Nickel(II) pincer complexes demonstrate that the remote substituent controls catalytic carbon dioxide reduction: Difference between revisions

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DOI 10.1039/c7cc09507d
Authors Dalton B. Burks, Shakeyia Davis, Robert W. Lamb, Xuan Liu, Roberta R. Rodrigues, Nalaka P. Liyanage, Yujie Sun, Charles Edwin Webster, Jared H. Delcamp, Elizabeth T. Papish,
Submitted 13.03.2018
Published online 2018
Licenses http://rsc.li/journals-terms-of-use#chorus,
Subjects Materials Chemistry, Metals and Alloys, Surfaces, Coatings and Films, General Chemistry, Ceramics and Composites, Electronic, Optical and Magnetic Materials, Catalysis
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===Catalyst===
===Catalyst===
{{#moleculelink:|link=QFRHHPFUSKJYCI-UHFFFAOYSA-L|image=true}}
{{#moleculelink:|link=UDPGSTPOVCEDJN-UHFFFAOYSA-L|image=true}}
<chemform smiles="C1C2N3C=CN(C)C3[Ni](N#CC)3C4N(C(N=23)=CC=1)C=CN4C" inchi="1S/C13H17N5.C2H3N.Ni/c1-15-6-8-17(10-15)12-4-3-5-13(14-12)18-9-7-16(2)11-18;1-2-3;/h3-9H,10-11H2,1-2H3;1H3;" inchikey="WWQONKLZHTWXPP-UHFFFAOYSA-N" height="200px" width="300px" float="none">
<chemform smiles="C1C2N3C=CN(C)C3[Ni](N#CC)3C4N(C(N=23)=CC=1)C=CN4C" inchi="1S/C13H17N5.C2H3N.Ni/c1-15-6-8-17(10-15)12-4-3-5-13(14-12)18-9-7-16(2)11-18;1-2-3;/h3-9H,10-11H2,1-2H3;1H3;" inchikey="WWQONKLZHTWXPP-UHFFFAOYSA-N" height="200px" width="300px" float="none">
   -INDIGO-01272314332D
   -INDIGO-01272314332D

Revision as of 11:37, 28 November 2023


Catalyst

Ni(4O(-)py)-(MeNHC)2Cl

Photosensitizer

Ir(ppy)3

Investigation

Investigation-Name: Table 1

Sacrificial electron donor

BIHTEA

Additives

TfOH

Investigations