Highly Efficient and Selective Photocatalytic CO2 Reduction by Iron and Cobalt Quaterpyridine Complexes

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DOI 10.1021/jacs.6b06002
Authors Zhenguo Guo, Siwei Cheng, Claudio Cometto, Elodie Anxolabéhère-Mallart, Siu-Mui Ng, Chi-Chiu Ko, Guijian Liu, Lingjing Chen, Marc Robert, Tai-Chu Lau,
Submitted 22.07.2016
Published online 26.07.2016
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Subjects Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
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Catalysts

[Fe(qpy)(H2O)2][ClO4]2 (100786) [Co(qpy)(H2O)2][ClO4]2 (100788) Co(ClO4)2 (100789)

Photosensitizers

Ru(bpy)3Cl2 (100787) purpurin (100499)

Investigations

REDIRECT Optimizations of conditions for Co(qpy)(H2O)2(ClO4)2 and Ru(bpy)3Cl2Investigation-Name: Co(qpy)(H2O)2(ClO4)2 and Ru(bpy)3Cl2

REDIRECT Optimizations of conditions for Fe(qpy)(H2O)2(ClO4)2 and Ru(bpy)3Cl2Investigation-Name: Fe(qpy)(H2O)2(ClO4)2 and Ru(bpy)3Cl2

REDIRECT Optimizations of conditions for Co(qpy)(H2O)2(ClO4)2 and purpurinInvestigation-Name: Co(qpy)(H2O)2(ClO4)2 and purpurin

REDIRECT Optimizations of conditions for Fe(qpy)(H2O)2(ClO4)2Investigation-Name: Fe(qpy)(H2O)2(ClO4)2

Sacrificial electron donor

BIH (100508)

Investigations