Photocatalytic CO2 conversion to CH4
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Table of all the experiments that have a turnover number for CH4 greater than 100, sorted in descending order.
TON CH4 >100
cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | solvent A | additives | . | . | λexc [nm] | . | TON CO | TON CH4 | TON H2 | . | . | . | |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1. | [Ni(bpy)-(MeNHC)2][PF6]2 | 0.002 | Ir(ppy)3 | 0.1 | BIH | 0.01 | MeCN | TEA 5% (v/v), H2O 2% (v/v) | solar spectrum | 570000 | ||||||||
2. | [Ni(bpy)-(MeNHC)2][PF6]2 | 0.002 | Ir(ppy)3 | 0.1 | TEA | MeCN | solar spectrum | 130000 | 29000 | 4900000 | ||||||||
3. | [Ni(bpy-bNHCEt)][PF6]2 | 0.002 | Ir(ppy)3 | 0.1 | BIH | 0.01 | MeCN | TEA, H2O | solar spectrum | 175000 | 19000 | 29000 | ||||||
4. | [Ni(bpy)-(MeNHC)2][PF6]2 | 0.002 | Ir(ppy)3 | 0.1 | BIH | 0.01 | MeCN | TEA, H2O | solar spectrum | 51000 | 12000 | |||||||
5. | [Ni(bpy)-(MeNHC)2][PF6]2 | 0.002 | Ir(ppy)3 | 0.1 | BIH | 0.01 | MeCN | TEA 5% (v/v), H2O 2% (v/v) | solar spectrum | 10000 | 58000 | |||||||
6. | [Ni(bpy-bNHCMe)][PF6]2 | 0.002 | Ir(ppy)3 | 0.1 | BIH | 0.01 | MeCN | TEA, H2O | solar spectrum | 8000 | 5000 | 34000 | ||||||
7. | [Ni(bpy)-(MeNHC)2][PF6]2 | 0.002 | Ir(ppy)3 | 0.1 | BIH | 0.01 | MeCN | TEA | solar spectrum | 108000 | 4000 | 278000 | ||||||
8. | [Ni(bpy-bNHCMe)][PF6]2 | 0.002 | Ir(ppy)3 | 0.1 | TEA | MeCN | solar spectrum | 5000 | 1000 | 15000 | ||||||||
9. | Fe(pTMAPP)Cl5 | 2 | Ir(ppy)3 | 0.2 | TEA | 0.05 | MeCN | TFE | > 420 | 195 | 45 | |||||||
10. | Fe(pTMAPP)Cl5 | 2 | Ir(ppy)3 | 0.2 | TEA | 0.05 | MeCN | TFE | > 420 | 159 | 34 | |||||||
11. | Fe(pTMAPP)Cl5 | 2 | Ir(ppy)3 | 0.2 | TEA | 0.05 | MeCN | > 420 | 140 | 28 | ||||||||
12. | Fe(pTMAPP)Cl5 | 2 | Ir(ppy)3 | 0.2 | TEA | 0.05 | MeCN | TFE | > 420 | 100 | 19 |
Table of all the experiments that have a turnover number for CH4 less than 100, sorted by catalyst. TON CH4 < 100
cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | solvent A | . | additives | . | . | λexc [nm] | . | TON CO | TON CH4 | TON H2 | . | . | |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1. | Fe(DHPP)Cl | 2 | Ir(ppy)3 | 0.2 | TEA | 0.05 | MeCN | > 420 | 139 | 26 | 15 | |||||||
2. | Fe(pTMAPP)Cl5 | 2 | [Ir(ppy)2(bpy)][PF6] | 0.2 | DIPEA | 0.05 | MeCN | > 420 | 20 | 3 | 4 | |||||||
3. | Fe(pTMAPP)Cl5 | 2 | Ir(ppy)3 | 0.2 | TEA | 0.05 | MeCN | > 420 | 367 | 79 | 26 | |||||||
4. | Fe(pTMAPP)Cl5 | 10 | Molecule:100493 | 1 | TEA | 0.1 | DMF | TFE | > 435 | 140 | 29 | 23 | ||||||
5. | Fe(pTMAPP)Cl5 | 10 | Molecule:100493 | 1 | TEA | 0.1 | DMF | > 435 | 50 | 8 | 8 | |||||||
6. | Fe(pTMAPP)Cl5 | 2 | Ir(ppy)3 | 0.2 | TEA | 0.05 | MeCN | > 420 | 89 | 18 | ||||||||
7. | Fe(pTMAPP)Cl5 | 2 | Ir(ppy)3 | 0.2 | TEA | 0.05 | MeCN | > 420 | 198 | 31 | 24 | |||||||
8. | Fe(pTMAPP)Cl5 | 10 | Molecule:100493 | 1 | TEA | 0.1 | DMF | TFE | > 435 | 71 | 14 | 10 | ||||||
9. | Fe(pTMAPP)Cl5 | 2 | Ir(ppy)3 | 0.2 | TEA | 0.05 | MeCN | > 420 | 89 | 18 | ||||||||
10. | Fe(pTMAPP)Cl5 | 2 | Ir(ppy)3 | 0.2 | TEA | 0.05 | MeCN | > 420 | 198 | 31 | 24 | |||||||
11. | Fe(pTMAPP)Cl5 | 2 | [Ir(ppy)2(bpy)][PF6] | 0.2 | TEOA | 0.05 | MeCN | > 420 | 134 | 23 | 67 | |||||||
12. | Fe(pTMAPP)Cl5 | 2 | [Ir(ppy)2(bpy)][PF6] | 0.2 | TEA | 0.05 | MeCN | > 420 | 24 | 3 | 5 | |||||||
13. | Fe(pTMAPP)Cl5 | 2 | Ir(ppy)3 | 0.2 | TEA | 0.05 | MeCN | TFE | > 420 | 100 | 19 | |||||||
14. | Fe(pTMAPP)Cl5 | 2 | [Ir(ppy)2(bpy)][PF6] | 0.2 | TEA | 0.05 | MeCN | > 420 | 178 | 32 | 103 | |||||||
15. | Fe(pTMAPP)Cl5 | 2 | [Ir(ppy)2(bpy)][PF6] | 0.2 | DIPEA | 0.05 | MeCN | > 420 | 151 | 24 | 77 | |||||||
16. | Fe(pTMAPP)Cl5 | 2 | [Ir(ppy)2(bpy)][PF6] | 0.2 | TEOA | 0.05 | MeCN | > 420 | 19 | 3 | 4 | |||||||
17. | Fe(pTMAPP)Cl5 | 2 | Ir(ppy)3 | 0.2 | TEA | 0.05 | MeCN | TFE | > 420 | 240 | 66 | 73 |
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