Exploring the Full Potential of Photocatalytic Carbon Dioxide Reduction Using a Dinuclear Re2Cl2 Complex Assisted by Various Photosensitizers

[EtF21]

Investigation

1. REDIRECT Optimizations of the conditions

Investigation-Name: Table 1Export

	1	2	3		4	5	6	7	8	9	10	11	12	13
PS	100496	100496	100496	100496	100496	100496	100496	100496		100496	100496	100496	100496	100619
PS eq.	1	1	1	1	1	1	1	1		0.1	0.25	0.5	2	1
e-D 1	BIH
e-D 1 eq.		100	200	200	200	400	400	1000	200	200	200	200	1000	200
e-D 2	TEA
e-D 2 eq.	5 % v/v	100	200	200	400	200	400	1000	200	200	200	200	100	200
TON CO	52	78	195	154	131	134	193	255	63	124	144	149	270	169

Photosensitizer

Ir(dFppy)3 Ir(dFppy)3, Cu(xant)(bcp)

Catalyst

(Re(bpy)(CO)3Cl)2xant ? (Re2Cl2 in publication)