Exploring the Full Potential of Photocatalytic Carbon Dioxide Reduction Using a Dinuclear Re2Cl2 Complex Assisted by Various Photosensitizers/Optimizations of the conditions

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
(tBuxant)-(Re(bpy)(CO)3Cl)2	0.05	Ir(fppy)3	0.05	TEA	0.36			DMF											> 400	4	52															n/a			Yes
(tBuxant)-(Re(bpy)(CO)3Cl)2	0.05	Ir(fppy)3	0.05	BIH	0.005			DMF				TEA	0.005						> 400	4	78															n/a			Yes
(tBuxant)-(Re(bpy)(CO)3Cl)2	0.05	Ir(fppy)3	0.05	BIH	0.01			DMF				TEA	0.01						> 400	4	195															n/a			Yes
(tBuxant)-(Re(bpy)(CO)3Cl)2	0.05	Ir(fppy)3	0.05	BIH	0.01			DMF				TEA	0.01						> 400	4	154															n/a			No
(tBuxant)-(Re(bpy)(CO)3Cl)2	0.05	Ir(fppy)3	0.05	BIH	0.01			DMF				TEA	0.02						> 400	4	131															n/a			Yes
(tBuxant)-(Re(bpy)(CO)3Cl)2	0.05	Ir(fppy)3	0.05	BIH	0.02			DMF				TEA	0.01						> 400	4	134															n/a			Yes
(tBuxant)-(Re(bpy)(CO)3Cl)2	0.05	Ir(fppy)3	0.05	BIH	0.02			DMF				TEA	0.02						> 400	4	193															n/a			Yes
(tBuxant)-(Re(bpy)(CO)3Cl)2	0.05	Ir(fppy)3	0.05	BIH	0.5			DMF				TEA	0.5						> 400	4	255															n/a			Yes
(tBuxant)-(Re(bpy)(CO)3Cl)2	0.05			BIH	0.01			DMF				TEA	0.01						> 400	4	63															n/a			Yes
(tBuxant)-(Re(bpy)(CO)3Cl)2	0.05	Ir(fppy)3	0.005	BIH	0.01			DMF				TEA	0.01						> 400	4	124															n/a			Yes
(tBuxant)-(Re(bpy)(CO)3Cl)2	0.05	Ir(fppy)3	0.0125	BIH	0.01			DMF				TEA	0.01						> 400	4	144															n/a			Yes
(tBuxant)-(Re(bpy)(CO)3Cl)2	0.05	Ir(fppy)3	0.025	BIH	0.01			DMF				TEA	0.01						> 400	4	149															n/a			Yes
(tBuxant)-(Re(bpy)(CO)3Cl)2	0.05	Ir(fppy)3	0.1	BIH	0.05			DMF				TEA	0.005						> 400	4	270															n/a			Yes
(tBuxant)-(Re(bpy)(CO)3Cl)2	0.05	[Cu(bcp)(xant)][PF6]	0.05	BIH	0.01			DMF				TEA	0.01						> 400	4	169															n/a			Yes