Photocatalytic CO2 conversion to CH4

Table of all the experiments that have a turnover number for CH₄ greater than 100, sorted in descending order.

TON CH4 >100

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	additives	TON CO	TON CH4	TON H2
1.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA 5% (v/v), H2O 2% (v/v)		570000
2.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	TEA		MeCN		130000	29000	4900000
3.	[Ni(bpy-bNHCEt)][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	175000	19000	29000
4.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	51000	12000
5.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA 5% (v/v), H2O 2% (v/v)		10000	58000
6.	[Ni(bpy-bNHCMe)][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	8000	5000	34000
7.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA	108000	4000	278000
8.	[Ni(bpy-bNHCMe)][PF6]2	2.0E-6	Ir(ppy)3	0.1	TEA		MeCN		5000	1000	15000
9.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN	TFE		195	45
10.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN	TFE		159	34
11.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN			140	28
12.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN	TFE		100	19

Table of all the experiments that have a turnover number for CH4 less than 100, sorted by catalyst. TON CH4 < 100

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	additives	TON CO	TON CH4	TON H2
1.	Fe(DHPP)Cl	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN		139	26	15
2.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN		198	31	24
3.	Fe(pTMAPP)Cl5	0.01	Molecule:100493	1	TEA	0.1	DMF	TFE	71	14	10
4.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN			89	18
5.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN		198	31	24
6.	Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	TEOA	0.05	MeCN		134	23	67
7.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN	TFE		100	19
8.	Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	TEA	0.05	MeCN		24	3	5
9.	Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	TEA	0.05	MeCN		178	32	103
10.	Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	DIPEA	0.05	MeCN		151	24	77
11.	Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	TEOA	0.05	MeCN		19	3	4
12.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN	TFE	240	66	73
13.	Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	DIPEA	0.05	MeCN		20	3	4
14.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN		367	79	26
15.	Fe(pTMAPP)Cl5	0.01	Molecule:100493	1	TEA	0.1	DMF	TFE	140	29	23
16.	Fe(pTMAPP)Cl5	0.01	Molecule:100493	1	TEA	0.1	DMF		50	8	8
17.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN			89	18