Visible light driven reduction of CO2 catalyzed by an abundant manganese catalyst with zinc porphyrin photosensitizer: Difference between revisions
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==== Sacrificial electron donor ==== | ==== Sacrificial electron donor ==== | ||
{{#moleculelink:|link= | {{#moleculelink: |link=CKPHTUFEGVEMOQ-UHFFFAOYSA-N|image=true}} |
Revision as of 16:44, 4 January 2024
Catalyst
Photosensitizer
Investigation
cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | solvent A | . | . | λexc [nm] | . | TON CO | TON HCOOH | . | |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1. | 2 | 0.5 | 0.1 | xenon lamp | 119 | 19 | ||||||||
2. | 1.5 | 0.5 | 0.1 | xenon lamp | 97 | 18 | ||||||||
3. | 0.5 | 0.25 | 0.1 | xenon lamp | 64 | 16 | ||||||||
4. | 0.5 | 0.5 | 0.1 | xenon lamp | 12 | 10 | ||||||||
5. | 0.5 | 1 | 0.1 | xenon lamp | 8 | 6 | ||||||||
6. | 0.5 | 0.1 | xenon lamp | 2 | 1 | |||||||||
7. | 0.5 | 0.1 | xenon lamp |
Investigation-Name: Table 1
Sacrificial electron donor
Molecule with key CKPHTUFEGVEMOQ-UHFFFAOYSA-N does not exist.
Investigations
- Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)