A Cu(I) Co(II) cryptate for the visible light-driven reduction of CO2/Photocatalytic reduction of CO2

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Molecule:100799	0.002	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		4:1			CO2					blue LED (450, 1200 mcd, 0.8 cm^2)	24	2305	1.6	0.15				47	0.032								98.0%; 0%; 2.0%; 0%; 0%	0.15		No
		[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		4:1			CO2					blue LED (450, 1200 mcd, 0.8 cm^2)	24	0	0	0				12.75	0.000885								n/a			No
Molecule:100799	0.002			TEOA	0.3			MeCN	H2O		4:1			CO2					blue LED (450, 1200 mcd, 0.8 cm^2)	24	0	0	0				2.22	0.00154								n/a			No
Molecule:100799	0.002	[Ru(phen)3][PF6]2	0.4					MeCN	H2O		4:1			CO2					blue LED (450, 1200 mcd, 0.8 cm^2)	24	0	0	0				2.05	0.00142								n/a			No
Molecule:100799	0.002	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		4:1			CO2						24	0	0	0				0	0								n/a			No
Molecule:100799	0.002	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		4:1			argon					blue LED (450, 1200 mcd, 0.8 cm^2)	24	0	0	0				0	0								n/a			No
Molecule:100799	0.002	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN						CO2					blue LED (450, 1200 mcd, 0.8 cm^2)	24	55.25	0.0384	0.004				12.13	0.00844								82.0%; 0%; 18.0%; 0%; 0%	0.004		No
Molecule:100799	0.002	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		9:1			CO2					blue LED (450, 1200 mcd, 0.8 cm^2)	24	1558	1.08	0.10				62.50	0.0434								96.1%; 0%; 3.9%; 0%; 0%	0.1		No
Molecule:100799	0.002	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		1:1			CO2					blue LED (450, 1200 mcd, 0.8 cm^2)	24	19.78	0.0137	0.002				5.55	0.00385								78.1%; 0%; 21.9%; 0%; 0%	0.002		No
Molecule:100799	0.002	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		4:1	100 µL Hg(0)		CO2					blue LED (450, 1200 mcd, 0.8 cm^2)	24	1835	1.27	0.12				53.50	0.0372								97.2%; 0%; 2.8%; 0%; 0%	0.12		No
Molecule:100895	0.002	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		4:1			CO2					blue LED (450, 1200 mcd, 0.8 cm^2)	24	11.60	0.00806	0.001				6.975	0.00484								62.4%; 0%; 37.6%; 0%; 0%	0.001		No
Molecule:100903	0.002	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		4:1			CO2					blue LED (450, 1200 mcd, 0.8 cm^2)	24	1425	0.99	0.09				33.75	0.0234								97.7%; 0%; 2.3%; 0%; 0%	0.09		No
Molecule:100897	0.002	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		4:1			CO2					blue LED (450, 1200 mcd, 0.8 cm^2)	24	695	0.48	0.04				16.78	0.0117								97.6%; 0%; 2.4%; 0%; 0%	0.04		No
Molecule:100799	0.0015	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		4:1			CO2					blue LED (450, 1200 mcd, 0.8 cm^2)	24	1623	1.13	0.08				28.37	0.0197								98.3%; 0%; 1.7%; 0%; 0%	0.08		No
Molecule:100799	0.001	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		4:1			CO2					blue LED (450, 1200 mcd, 0.8 cm^2)	24	1565	1.09	0.05				31.30	0.0217								98.0%; 0%; 2.0%; 0%; 0%	0.05		No
Molecule:100799	0.0005	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		4:1			CO2					blue LED (450, 1200 mcd, 0.8 cm^2)	24	1660	1.15	0.03				42.10	0.0292								97.5%; 0%; 2.5%; 0%; 0%	0.03		No
	0.002	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		4:1			CO2					blue LED (450, 1200 mcd, 0.8 cm^2)	24	2900	2.01	0.19				93.75	0.0651								96.9%; 0%; 3.1%; 0%; 0%	0.19		No
Molecule:100900	0.002	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		4:1			CO2					blue LED (450, 1200 mcd, 0.8 cm^2)	24	1598	1.11	0.10				44.75	0.0311								97.3%; 0%; 2.7%; 0%; 0%	0.1		No
Molecule:100901	0.002	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		4:1			CO2					blue LED (450, 1200 mcd, 0.8 cm^2)	24	1553	1.08	0.10				40	0.0278								97.5%; 0%; 2.5%; 0%; 0%	0.1		No