New Photosensitizers Based on Heteroleptic Cu(I) Complexes and CO2 Photocatalytic Reduction with (Ni(II)(cyclam))Cl2

Content of the published article in detail

Catalysts

Ni(cyclam)Cl2

Photosensitizers

100906 100907 100908 100909

Investigations

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	.	.	.	.	λexc [nm]	.	TON CO	.
1.	Ni(cyclam)Cl2	0.1	Molecule:100906	1	BIH	0.02	MeCN					420 nm (4 x 8 W)		4.3
2.	Ni(cyclam)Cl2	0.1	Molecule:100907	1	BIH	0.02	MeCN					420 nm (4 x 8 W)		4.9
3.	Ni(cyclam)Cl2	0.1	Molecule:100908	1	BIH	0.02	MeCN					420 nm (4 x 8 W)		8.1
4.	Ni(cyclam)Cl2	0.1	Molecule:100909	1	BIH	0.02	MeCN					420 nm (4 x 8 W)		4.6
5.	Ni(cyclam)Cl2	0.1	Molecule:100906	1	BIH	0.01	MeCN					420 nm (4 x 8 W)		2.6
6.	Ni(cyclam)Cl2	0.1	Molecule:100907	1	BIH	0.01	MeCN					420 nm (4 x 8 W)		3.5
7.	Ni(cyclam)Cl2	0.1	Molecule:100908	1	BIH	0.01	MeCN					420 nm (4 x 8 W)		5.0
8.	Ni(cyclam)Cl2	0.1	Molecule:100909	1	BIH	0.01	MeCN					420 nm (4 x 8 W)		1.8
9.	Ni(cyclam)Cl2	0.1	Molecule:100906	1	BIH	0.01	MeCN					420 nm (4 x 8 W)		2.8
10.			Molecule:100908	1	BIH	0.01	MeCN					420 nm (4 x 8 W)
11.	Ni(cyclam)Cl2	0.1	Molecule:100908	1	BIH	0.01	MeCN					420 nm (4 x 8 W)
12.	Ni(cyclam)Cl2	0.1	Molecule:100908	1			MeCN					420 nm (4 x 8 W)
13.	Ni(cyclam)Cl2	0.1	Molecule:100908	1	BIH	0.01	MeCN					420 nm (4 x 8 W)
14.	Ni(cyclam)Cl2	0.1			BIH	0.01	MeCN					420 nm (4 x 8 W)
15.	Ni(cyclam)Cl2	0.1	Molecule:100906	1	BIH	0.01	MeCN					dark
16.	[Cu(ACN)4][BF4]	0.1	Molecule:100906	1	BIH	0.01	MeCN					420 nm (4 x 8 W)
17.	Ni(cyclam)Cl2	0.1	Molecule:100906	1	BIH	0.02	MeCN					420 nm (4 x 8 W)		7.3
18.	Ni(cyclam)Cl2	0.1	Molecule:100907	1	BIH	0.02	MeCN					420 nm (4 x 8 W)		6.5

Investigation-Name: Photocatalytic CO2 reduction and control experimentsExport

Sacrificial Electron Donor

In this study, the experiments were done with the sacrificial electron donors

Additives

N(Me)3