Visible-Light-Driven Photocatalytic CO2 Reduction by a Ni(II) Complex Bearing a Bioinspired Tetradentate Ligand for Selective CO Production
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Investigation
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | solvent A | . | . | . | λexc [nm] | . | TON CO | . | TON H2 | . | . | . | ||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| (edit) | 1. | [Ni(bpet)(MeCN)2][ClO4]2 | 0.03 | Ru(bpy)3Cl2 | 0.5 | BIH | 0.1 | DMA | 450 | 713 | 6.9 | ||||||||
| (edit) | 2. | [Ni(bpet)(MeCN)2][ClO4]2 | 0.03 | Ru(bpy)3Cl2 | 0.5 | BIH | 0.1 | DMF | 450 | 159 | 11 | ||||||||
| (edit) | 3. | [Ni(bpet)(MeCN)2][ClO4]2 | 0.03 | Ru(bpy)3Cl2 | 0.5 | BIH | 0.1 | DMA | 450 | 67 | 3.4 | ||||||||
| (edit) | 4. | [Ni(bpet)(MeCN)2][ClO4]2 | 0.03 | Ru(bpy)3Cl2 | 0.5 | BIH | 0.1 | MeCN | 450 | ||||||||||
| (edit) | 5. | [Ni(bpet)(MeCN)2][ClO4]2 | 0.03 | Ru(bpy)3Cl2 | 0.5 | TEA | 0.1 | DMA | 450 | ||||||||||
| (edit) | 6. | [Ni(bpet)(MeCN)2][ClO4]2 | 0.03 | Ru(bpy)3Cl2 | 0.5 | TEOA | 0.1 | DMA | 450 | 2.6 | 25.5 |
Investigation-Name: Table 1
Catalyst
Photosensitizer
Sacrificial electron donor
Investigations
- Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)
