Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N-Heterocyclic Carbene–Isoquinoline Complex: Difference between revisions

Revision as of 09:41, 7 July 2023

Molecule with key HHVSVDHKXSYIDH-UHFFFAOYSA-N does not exist.

Molecule with key UEEXRMUCXBPYOV-UHFFFAOYSA-N does not exist.

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	λexc [nm]	TON CO
1.	[Ni(bimiqpr)][PF6]2	0.000002	Ir(ppy)3	0.2	TEA	0.07	MeCN	solar spectrum	98000
2.	[Ni(bimiqpr)][PF6]2	0.00002	Ir(ppy)3	0.2	TEA	0.07	MeCN	solar spectrum	9000
3.	[Ni(bimiqpr)][PF6]2	0.0002	Ir(ppy)3	0.2	TEA	0.07	MeCN	solar spectrum	1500

Investigation-Name: Table 1

DOI	10.1021/ja4074003
Authors	V. Sara Thoi, Nikolay Kornienko, Charles G. Margarit, Peidong Yang, Christopher J. Chang,
Submitted	13.09.2013
Published online	13.09.2013
Licenses	-
Subjects	Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
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@@ Line 2: / Line 2: @@
 {{#doiinfobox: 10.1021/ja4074003}}
-==== Investigation ====
+==== Catalyst====
-{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}}
+{{#moleculelink:|link=HHVSVDHKXSYIDH-UHFFFAOYSA-N|image=true}}
-[[Category:Photocatalytic CO2 conversion to CO]]
-==== Catalyst ====
+====Photosensitizer====
-<chemform smiles="" inchi="" inchikey="HHVSVDHKXSYIDH-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform>
+{{#moleculelink:|link=UEEXRMUCXBPYOV-UHFFFAOYSA-N|image=true}}
-==== Photosensitizer ====
+====Investigation====
-<chemform smiles="" inchi="" inchikey="UEEXRMUCXBPYOV-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform>
+{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}}
-==== Sacrificial electron donor ====
+====Sacrificial electron donor====
-<chemform smiles="" inchi="" inchikey="ZMANZCXQSJIPKH-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform>
+{{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=true}}
+[[Category:Photocatalytic CO2 conversion to CO]]