Nickel(II) pincer complexes demonstrate that the remote substituent controls catalytic carbon dioxide reduction: Difference between revisions
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{{#doiinfobox: 10.1039/c7cc09507d}} | {{#doiinfobox: 10.1039/c7cc09507d}} | ||
===Abstract=== | |||
====Summary==== | |||
A photochemical reduction of CO<sub>2</sub> to xx was shown using the nickel complexes or as catalysts in combination with the iridium-based photosensitizer {{#moleculelink:|link=NSABRUJKERBGOU-UHFFFAOYSA-N|image=false|width=300|height=200}}. Turnover numbers (TONs) of xx for xx with the cobalt complex xx were reached in xx. The experiments were conducted under visible-light irradiation (λ > xx nm) using xx as sacrificial electron donor (see section SEDs below). | |||
====Advances and special progress==== | |||
====Additional remarks==== | |||
===Content of the published article in detail=== | |||
The article contains results for the reduction of CO<sub>2</sub> to xx under visible-light catalysis using nickel complexes as catalysts. The catalytic system performs best (referring to the TON of CO production) in xx with the cobalt catalyst xx. | |||
===Catalyst=== | ===Catalyst=== | ||
{{#moleculelink:|link=UDPGSTPOVCEDJN-UHFFFAOYSA-L|image=true}} | {{#moleculelink:|link=UDPGSTPOVCEDJN-UHFFFAOYSA-L|image=true}} | ||
| Line 97: | Line 104: | ||
===Investigation === | ===Investigation === | ||
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}} | {{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}} | ||
====Sacrificial Electron Donor==== | |||
===Sacrificial | In this study, the experiments were done with the sacrificial electron donors BIH ({{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=false|width=300|height=200}}) and TEA ({{#moleculelink: |link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=false|width=300|height=200}}). | ||
{{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image= | ====Additives==== | ||
In this study, {{#moleculelink:|link=ITMCEJHCFYSIIV-UHFFFAOYSA-N|image=false|width=300|height=200}} was used as an additive. | |||
===Additives=== | |||
[[Category:Photocatalytic CO2 conversion to CO]] | [[Category:Photocatalytic CO2 conversion to CO]] | ||
Revision as of 14:44, 22 January 2024
Abstract
Summary
A photochemical reduction of CO2 to xx was shown using the nickel complexes or as catalysts in combination with the iridium-based photosensitizer Ir(ppy)3. Turnover numbers (TONs) of xx for xx with the cobalt complex xx were reached in xx. The experiments were conducted under visible-light irradiation (λ > xx nm) using xx as sacrificial electron donor (see section SEDs below).
Advances and special progress
Additional remarks
Content of the published article in detail
The article contains results for the reduction of CO2 to xx under visible-light catalysis using nickel complexes as catalysts. The catalytic system performs best (referring to the TON of CO production) in xx with the cobalt catalyst xx.
Catalyst
Ni(4O(-)py)-(MeNHC)2Cl
[Ni(py)-(MeNHC)2(MeCN)][PF6]2
Photosensitizer
Investigation
Investigation-Name: Table 1
Sacrificial Electron Donor
In this study, the experiments were done with the sacrificial electron donors BIH (BIH) and TEA (TEA).
Additives
In this study, TfOH was used as an additive.
Investigations
- Photocatalytic CO2 reduction under varied conditions (Molecular process, Photocatalytic CO2 conversion experiments)
