Selective and Efficient Photocatalytic CO2 Reduction to CO Using Visible Light and an Iron-Based Homogeneous Catalyst: Difference between revisions

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DOI 10.1021/ja510290t
Authors Julien Bonin, Marc Robert, Mathilde Routier,
Submitted 14.11.2014
Published online 20.11.2014
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[[Category:Photocatalytic CO2 conversion to CO]][[Category:Publication]]
[[Category:Photocatalytic CO2 conversion to CO]][[Category:Publication]]
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===Abstract===
====Summary====
The photochemical reduction of CO<sub>2</sub> to CO was shown using the iron complex {{#moleculelink:|link=JQYRTQVHCKLBTL-YQGGSDPOSA-M|image=false|width=300|height=200}} in combination with the photosensitizers {{#moleculelink:|link=NSABRUJKERBGOU-UHFFFAOYSA-N|image=false|width=300|height=200}} or {{#moleculelink:|link=KEQZHLAEKAVZLY-UHFFFAOYSA-N|image=false|width=300|height=200}}. Turnover numbers (TONs) of up to 140 and a selectivity of 93% for CO were reached in acetonitrile after 55 h of irradiation. The experiments were conducted under visible-light irradiation (λ > 400 nm) with TEA (see section SEDs below) as sacrificial electron donor.
====Advances and special progress====
The authors reported one of the highest TONs in homogeneous photocatalysis at that time in this study without detecting significant degradation of the catalyst or sensitizer. In addition, they reported the use of a cheap organic photosensitizer for CO<sub>2</sub> conversion with a slightly lower TON (60), but higher selectivity (100%).
====Additional remarks====
===Content of the published article in detail===
The article contains results of a study for the reduction of CO<sub>2</sub> to CO using an iron complex and an iridium-based or organic photosensitizer. The catalytic system performs best (referring to the TON of CO production) in acetonitrile with photosensitizer {{#moleculelink:|link=NSABRUJKERBGOU-UHFFFAOYSA-N|image=false|width=300|height=200}}.
====Catalyst====
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  -INDIGO-05102411192D
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M  V30 19 C 10.1574 -6.01331 0.0 0
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M  V30 49 C 8.14033 -10.6703 0.0 0
M  V30 50 C 7.27029 -9.17468 0.0 0
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M  V30 52 O 9.87309 -8.6716 0.0 0
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M  V30 54 O 4.61474 -3.51989 0.0 0
M  V30 55 O 4.62092 -6.9905 0.0 0
M  V30 56 O 11.6135 -3.40454 0.0 0
M  V30 57 O 11.6196 -6.87514 0.0 0
M  V30 58 Cl 8.025 -6.125 0.0 0
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M  V30 1 2 1 2
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M  V30 3 1 3 4
M  V30 4 2 4 5
M  V30 5 1 1 5
M  V30 6 1 5 11
M  V30 7 2 3 22
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M  V30 END CTAB
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</chemform>
====Photosensitizer====
<chemform smiles="" inchi="" inchikey="NSABRUJKERBGOU-UHFFFAOYSA-N " height="200px" width="300px" float="none"></chemform><chemform smiles="C1C=CC2C=C3C=CC=CC3=C(C#N)C=2C=1" inchi="1S/C15H9N/c16-10-15-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)15/h1-9H" inchikey="KEQZHLAEKAVZLY-UHFFFAOYSA-N" height="200px" width="300px" float="none">
  -INDIGO-05102413272D
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M  V30 4 C 6.11515 -7.00053 0.0 0
M  V30 5 C 4.38485 -7.00502 0.0 0
M  V30 6 C 5.25382 -7.50003 0.0 0
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M  V30 15 C 6.97982 -4.50121 0.0 0
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M  V30 1 2 3 1
M  V30 2 2 4 2
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M  V30 4 1 2 3
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</chemform>
====Investigation====
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=photocatalytic conversion of CO2 to CO|importFile=}}
====Sacrificial electron donor====
In this study, the experiments were done with the sacrificial electron donor TEA ({{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=false|width=300|height=200}}).
====Additives====
In this study, no additives were tested.

Latest revision as of 12:43, 15 May 2024


Abstract[edit | edit source]

Summary[edit | edit source]

The photochemical reduction of CO2 to CO was shown using the iron complex Fe(DHPP)Cl in combination with the photosensitizers Ir(ppy)3 or 9-Anthracenecarbonitrile. Turnover numbers (TONs) of up to 140 and a selectivity of 93% for CO were reached in acetonitrile after 55 h of irradiation. The experiments were conducted under visible-light irradiation (λ > 400 nm) with TEA (see section SEDs below) as sacrificial electron donor.

Advances and special progress[edit | edit source]

The authors reported one of the highest TONs in homogeneous photocatalysis at that time in this study without detecting significant degradation of the catalyst or sensitizer. In addition, they reported the use of a cheap organic photosensitizer for CO2 conversion with a slightly lower TON (60), but higher selectivity (100%).

Additional remarks[edit | edit source]

Content of the published article in detail[edit | edit source]

The article contains results of a study for the reduction of CO2 to CO using an iron complex and an iridium-based or organic photosensitizer. The catalytic system performs best (referring to the TON of CO production) in acetonitrile with photosensitizer Ir(ppy)3.

Catalyst[edit | edit source]

Fe(DHPP)Cl

Photosensitizer[edit | edit source]

Ir(ppy)3 9-Anthracenecarbonitrile

Investigation[edit | edit source]

catcat conc [µM]PSPS conc [mM]e-De-D conc [M]solvent A..TON CO.
1.

Fe(DHPP)Cl

0.002

Ir(ppy)3

0.2

TEA

0.36

MeCN

140
2.

Fe(DHPP)Cl

0.002

Molecule:100936

0.2

TEA

0.36

MeCN

40
3.

Fe(DHPP)Cl

0.002

Molecule:100936

0.2

TEA

0.05

MeCN

60
Investigation-Name: photocatalytic conversion of CO2 to CO

Sacrificial electron donor[edit | edit source]

In this study, the experiments were done with the sacrificial electron donor TEA (TEA).

Additives[edit | edit source]

In this study, no additives were tested.

Investigations

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