Photocatalytic CO2 conversion to CH4

Table of all the experiments that have a turnover number for CH₄ greater than 100, sorted in descending order.

TON CH4 >100

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	additives	λexc [nm]	TON CO	TON CH4	TON H2
1.	[Ni(bpy)-(MeNHC)2][PF6]2	0.002	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA 5% (v/v), H2O 2% (v/v)	solar spectrum		570000
2.	[Ni(bpy)-(MeNHC)2][PF6]2	0.002	Ir(ppy)3	0.1	TEA		MeCN		solar spectrum	130000	29000	4900000
3.	[Ni(bpy-bNHCEt)][PF6]2	0.002	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	solar spectrum	175000	19000	29000
4.	[Ni(bpy)-(MeNHC)2][PF6]2	0.002	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	solar spectrum	51000	12000
5.	[Ni(bpy)-(MeNHC)2][PF6]2	0.002	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA 5% (v/v), H2O 2% (v/v)	solar spectrum		10000	58000
6.	[Ni(bpy-bNHCMe)][PF6]2	0.002	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	solar spectrum	8000	5000	34000
7.	[Ni(bpy)-(MeNHC)2][PF6]2	0.002	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA	solar spectrum	108000	4000	278000
8.	[Ni(bpy-bNHCMe)][PF6]2	0.002	Ir(ppy)3	0.1	TEA		MeCN		solar spectrum	5000	1000	15000
9.	Fe(pTMAPP)Cl5	2	Ir(ppy)3	0.2	TEA	0.05	MeCN	TFE	> 420		195	45
10.	Fe(pTMAPP)Cl5	2	Ir(ppy)3	0.2	TEA	0.05	MeCN	TFE	> 420		159	34
11.	Fe(pTMAPP)Cl5	2	Ir(ppy)3	0.2	TEA	0.05	MeCN		> 420		140	28
12.	Fe(pTMAPP)Cl5	2	Ir(ppy)3	0.2	TEA	0.05	MeCN	TFE	> 420		100	19

Table of all the experiments that have a turnover number for CH4 less than 100, sorted by catalyst. TON CH4 < 100

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	additives	λexc [nm]	TON CO	TON CH4	TON H2
1.	Fe(DHPP)Cl	2	Ir(ppy)3	0.2	TEA	0.05	MeCN		> 420	139	26	15
2.	Fe(pTMAPP)Cl5	2	[Ir(ppy)2(bpy)][PF6]	0.2	TEOA	0.05	MeCN		> 420	134	23	67
3.	Fe(pTMAPP)Cl5	2	[Ir(ppy)2(bpy)][PF6]	0.2	TEA	0.05	MeCN		> 420	24	3	5
4.	Fe(pTMAPP)Cl5	2	Ir(ppy)3	0.2	TEA	0.05	MeCN	TFE	> 420		100	19
5.	Fe(pTMAPP)Cl5	2	[Ir(ppy)2(bpy)][PF6]	0.2	TEA	0.05	MeCN		> 420	178	32	103
6.	Fe(pTMAPP)Cl5	2	[Ir(ppy)2(bpy)][PF6]	0.2	DIPEA	0.05	MeCN		> 420	151	24	77
7.	Fe(pTMAPP)Cl5	2	[Ir(ppy)2(bpy)][PF6]	0.2	TEOA	0.05	MeCN		> 420	19	3	4
8.	Fe(pTMAPP)Cl5	2	Ir(ppy)3	0.2	TEA	0.05	MeCN	TFE	> 420	240	66	73
9.	Fe(pTMAPP)Cl5	2	[Ir(ppy)2(bpy)][PF6]	0.2	DIPEA	0.05	MeCN		> 420	20	3	4
10.	Fe(pTMAPP)Cl5	2	Ir(ppy)3	0.2	TEA	0.05	MeCN		> 420	367	79	26
11.	Fe(pTMAPP)Cl5	10	Molecule:100493	1	TEA	0.1	DMF	TFE	> 435	140	29	23
12.	Fe(pTMAPP)Cl5	10	Molecule:100493	1	TEA	0.1	DMF		> 435	50	8	8
13.	Fe(pTMAPP)Cl5	2	Ir(ppy)3	0.2	TEA	0.05	MeCN		> 420		89	18
14.	Fe(pTMAPP)Cl5	2	Ir(ppy)3	0.2	TEA	0.05	MeCN		> 420	198	31	24
15.	Fe(pTMAPP)Cl5	10	Molecule:100493	1	TEA	0.1	DMF	TFE	> 435	71	14	10
16.	Fe(pTMAPP)Cl5	2	Ir(ppy)3	0.2	TEA	0.05	MeCN		> 420		89	18
17.	Fe(pTMAPP)Cl5	2	Ir(ppy)3	0.2	TEA	0.05	MeCN		> 420	198	31	24

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