Exploring the Full Potential of Photocatalytic Carbon Dioxide Reduction Using a Dinuclear Re2Cl2 Complex Assisted by Various Photosensitizers/Optimizations of the conditions: Difference between revisions
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< Exploring the Full Potential of Photocatalytic Carbon Dioxide Reduction Using a Dinuclear Re2Cl2 Complex Assisted by Various Photosensitizers
investigation
Molecular process, Photocatalytic CO2 conversion experimentsNo edit summary |
No edit summary |
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|catalyst=Molecule:100620 | |catalyst=Molecule:100620 | ||
|cat conc=0.05 | |cat conc=0.05 | ||
|PS=Molecule: | |PS=Molecule:100802 | ||
|PS conc=0.05 | |PS conc=0.05 | ||
|e-D=Molecule:100505 | |e-D=Molecule:100505 | ||
Line 15: | Line 15: | ||
|catalyst=Molecule:100620 | |catalyst=Molecule:100620 | ||
|cat conc=0.05 | |cat conc=0.05 | ||
|PS=Molecule: | |PS=Molecule:100802 | ||
|PS conc=0.05 | |PS conc=0.05 | ||
|e-D=Molecule:100508 | |e-D=Molecule:100508 | ||
Line 29: | Line 29: | ||
|catalyst=Molecule:100620 | |catalyst=Molecule:100620 | ||
|cat conc=0.05 | |cat conc=0.05 | ||
|PS=Molecule: | |PS=Molecule:100802 | ||
|PS conc=0.05 | |PS conc=0.05 | ||
|e-D=Molecule:100508 | |e-D=Molecule:100508 | ||
Line 43: | Line 43: | ||
|catalyst=Molecule:100620 | |catalyst=Molecule:100620 | ||
|cat conc=0.05 | |cat conc=0.05 | ||
|PS=Molecule: | |PS=Molecule:100802 | ||
|PS conc=0.05 | |PS conc=0.05 | ||
|e-D=Molecule:100508 | |e-D=Molecule:100508 | ||
Line 57: | Line 57: | ||
|catalyst=Molecule:100620 | |catalyst=Molecule:100620 | ||
|cat conc=0.05 | |cat conc=0.05 | ||
|PS=Molecule: | |PS=Molecule:100802 | ||
|PS conc=0.05 | |PS conc=0.05 | ||
|e-D=Molecule:100508 | |e-D=Molecule:100508 | ||
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|catalyst=Molecule:100620 | |catalyst=Molecule:100620 | ||
|cat conc=0.05 | |cat conc=0.05 | ||
|PS=Molecule: | |PS=Molecule:100802 | ||
|PS conc=0.05 | |PS conc=0.05 | ||
|e-D=Molecule:100508 | |e-D=Molecule:100508 | ||
Line 85: | Line 85: | ||
|catalyst=Molecule:100620 | |catalyst=Molecule:100620 | ||
|cat conc=0.05 | |cat conc=0.05 | ||
|PS=Molecule: | |PS=Molecule:100802 | ||
|PS conc=0.05 | |PS conc=0.05 | ||
|e-D=Molecule:100508 | |e-D=Molecule:100508 | ||
Line 99: | Line 99: | ||
|catalyst=Molecule:100620 | |catalyst=Molecule:100620 | ||
|cat conc=0.05 | |cat conc=0.05 | ||
|PS=Molecule: | |PS=Molecule:100802 | ||
|PS conc=0.05 | |PS conc=0.05 | ||
|e-D=Molecule:100508 | |e-D=Molecule:100508 | ||
Line 125: | Line 125: | ||
|catalyst=Molecule:100620 | |catalyst=Molecule:100620 | ||
|cat conc=0.05 | |cat conc=0.05 | ||
|PS=Molecule: | |PS=Molecule:100802 | ||
|PS conc=0.005 | |PS conc=0.005 | ||
|e-D=Molecule:100508 | |e-D=Molecule:100508 | ||
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|catalyst=Molecule:100620 | |catalyst=Molecule:100620 | ||
|cat conc=0.05 | |cat conc=0.05 | ||
|PS=Molecule: | |PS=Molecule:100802 | ||
|PS conc=0.0125 | |PS conc=0.0125 | ||
|e-D=Molecule:100508 | |e-D=Molecule:100508 | ||
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|catalyst=Molecule:100620 | |catalyst=Molecule:100620 | ||
|cat conc=0.05 | |cat conc=0.05 | ||
|PS=Molecule: | |PS=Molecule:100802 | ||
|PS conc=0.025 | |PS conc=0.025 | ||
|e-D=Molecule:100508 | |e-D=Molecule:100508 | ||
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|catalyst=Molecule:100620 | |catalyst=Molecule:100620 | ||
|cat conc=0.05 | |cat conc=0.05 | ||
|PS=Molecule: | |PS=Molecule:100802 | ||
|PS conc=0.1 | |PS conc=0.1 | ||
|e-D=Molecule:100508 | |e-D=Molecule:100508 |
Revision as of 14:54, 27 November 2023
cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
0.05 | 0.05 | 0.36 |
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> 400 | 4 | 52 | n/a |
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Yes | ||||||||||||||||||||||||||||
0.05 | 0.05 | 0.005 |
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TEA | 0.005 | > 400 | 4 | 78 | n/a |
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Yes | ||||||||||||||||||||||||||
0.05 | 0.05 | 0.01 |
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TEA | 0.01 | > 400 | 4 | 195 | n/a |
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Yes | ||||||||||||||||||||||||||
0.05 | 0.05 | 0.01 |
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TEA | 0.01 | > 400 | 4 | 154 | n/a |
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No | ||||||||||||||||||||||||||
0.05 | 0.05 | 0.01 |
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TEA | 0.02 | > 400 | 4 | 131 | n/a |
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Yes | ||||||||||||||||||||||||||
0.05 | 0.05 | 0.02 |
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TEA | 0.01 | > 400 | 4 | 134 | n/a |
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Yes | ||||||||||||||||||||||||||
0.05 | 0.05 | 0.02 |
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TEA | 0.02 | > 400 | 4 | 193 | n/a |
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Yes | ||||||||||||||||||||||||||
0.05 | 0.05 | 0.5 |
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TEA | 0.5 | > 400 | 4 | 255 | n/a |
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Yes | ||||||||||||||||||||||||||
0.05 |
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0.01 |
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TEA | 0.01 | > 400 | 4 | 63 | n/a |
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Yes | ||||||||||||||||||||||||||
0.05 | 0.005 | 0.01 |
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TEA | 0.01 | > 400 | 4 | 124 | n/a |
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Yes | ||||||||||||||||||||||||||
0.05 | 0.0125 | 0.01 |
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TEA | 0.01 | > 400 | 4 | 144 | n/a |
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Yes | ||||||||||||||||||||||||||
0.05 | 0.025 | 0.01 |
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TEA | 0.01 | > 400 | 4 | 149 | n/a |
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Yes | ||||||||||||||||||||||||||
0.05 | 0.1 | 0.05 |
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TEA | 0.005 | > 400 | 4 | 270 | n/a |
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Yes | ||||||||||||||||||||||||||
0.05 | 0.05 | 0.01 |
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TEA | 0.01 | > 400 | 4 | 169 | n/a |
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Yes |