New Photosensitizers Based on Heteroleptic Cu(I) Complexes and CO2 Photocatalytic Reduction with (Ni(II)(cyclam))Cl2: Difference between revisions
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{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Photocatalytic CO2 reduction and control experiments|importFile=}} | {{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Photocatalytic CO2 reduction and control experiments|importFile=}} | ||
====Sacrificial Electron Donor==== | ====Sacrificial Electron Donor==== | ||
In this study, the experiments were done with the sacrificial electron | In this study, the experiments were done with the sacrificial electron donor {{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=false|width=300|height=200}}. | ||
====Additives==== | ====Additives==== | ||
<chemform smiles=" | In this study, {{#moleculelink:|link=GETQZCLCWQTVFV-UHFFFAOYSA-N|image=false|width=300|height=200}} was used as a proton donor instead of {{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=false|width=300|height=200}} for one experiment. {{#moleculelink:|link=|image=|width=|height=}} was used as a catalyst for a control experiment. | ||
-INDIGO- | |||
<chemform smiles="N(~[Cu+](~N#CC)(~N#CC)~N#CC)#CC.[B-](F)(F)(F)F" inchi="1S/4C2H3N.BF4.Cu/c4*1-2-3;2-1(3,4)5;/h4*1H3;;/q;;;;-1;+1" inchikey="YZGSKMIIVMCEFE-UHFFFAOYSA-N" height="200px" width="300px" float="none"> | |||
-INDIGO-04032418022D | |||
0 0 0 0 0 0 0 0 0 0 0 V3000 | 0 0 0 0 0 0 0 0 0 0 0 V3000 | ||
M V30 BEGIN CTAB | M V30 BEGIN CTAB | ||
M V30 COUNTS | M V30 COUNTS 18 16 0 0 0 | ||
M V30 BEGIN ATOM | M V30 BEGIN ATOM | ||
M V30 1 C 7. | M V30 1 N 9.05026 -5.17526 0.0 0 | ||
M V30 | M V30 2 C 9.05026 -4.17526 0.0 0 | ||
M V30 | M V30 3 C 9.05026 -3.17526 0.0 0 | ||
M V30 | M V30 4 Cu 9.05026 -6.17526 0.0 0 CHG=1 | ||
M V30 5 N 9.05026 -7.17526 0.0 0 | |||
M V30 6 N 10.0503 -6.17526 0.0 0 | |||
M V30 7 N 8.05026 -6.17526 0.0 0 | |||
M V30 8 C 11.0503 -6.17526 0.0 0 | |||
M V30 9 C 12.0503 -6.17526 0.0 0 | |||
M V30 10 C 9.05026 -8.17526 0.0 0 | |||
M V30 11 C 9.05026 -9.17526 0.0 0 | |||
M V30 12 C 7.05026 -6.17526 0.0 0 | |||
M V30 13 C 6.05026 -6.17526 0.0 0 | |||
M V30 14 B 11.7503 -3.70026 0.0 0 CHG=-1 | |||
M V30 15 F 10.7503 -3.70026 0.0 0 | |||
M V30 16 F 11.7503 -2.70026 0.0 0 | |||
M V30 17 F 12.7503 -3.70026 0.0 0 | |||
M V30 18 F 11.7503 -4.70026 0.0 0 | |||
M V30 END ATOM | M V30 END ATOM | ||
M V30 BEGIN BOND | M V30 BEGIN BOND | ||
M V30 1 | M V30 1 3 1 2 | ||
M V30 2 1 2 3 | M V30 2 1 2 3 | ||
M V30 3 1 | M V30 3 8 1 4 | ||
M V30 4 8 4 5 | |||
M V30 5 8 4 6 | |||
M V30 6 8 4 7 | |||
M V30 7 3 6 8 | |||
M V30 8 1 8 9 | |||
M V30 9 3 5 10 | |||
M V30 10 1 10 11 | |||
M V30 11 3 7 12 | |||
M V30 12 1 12 13 | |||
M V30 13 1 14 15 | |||
M V30 14 1 14 16 | |||
M V30 15 1 14 17 | |||
M V30 16 1 14 18 | |||
M V30 END BOND | M V30 END BOND | ||
M V30 END CTAB | M V30 END CTAB | ||
M END | M END | ||
</chemform> | </chemform> | ||
Revision as of 17:03, 3 April 2024
Abstract
Summary
Advances and special progress
Additional remarks
Content of the published article in detail
Catalysts
Photosensitizers
Investigations
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | solvent A | . | . | . | . | λexc [nm] | . | TON CO | . | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1. | 0.1 | 1 | 0.02 | 420 nm (4 x 8 W) | 4.3 | ||||||||||
| 2. | 0.1 | 1 | 0.02 | 420 nm (4 x 8 W) | 4.9 | ||||||||||
| 3. | 0.1 | 1 | 0.02 | 420 nm (4 x 8 W) | 8.1 | ||||||||||
| 4. | 0.1 | 1 | 0.02 | 420 nm (4 x 8 W) | 4.6 | ||||||||||
| 5. | 0.1 | 1 | 0.01 | 420 nm (4 x 8 W) | 2.6 | ||||||||||
| 6. | 0.1 | 1 | 0.01 | 420 nm (4 x 8 W) | 3.5 | ||||||||||
| 7. | 0.1 | 1 | 0.01 | 420 nm (4 x 8 W) | 5.0 | ||||||||||
| 8. | 0.1 | 1 | 0.01 | 420 nm (4 x 8 W) | 1.8 | ||||||||||
| 9. | 0.1 | 1 | 0.01 | 420 nm (4 x 8 W) | 2.8 | ||||||||||
| 10. | 1 | 0.01 | 420 nm (4 x 8 W) | ||||||||||||
| 11. | 0.1 | 1 | 0.01 | 420 nm (4 x 8 W) | |||||||||||
| 12. | 0.1 | 1 | 420 nm (4 x 8 W) | ||||||||||||
| 13. | 0.1 | 1 | 0.01 | 420 nm (4 x 8 W) | |||||||||||
| 14. | 0.1 | 0.01 | 420 nm (4 x 8 W) | ||||||||||||
| 15. | 0.1 | 1 | 0.01 | dark | |||||||||||
| 16. | 0.1 | 1 | 0.01 | 420 nm (4 x 8 W) | |||||||||||
| 17. | 0.1 | 1 | 0.02 | 420 nm (4 x 8 W) | 7.3 | ||||||||||
| 18. | 0.1 | 1 | 0.02 | 420 nm (4 x 8 W) | 6.5 |
Investigation-Name: Photocatalytic CO2 reduction and control experiments
Sacrificial Electron Donor
In this study, the experiments were done with the sacrificial electron donor BIH.
Additives
In this study, N(Me)3 was used as a proton donor instead of TEOA for one experiment. -missing link parameter- was used as a catalyst for a control experiment.
Investigations
- Photocatalytic CO2 reduction and control experiments (Molecular process, Photocatalytic CO2 conversion experiments)
