Exploring the Full Potential of Photocatalytic Carbon Dioxide Reduction Using a Dinuclear Re2Cl2 Complex Assisted by Various Photosensitizers: Difference between revisions

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DOI 10.1002/cptc.202100034
Authors Robin Giereth, Martin Obermeier, Lukas Forschner, Michael Karnahl, Matthias Schwalbe, Stefanie Tschierlei,
Submitted 17.03.2021
Published online 02.05.2021
Licenses http://creativecommons.org/licenses/by-nc-nd/4.0/, http://doi.wiley.com/10.1002/tdm_license_1.1,
Subjects Organic Chemistry, Physical and Theoretical Chemistry, Analytical Chemistry
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===Catalyst===
===Catalyst===
{{#moleculelink:|link=SPPICNUXBVPFDY-UHFFFAOYSA-N|image=true}}<chemform smiles="C12C=C(C(C)(C)C)C=C(C3C=N4[Re+]N5=CC=CC=C5C4=CC=3)C=1OC1C(C3C=CC4C5C=CC=CN=5[Re+]N=4C=3)=CC(C(C)(C)C)=CC=1C2(C)C" inchi="1S/C43H42N4O.2Re/c1-41(2,3)29-21-31(27-15-17-37(46-25-27)35-13-9-11-19-44-35)39-33(23-29)43(7,8)34-24-30(42(4,5)6)22-32(40(34)48-39)28-16-18-38(47-26-28)36-14-10-12-20-45-36;;/h9-26H,1-8H3;;/q;2*+1" inchikey="QXFGRTLTRDAHQO-UHFFFAOYSA-N" height="200px" width="300px" float="none">
{{#moleculelink:|link=SPPICNUXBVPFDY-UHFFFAOYSA-N|image=true}}
  -INDIGO-11272315032D
 
