Molecular Catalysis of the Electrochemical and Photochemical Reduction of CO2 with Earth-Abundant Metal Complexes. Selective Production of CO vs HCOOH by Switching of the Metal Center: Difference between revisions
From ChemWiki
publication
| About |
|---|
No edit summary |
(auto-generated) |
||
| Line 163: | Line 163: | ||
====Sacrificial electron donor==== | ====Sacrificial electron donor==== | ||
{{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=true}} | {{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=true}} | ||
Please remove this! | |||
Revision as of 22:50, 27 December 2023
Catalyst
[Fe(pabop)Cl2][CLO4]
[Co(pabop)][ClO4]2
Photosensitizer
Investigation
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | solvent A | . | . | λexc [nm] | . | TON CO | TON HCOOH | . | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1. | 0.05 | 0.2 | >460 | 270 | |||||||||
| 2. | 0.05 | 0.2 | >420 | 5 |
Investigation-Name: Table 1
Sacrificial electron donor
TEA
Please remove this!
Investigations
- Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)
