Visible-Light-Driven Photocatalytic CO2 Reduction by a Ni(II) Complex Bearing a Bioinspired Tetradentate Ligand for Selective CO Production: Difference between revisions

Revision as of 16:58, 27 November 2023

Catalyst

Molecule with key YWLPEVCCGUVAOP-UHFFFAOYSA-N does not exist.

Photosensitizer

Investigation

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	λexc [nm]	TON CO	TON H2
1.	[Ni(bpet)(MeCN)2][ClO4]2	0.03	Ru(bpy)3Cl2	0.5	BIH	0.1	DMA	450	713	6.9
2.	[Ni(bpet)(MeCN)2][ClO4]2	0.03	Ru(bpy)3Cl2	0.5	BIH	0.1	DMF	450	159	11
3.	[Ni(bpet)(MeCN)2][ClO4]2	0.03	Ru(bpy)3Cl2	0.5	BIH	0.1	DMA	450	67	3.4
4.	[Ni(bpet)(MeCN)2][ClO4]2	0.03	Ru(bpy)3Cl2	0.5	BIH	0.1	MeCN	450
5.	[Ni(bpet)(MeCN)2][ClO4]2	0.03	Ru(bpy)3Cl2	0.5	TEA	0.1	DMA	450
6.	[Ni(bpet)(MeCN)2][ClO4]2	0.03	Ru(bpy)3Cl2	0.5	TEOA	0.1	DMA	450	2.6	25.5

Investigation-Name: Table 1

Sacrificial electron donor

BIH TEA TEOA

Investigations

Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)

DOI	10.1021/jacs.7b01956
Authors	Dachao Hong, Yuto Tsukakoshi, Hiroaki Kotani, Tomoya Ishizuka, Takahiko Kojima,
Submitted	28.04.2017
Published online	04.05.2017
Licenses	-
Subjects	Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
Go to literature page

