Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N-Heterocyclic Carbene–Isoquinoline Complex: Difference between revisions
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{{#doiinfobox: 10.1021/ja4074003}} | {{#doiinfobox: 10.1021/ja4074003}} | ||
=== Investigation === | ==== Investigation ==== | ||
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}} | {{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}} | ||
[[Category:Photocatalytic CO2 conversion to CO]] | [[Category:Photocatalytic CO2 conversion to CO]] | ||
==== Catalyst ==== | ==== Catalyst ==== | ||
<chemform smiles="" inchi="" inchikey="HHVSVDHKXSYIDH-UHFFFAOYSA-N " height="200px" width="300px" float="none"></chemform> | <chemform smiles="" inchi="" inchikey="HHVSVDHKXSYIDH-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform> | ||
==== Photosensitizer ==== | ==== Photosensitizer ==== | ||
==== <chemform smiles="" inchi="" inchikey="UEEXRMUCXBPYOV-UHFFFAOYSA-N " height="200px" width="300px" float="none"></chemform> ==== | ==== <chemform smiles="" inchi="" inchikey="UEEXRMUCXBPYOV-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform> ==== | ||
Revision as of 14:40, 2 February 2023
Investigation
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | solvent A | λexc [nm] | . | TON CO | . | . | . | . | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1. | 0.002 | 0.2 | 0.07 | solar spectrum | 98000 | |||||||||
| 2. | 0.02 | 0.2 | 0.07 | solar spectrum | 9000 | |||||||||
| 3. | 0.2 | 0.2 | 0.07 | solar spectrum | 1500 |
Investigation-Name: Table 1
Catalyst
Photosensitizer
Investigations
- Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)
