New Photosensitizers Based on Heteroleptic Cu(I) Complexes and CO2 Photocatalytic Reduction with (Ni(II)(cyclam))Cl2: Difference between revisions
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publication
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====Investigations==== | ====Investigations==== | ||
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Photocatalytic CO2 reduction and control experiments|importFile=}} | |||
====Sacrificial Electron Donor==== | ====Sacrificial Electron Donor==== | ||
In this study, the experiments were done with the sacrificial electron donors | In this study, the experiments were done with the sacrificial electron donors | ||
====Additives==== | ====Additives==== | ||
<chemform smiles="CN(C)C" inchi="1S/C3H9N/c1-4(2)3/h1-3H3" inchikey="GETQZCLCWQTVFV-UHFFFAOYSA-N" height="200px" width="300px" float="none"> | |||
-INDIGO-04032416482D | |||
0 0 0 0 0 0 0 0 0 0 0 V3000 | |||
M V30 BEGIN CTAB | |||
M V30 COUNTS 4 3 0 0 0 | |||
M V30 BEGIN ATOM | |||
M V30 1 C 7.71725 -5.52526 0.0 0 | |||
M V30 2 N 8.58327 -5.02526 0.0 0 | |||
M V30 3 C 9.4493 -5.52526 0.0 0 | |||
M V30 4 C 8.58327 -4.02526 0.0 0 | |||
M V30 END ATOM | |||
M V30 BEGIN BOND | |||
M V30 1 1 1 2 | |||
M V30 2 1 2 3 | |||
M V30 3 1 2 4 | |||
M V30 END BOND | |||
M V30 END CTAB | |||
M END | |||
</chemform> | |||
Revision as of 15:48, 3 April 2024
Abstract
Summary
Advances and special progress
Additional remarks
Content of the published article in detail
Catalysts
Photosensitizers
Investigations
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | solvent A | . | . | . | . | λexc [nm] | . | TON CO | . | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1. | 0.1 | 1 | 0.02 | 420 nm (4 x 8 W) | 4.3 | ||||||||||
| 2. | 0.1 | 1 | 0.02 | 420 nm (4 x 8 W) | 4.9 | ||||||||||
| 3. | 0.1 | 1 | 0.02 | 420 nm (4 x 8 W) | 8.1 | ||||||||||
| 4. | 0.1 | 1 | 0.02 | 420 nm (4 x 8 W) | 4.6 | ||||||||||
| 5. | 0.1 | 1 | 0.01 | 420 nm (4 x 8 W) | 2.6 | ||||||||||
| 6. | 0.1 | 1 | 0.01 | 420 nm (4 x 8 W) | 3.5 | ||||||||||
| 7. | 0.1 | 1 | 0.01 | 420 nm (4 x 8 W) | 5.0 | ||||||||||
| 8. | 0.1 | 1 | 0.01 | 420 nm (4 x 8 W) | 1.8 | ||||||||||
| 9. | 0.1 | 1 | 0.01 | 420 nm (4 x 8 W) | 2.8 | ||||||||||
| 10. | 1 | 0.01 | 420 nm (4 x 8 W) | ||||||||||||
| 11. | 0.1 | 1 | 0.01 | 420 nm (4 x 8 W) | |||||||||||
| 12. | 0.1 | 1 | 420 nm (4 x 8 W) | ||||||||||||
| 13. | 0.1 | 1 | 0.01 | 420 nm (4 x 8 W) | |||||||||||
| 14. | 0.1 | 0.01 | 420 nm (4 x 8 W) | ||||||||||||
| 15. | 0.1 | 1 | 0.01 | dark | |||||||||||
| 16. | 0.1 | 1 | 0.01 | 420 nm (4 x 8 W) | |||||||||||
| 17. | 0.1 | 1 | 0.02 | 420 nm (4 x 8 W) | 7.3 | ||||||||||
| 18. | 0.1 | 1 | 0.02 | 420 nm (4 x 8 W) | 6.5 |
Investigation-Name: Photocatalytic CO2 reduction and control experiments
Sacrificial Electron Donor
In this study, the experiments were done with the sacrificial electron donors
Additives
Investigations
- Photocatalytic CO2 reduction and control experiments (Molecular process, Photocatalytic CO2 conversion experiments)
