Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N-Heterocyclic Carbene–Isoquinoline Complex: Difference between revisions

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DOI 10.1021/ja4074003
Authors V. Sara Thoi, Nikolay Kornienko, Charles G. Margarit, Peidong Yang, Christopher J. Chang,
Submitted 13.09.2013
Published online 13.09.2013
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Subjects Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
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(Added molecules)
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{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}}
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}}
[[Category:Photocatalytic CO2 conversion to CO]]
[[Category:Photocatalytic CO2 conversion to CO]]
==== Catalyst ====
<chemform smiles="" inchi="" inchikey="HHVSVDHKXSYIDH-UHFFFAOYSA-N " height="200px" width="300px" float="none"></chemform>
==== Photosensitizer ====
==== <chemform smiles="" inchi="" inchikey="UEEXRMUCXBPYOV-UHFFFAOYSA-N " height="200px" width="300px" float="none"></chemform> ====

Revision as of 13:50, 2 February 2023


Investigation

catcat conc [µM]PSPS conc [mM]e-De-D conc [M]solvent Aλexc [nm].TON CO....
1.

[Ni(bimiqpr)][PF6]2

0.000002

Ir(ppy)3

0.2

TEA

0.07

MeCN

solar spectrum98000
2.

[Ni(bimiqpr)][PF6]2

0.00002

Ir(ppy)3

0.2

TEA

0.07

MeCN

solar spectrum9000
3.

[Ni(bimiqpr)][PF6]2

0.0002

Ir(ppy)3

0.2

TEA

0.07

MeCN

solar spectrum1500
Investigation-Name: Table 1

Catalyst

Photosensitizer

Investigations

  • Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)