Visible light driven reduction of CO2 catalyzed by an abundant manganese catalyst with zinc porphyrin photosensitizer: Difference between revisions

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DOI 10.1016/j.apcata.2016.04.035
Authors Jun-Xiao Zhang, Chang-Ying Hu, Wei Wang, Hui Wang, Zhao-Yong Bian,
Submitted 08.05.2016
Licenses https://www.elsevier.com/tdm/userlicense/1.0/,
Subjects Process Chemistry and Technology, Catalysis
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==== Sacrificial electron donor ====
==== Sacrificial electron donor ====
{{#moleculelink: |link=CKPHTUFEGVEMOQ-UHFFFAOYSA-N|image=true}}
{{#moleculelink: |link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=true}}

Revision as of 16:53, 4 January 2024


Catalyst

Mn(bpy)(CO)3Br

Photosensitizer

ZnTPP

Investigation

catcat conc [µM]PSPS conc [mM]e-De-D conc [M]solvent A..λexc [nm].TON COTON HCOOH.
1.

Mn(bpy)(CO)3Br

2

ZnTPP

0.5

TEA

0.1

MeCN

xenon lamp11919
2.

Mn(bpy)(CO)3Br

1.5

ZnTPP

0.5

TEA

0.1

MeCN

xenon lamp9718
3.

Mn(bpy)(CO)3Br

0.5

ZnTPP

0.25

TEA

0.1

MeCN

xenon lamp6416
4.

Mn(bpy)(CO)3Br

0.5

ZnTPP

0.5

TEA

0.1

MeCN

xenon lamp1210
5.

Mn(bpy)(CO)3Br

0.5

ZnTPP

1

TEA

0.1

MeCN

xenon lamp86
6.

Mn(bpy)(CO)3Br

0.5


TEA

0.1

MeCN

xenon lamp21
7.


ZnTPP

0.5

TEA

0.1

MeCN

xenon lamp
Investigation-Name: Table 1

Sacrificial electron donor

TEA

Investigations

  • Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)