Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N-Heterocyclic Carbene–Isoquinoline Complex: Difference between revisions
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==== Photosensitizer ==== | ==== Photosensitizer ==== | ||
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==== <chemform smiles="" inchi="" inchikey=" | ==== Sacrificial electron donor ==== | ||
<chemform smiles="" inchi="" inchikey="ZMANZCXQSJIPKH-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform> | |||
Revision as of 10:30, 3 May 2023
Investigation
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | solvent A | λexc [nm] | . | TON CO | . | . | . | . | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1. | 0.000002 | 0.2 | 0.07 | solar spectrum | 98000 | |||||||||
| 2. | 0.00002 | 0.2 | 0.07 | solar spectrum | 9000 | |||||||||
| 3. | 0.0002 | 0.2 | 0.07 | solar spectrum | 1500 |
Investigation-Name: Table 1
Catalyst
Photosensitizer
Sacrificial electron donor
Investigations
- Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)
