Photocatalytic CO2 conversion to CH4

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Table of all the experiments that have a turnover number for CH4 greater than 100, sorted in descending order.

TON CH4 >100

catcat conc [µM]PSPS conc [mM]e-De-D conc [M]solvent Aadditives..λexc [nm].TON COTON CH4TON H2...
1.[Ni(bpy)-(MeNHC)2][PF6]20.002Ir(ppy)30.1BIH0.01MeCNTEA 5% (v/v), H2O 2% (v/v)solar spectrum570000
2.[Ni(bpy)-(MeNHC)2][PF6]20.002Ir(ppy)30.1TEAMeCNsolar spectrum130000290004900000
3.[Ni(bpy-bNHCEt)][PF6]20.002Ir(ppy)30.1BIH0.01MeCNTEA, H2Osolar spectrum1750001900029000
4.[Ni(bpy)-(MeNHC)2][PF6]20.002Ir(ppy)30.1BIH0.01MeCNTEA, H2Osolar spectrum5100012000
5.[Ni(bpy)-(MeNHC)2][PF6]20.002Ir(ppy)30.1BIH0.01MeCNTEA 5% (v/v), H2O 2% (v/v)solar spectrum1000058000
6.[Ni(bpy-bNHCMe)][PF6]20.002Ir(ppy)30.1BIH0.01MeCNTEA, H2Osolar spectrum8000500034000
7.[Ni(bpy)-(MeNHC)2][PF6]20.002Ir(ppy)30.1BIH0.01MeCNTEAsolar spectrum1080004000278000
8.[Ni(bpy-bNHCMe)][PF6]20.002Ir(ppy)30.1TEAMeCNsolar spectrum5000100015000
9.Fe(pTMAPP)Cl52Ir(ppy)30.2TEA0.05MeCNTFE> 42019545
10.Fe(pTMAPP)Cl52Ir(ppy)30.2TEA0.05MeCNTFE> 42015934
11.Fe(pTMAPP)Cl52Ir(ppy)30.2TEA0.05MeCN> 42014028
12.Fe(pTMAPP)Cl52Ir(ppy)30.2TEA0.05MeCNTFE> 42010019

Table of all the experiments that have a turnover number for CH4 less than 100, sorted by catalyst. TON CH4 < 100

catcat conc [µM]PSPS conc [mM]e-De-D conc [M]solvent A.additives..λexc [nm].TON COTON CH4TON H2..
1.Fe(DHPP)Cl2Ir(ppy)30.2TEA0.05MeCN> 4201392615
2.Fe(pTMAPP)Cl52[Ir(ppy)2(bpy)][PF6]0.2DIPEA0.05MeCN> 4202034
3.Fe(pTMAPP)Cl52Ir(ppy)30.2TEA0.05MeCN> 4203677926
4.Fe(pTMAPP)Cl510Molecule:100493 1TEA0.1DMFTFE> 4351402923
5.Fe(pTMAPP)Cl510Molecule:100493 1TEA0.1DMF> 4355088
6.Fe(pTMAPP)Cl52Ir(ppy)30.2TEA0.05MeCN> 4208918
7.Fe(pTMAPP)Cl52Ir(ppy)30.2TEA0.05MeCN> 4201983124
8.Fe(pTMAPP)Cl510Molecule:100493 1TEA0.1DMFTFE> 435711410
9.Fe(pTMAPP)Cl52Ir(ppy)30.2TEA0.05MeCN> 4208918
10.Fe(pTMAPP)Cl52Ir(ppy)30.2TEA0.05MeCN> 4201983124
11.Fe(pTMAPP)Cl52[Ir(ppy)2(bpy)][PF6]0.2TEOA0.05MeCN> 4201342367
12.Fe(pTMAPP)Cl52[Ir(ppy)2(bpy)][PF6]0.2TEA0.05MeCN> 4202435
13.Fe(pTMAPP)Cl52Ir(ppy)30.2TEA0.05MeCNTFE> 42010019
14.Fe(pTMAPP)Cl52[Ir(ppy)2(bpy)][PF6]0.2TEA0.05MeCN> 42017832103
15.Fe(pTMAPP)Cl52[Ir(ppy)2(bpy)][PF6]0.2DIPEA0.05MeCN> 4201512477
16.Fe(pTMAPP)Cl52[Ir(ppy)2(bpy)][PF6]0.2TEOA0.05MeCN> 4201934
17.Fe(pTMAPP)Cl52Ir(ppy)30.2TEA0.05MeCNTFE> 4202406673
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