  0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 COUNTS 50 58 0 0 0
M  V30 BEGIN ATOM
M  V30 1 C 7.98749 -8.45976 0.0 0
M  V30 2 C 8.98751 -8.45976 0.0 0
M  V30 3 O 9.48751 -7.59375 0.0 0
M  V30 4 C 8.98751 -6.72774 0.0 0
M  V30 5 C 7.98749 -6.72774 0.0 0
M  V30 6 C 7.48749 -7.59375 0.0 0
M  V30 7 C 7.48958 -5.86404 0.0 0
M  V30 8 C 7.98945 -4.99766 0.0 0
M  V30 9 C 9.48938 -5.85789 0.0 0
M  V30 10 C 8.98444 -4.99546 0.0 0
M  V30 11 C 9.48542 -9.32346 0.0 0
M  V30 12 C 8.98555 -10.1898 0.0 0
M  V30 13 C 7.48562 -9.32961 0.0 0
M  V30 14 C 7.99056 -10.192 0.0 0
M  V30 15 C 7.48837 -4.13226 0.0 0
M  V30 16 C 7.98729 -3.26561 0.0 0
M  V30 17 C 6.48837 -4.13351 0.0 0
M  V30 18 C 6.98837 -3.26624 0.0 0
M  V30 19 C 7.49416 -11.0601 0.0 0
M  V30 20 C 6.49417 -11.0643 0.0 0
M  V30 21 C 7.99774 -11.9241 0.0 0
M  V30 22 C 6.99416 -11.9262 0.0 0
M  V30 23 C 6.78038 -6.88664 0.0 0
M  V30 24 C 6.78038 -8.30086 0.0 0
M  V30 25 C 10.4894 -5.85789 0.0 0
M  V30 26 N 11.987 -4.99132 0.0 0
M  V30 27 C 10.9894 -4.99106 0.0 0
M  V30 28 C 12.4881 -5.85782 0.0 0
M  V30 29 C 10.9924 -6.72786 0.0 0
M  V30 30 C 11.9925 -6.7214 0.0 0
M  V30 31 C 13.4881 -5.85782 0.0 0
M  V30 32 C 14.9858 -4.99125 0.0 0
M  V30 33 N 13.9881 -4.99099 0.0 0
M  V30 34 C 15.4868 -5.85775 0.0 0
M  V30 35 C 13.9911 -6.7278 0.0 0
M  V30 36 C 14.9912 -6.72133 0.0 0
M  V30 37 C 10.4854 -9.32346 0.0 0
M  V30 38 C 11.9831 -8.45688 0.0 0
M  V30 39 C 10.9854 -8.45662 0.0 0
M  V30 40 C 12.4841 -9.32339 0.0 0
M  V30 41 C 10.9885 -10.1934 0.0 0
M  V30 42 N 11.9885 -10.187 0.0 0
M  V30 43 C 13.4841 -9.32339 0.0 0
M  V30 44 C 14.9818 -8.45681 0.0 0
M  V30 45 C 13.9842 -8.45655 0.0 0
M  V30 46 C 15.4829 -9.32332 0.0 0
M  V30 47 N 13.9872 -10.1934 0.0 0
M  V30 48 C 14.9872 -10.1869 0.0 0
M  V30 49 Re 12.9441 -4.13421 0.0 0 CHG=1
M  V30 50 Re 12.9174 -11.1007 0.0 0 CHG=1
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 1 1 6
M  V30 2 2 1 2
M  V30 3 1 2 3
M  V30 4 1 3 4
M  V30 5 2 4 5
M  V30 6 1 5 6
M  V30 7 2 8 7
M  V30 8 1 4 9
M  V30 9 1 7 5
M  V30 10 2 9 10
M  V30 11 1 10 8
M  V30 12 2 12 11
M  V30 13 1 1 13
M  V30 14 1 11 2
M  V30 15 2 13 14
M  V30 16 1 14 12
M  V30 17 1 8 15
M  V30 18 1 15 16
M  V30 19 1 15 17
M  V30 20 1 15 18
M  V30 21 1 14 19
M  V30 22 1 19 20
M  V30 23 1 19 21
M  V30 24 1 19 22
M  V30 25 1 6 23
M  V30 26 1 6 24
M  V30 27 1 9 25
M  V30 28 2 27 25
M  V30 29 2 28 26
M  V30 30 1 25 29
M  V30 31 1 26 27
M  V30 32 2 29 30
M  V30 33 1 30 28
M  V30 34 1 28 31
M  V30 35 2 33 31
M  V30 36 2 34 32
M  V30 37 1 31 35
M  V30 38 1 32 33
M  V30 39 2 35 36
M  V30 40 1 36 34
M  V30 41 1 11 37
M  V30 42 2 39 37
M  V30 43 2 40 38
M  V30 44 1 37 41
M  V30 45 1 38 39
M  V30 46 2 41 42
M  V30 47 1 42 40
M  V30 48 1 40 43
M  V30 49 2 45 43
M  V30 50 2 46 44
M  V30 51 1 43 47
M  V30 52 1 44 45
M  V30 53 2 47 48
M  V30 54 1 48 46
M  V30 55 10 26 49
M  V30 56 10 49 33
M  V30 57 10 42 50
M  V30 58 10 47 50
M  V30 END BOND
M  V30 END CTAB
M  END
</chemform>


===Photosensitizer===
===Photosensitizer===

Revision as of 13:08, 10 January 2024


WikiTemplate chemistry.pngFaulty molecule
A molecule on this page has a mistake in its structure or is missing a part. Please edit the structure or redraw a new molecule using the replace molecule workflow.

Catalyst

Molecule with key SPPICNUXBVPFDY-UHFFFAOYSA-N does not exist.

Photosensitizer

Ir(fppy)3 [Cu(bcp)(xant)][PF6]

Investigation

  1. REDIRECT Optimizations of the conditions
Investigation-Name: Table 1

Sacrificial electron donor

TEABIH

Investigations

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