New Photosensitizers Based on Heteroleptic Cu(I) Complexes and CO2 Photocatalytic Reduction with (Ni(II)(cyclam))Cl2

Content of the published article in detail

Catalysts

Ni(cyclam)Cl2 (100812)

Photosensitizers

(100906) (100907) (100908) (100909)

Investigations

		cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	.	.	.	.	λexc [nm]	.	TON CO	.	.
(edit)	1.	Ni(cyclam)Cl2	0.1	Molecule:100906	1	BIH	0.02	MeCN					420 nm (4 x 8 W)		4.3
(edit)	2.	Ni(cyclam)Cl2	0.1	Molecule:100907	1	BIH	0.02	MeCN					420 nm (4 x 8 W)		4.9
(edit)	3.	Ni(cyclam)Cl2	0.1	Molecule:100908	1	BIH	0.02	MeCN					420 nm (4 x 8 W)		8.1
(edit)	4.	Ni(cyclam)Cl2	0.1	Molecule:100909	1	BIH	0.02	MeCN					420 nm (4 x 8 W)		4.6
(edit)	5.	Ni(cyclam)Cl2	0.1	Molecule:100906	1	BIH	0.01	MeCN					420 nm (4 x 8 W)		2.6
(edit)	6.	Ni(cyclam)Cl2	0.1	Molecule:100907	1	BIH	0.01	MeCN					420 nm (4 x 8 W)		3.5
(edit)	7.	Ni(cyclam)Cl2	0.1	Molecule:100908	1	BIH	0.01	MeCN					420 nm (4 x 8 W)		5.0
(edit)	8.	Ni(cyclam)Cl2	0.1	Molecule:100909	1	BIH	0.01	MeCN					420 nm (4 x 8 W)		1.8
(edit)	9.	Ni(cyclam)Cl2	0.1	Molecule:100906	1	BIH	0.01	MeCN					420 nm (4 x 8 W)		2.8
(edit)	10.			Molecule:100908	1	BIH	0.01	MeCN					420 nm (4 x 8 W)
(edit)	11.	Ni(cyclam)Cl2	0.1	Molecule:100908	1	BIH	0.01	MeCN					420 nm (4 x 8 W)
(edit)	12.	Ni(cyclam)Cl2	0.1	Molecule:100908	1			MeCN					420 nm (4 x 8 W)
(edit)	13.	Ni(cyclam)Cl2	0.1	Molecule:100908	1	BIH	0.01	MeCN					420 nm (4 x 8 W)
(edit)	14.	Ni(cyclam)Cl2	0.1			BIH	0.01	MeCN					420 nm (4 x 8 W)
(edit)	15.	Ni(cyclam)Cl2	0.1	Molecule:100906	1	BIH	0.01	MeCN					dark
(edit)	16.	[Cu(ACN)4][BF4]	0.1	Molecule:100906	1	BIH	0.01	MeCN					420 nm (4 x 8 W)
(edit)	17.	Ni(cyclam)Cl2	0.1	Molecule:100906	1	BIH	0.02	MeCN					420 nm (4 x 8 W)		7.3
(edit)	18.	Ni(cyclam)Cl2	0.1	Molecule:100907	1	BIH	0.02	MeCN					420 nm (4 x 8 W)		6.5

Investigation-Name: Photocatalytic CO2 reduction and control experiments

Sacrificial Electron Donor

In this study, the experiments were done with the sacrificial electron donor BIH (100508).

Additives

In this study, N(Me)3 (100910) was used as a proton donor instead of TEOA (100507) for one experiment. [Cu(ACN)4][BF4] (100911) was used as a catalyst for a control experiment.