958 -3.175 0.0 0
M  V30 27 F 12.092 -3.675 0.0 0
M  V30 28 F 13.824 -3.675 0.0 0
M  V30 29 F 12.958 -5.175 0.0 0
M  V30 30 F 12.359 -8.075 0.0 0
M  V30 31 P 13.225 -7.575 0.0 0 CHG=-1
M  V30 32 F 14.091 -8.075 0.0 0
M  V30 33 F 13.225 -6.575 0.0 0
M  V30 34 F 12.359 -7.075 0.0 0
M  V30 35 F 14.091 -7.075 0.0 0
M  V30 36 F 13.225 -8.575 0.0 0
M  V30 END ATOM
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 BEGIN BOND
Line 61: Line 75:
M  V30 25 3 20 21
M  V30 25 3 20 21
M  V30 26 1 21 22
M  V30 26 1 21 22
M  V30 27 1 23 24
M  V30 28 1 24 25
M  V30 29 1 24 26
M  V30 30 1 24 27
M  V30 31 1 24 28
M  V30 32 1 24 29
M  V30 33 1 30 31
M  V30 34 1 31 32
M  V30 35 1 31 33
M  V30 36 1 31 34
M  V30 37 1 31 35
M  V30 38 1 31 36
M  V30 END BOND
M  V30 END BOND
M  V30 END CTAB
M  V30 END CTAB

Revision as of 14:47, 28 November 2023


Catalyst

Ni(4O(-)py)-(MeNHC)2Cl [Ni(py)-(MeNHC)2(MeCN)][PF6]2

Photosensitizer

Ir(ppy)3

Investigation

  1. REDIRECT Photocatalytic CO2 reduction under varied conditions
Investigation-Name: Table 1

Sacrificial electron donor

BIHTEA

Additives

TfOH

Investigations

Retrieved from "https://chemwiki.scc.kit.edu/main/mediawiki/index.php?title=Nickel(II)_pincer_complexes_demonstrate_that_the_remote_substituent_controls_catalytic_carbon_dioxide_reduction&oldid=4566"
Powered by MediaWiki
Powered by Semantic MediaWiki