Water-Assisted Highly Efficient Photocatalytic Reduction of CO2 to CO with Noble Metal-Free Bis(terpyridine)iron(II) Complexes and an Organic Photosensitizer

Abstract

Summary

A photochemical reduction of CO₂ to CO was shown using the iron complexes xx, xx and xx as catalysts in combination with the organic photosensitizer 4CzIPN (100938). Turnover numbers (TONs) of 6320 and a selectivity of 99.4% for CO were reached in DMF/H₂O with catalyst . The experiments were conducted under visible-light irradiation (λ = 440 nm) using TEA as sacrificial electron donor (see section SEDs below).

Content of the published article in detail

The article contains results for the reduction of CO₂ to CO under visible-light catalysis using the iron complex as a catalyst. The catalytic system performs best (referring to the TON of CO production) in DMF/H₂O.

Catalyst

(100946) [Show R-Groups]

Photosensitizer

4CzIPN (100938)

Sacrificial electron donor

In this study, the experiments were done with the sacrificial electron donor TEA (TEA (100505)).

Additives

In this study, no additives were tested.