@@ Line 6: / Line 6: @@
 ====Photosensitizer====
-<chemform smiles="C12C3=CC=CC=N3[Ru+2](N1=CC=CC=2)1(N2C=CC=CC=2C2N1=CC=CC=2)1N2C=CC=CC=2C2N1=CC=CC=2" inchi="1S/3C10H8N2.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;/h3*1-8H;/q;;;+2" inchikey="HNVRWFFXWFXICS-UHFFFAOYSA-N" height="200px" width="300px" float="none">
+<chemform smiles="C1C=N2[Ru+2]3(N4C(C5N3=CC=CC=5)=CC=CC=4)3(N4=CC=CC=C4C4=CC=CC=N43)N3=CC=CC=C3C2=CC=1.[Cl-].[Cl-]" inchi="1S/3C10H8N2.2ClH.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;;;/h3*1-8H;2*1H;/q;;;;;+2/p-2" inchikey="SJFYGUKHUNLZTK-UHFFFAOYSA-L" height="200px" width="300px" float="none">
-   -INDIGO-02012310412D
+   -INDIGO-11272316582D
   0  0  0  0  0  0  0  0  0  0 V3000
 M  V30 BEGIN CTAB
-M  V30 COUNTS 37 45 0 0 0
+M  V30 COUNTS 39 45 0 0 0
 M  V30 BEGIN ATOM
-M  V30 1 C 10.5435 -4.92762 0.0 0
+M  V30 1 C 8.38485 -1.67507 0.0 0
-M  V30 2 C 11.7491 -4.99092 0.0 0
+M  V30 2 C 10.1152 -1.67459 0.0 0
-M  V30 3 C 11.2288 -4.73543 0.0 0
+M  V30 3 C 9.25164 -1.17497 0.0 0
-M  V30 4 C 11.8152 -5.59773 0.0 0
+M  V30 4 C 10.1152 -2.67553 0.0 0
-M  V30 5 N 10.1065 -5.76474 0.0 0
+M  V30 5 C 8.38485 -2.68002 0.0 0
-M  V30 6 C 11.152 -6.14351 0.0 0
+M  V30 6 N 9.25382 -3.17503 0.0 0
-M  V30 7 N 9.25866 -4.63911 0.0 0
+M  V30 7 C 10.9812 -3.17553 0.0 0
-M  V30 8 C 9.63235 -3.30328 0.0 0
+M  V30 8 C 12.7115 -3.17389 0.0 0
-M  V30 9 C 9.14128 -3.93512 0.0 0
+M  V30 9 C 11.8476 -2.67484 0.0 0
-M  V30 10 C 10.2777 -3.25752 0.0 0
+M  V30 10 C 12.7121 -4.17483 0.0 0
-M  V30 11 C 10.2001 -4.55637 0.0 0
+M  V30 11 N 10.9818 -4.18048 0.0 0
-M  V30 12 C 10.6339 -3.773 0.0 0
+M  V30 12 C 11.8512 -4.67491 0.0 0
-M  V30 13 C 5.94213 -3.03516 0.0 0
+M  V30 13 N 10.9848 -6.20007 0.0 0
-M  V30 14 C 7.24168 -3.49305 0.0 0
+M  V30 14 C 12.7152 -6.19959 0.0 0
-M  V30 15 C 6.59328 -2.8886 0.0 0
+M  V30 15 C 11.8516 -5.69997 0.0 0
-M  V30 16 N 7.04427 -4.43995 0.0 0
+M  V30 16 C 12.7152 -7.20053 0.0 0
-M  V30 17 C 5.69026 -3.59788 0.0 0
+M  V30 17 C 10.9848 -7.20502 0.0 0
-M  V30 18 C 6.01761 -4.2224 0.0 0
+M  V30 18 C 11.8538 -7.70003 0.0 0
-M  V30 19 C 4.16032 -4.25649 0.0 0
+M  V30 19 C 10.1188 -7.70502 0.0 0
-M  V30 20 C 5.64012 -4.58942 0.0 0
+M  V30 20 C 9.2551 -9.20433 0.0 0
-M  V30 21 C 4.8164 -4.06601 0.0 0
+M  V30 21 C 10.1192 -8.70573 0.0 0
-M  V30 22 N 5.79253 -5.37659 0.0 0
+M  V30 22 C 8.38792 -8.70444 0.0 0
-M  V30 23 C 3.99774 -4.91039 0.0 0
+M  V30 23 N 9.24818 -7.20313 0.0 0
-M  V30 24 C 4.6602 -5.58382 0.0 0
+M  V30 24 C 8.38534 -7.70875 0.0 0
-M  V30 25 C 5.61199 -8.17009 0.0 0
+M  V30 25 C 5.70985 -6.27507 0.0 0
-M  V30 26 C 7.22575 -8.54472 0.0 0
+M  V30 26 N 7.44015 -6.27459 0.0 0
-M  V30 27 N 6.81042 -7.59487 0.0 0
+M  V30 27 C 6.57664 -5.77497 0.0 0
-M  V30 28 C 7.08099 -9.28642 0.0 0
+M  V30 28 C 7.44015 -7.27553 0.0 0
-M  V30 29 C 5.63354 -9.26837 0.0 0
+M  V30 29 C 5.70985 -7.28002 0.0 0
-M  V30 30 C 6.38037 -9.63065 0.0 0
+M  V30 30 C 6.57882 -7.77503 0.0 0
-M  V30 31 C 8.04784 -8.35665 0.0 0
+M  V30 31 C 6.57664 -4.77497 0.0 0
-M  V30 32 C 9.63143 -8.08568 0.0 0
+M  V30 32 C 5.71006 -3.2773 0.0 0
-M  V30 33 N 8.65644 -7.66877 0.0 0
+M  V30 33 C 5.7098 -4.27494 0.0 0
-M  V30 34 C 9.74901 -9.15397 0.0 0
+M  V30 34 C 6.57657 -2.77625 0.0 0
-M  V30 35 C 8.28703 -9.41911 0.0 0
+M  V30 35 N 7.44661 -4.27191 0.0 0
-M  V30 36 C 9.08273 -9.6819 0.0 0
+M  V30 36 C 7.44015 -3.27186 0.0 0
-M  V30 37 Ru 7.90443 -6.04653 0.0 0 CHG=2
+M  V30 37 Ru 9.21263 -5.19691 0.0 0 CHG=2
+M  V30 38 Cl 14.05 -1.95 0.0 0 CHG=-1
+M  V30 39 Cl 14.1 -3.225 0.0 0 CHG=-1
 M  V30 END ATOM
 M  V30 BEGIN BOND
@@ Line 58: / Line 60: @@
 M  V30 5 2 5 6
 M  V30 6 1 6 4
-M  V30 7 2 9 7
+M  V30 7 1 4 7
-M  V30 8 2 10 8
+M  V30 8 2 9 7
-M  V30 9 1 7 11
+M  V30 9 2 10 8
-M  V30 10 1 8 9
+M  V30 10 1 7 11
-M  V30 11 2 11 12
+M  V30 11 1 8 9
-M  V30 12 1 12 10
+M  V30 12 2 11 12
-M  V30 13 2 15 13
+M  V30 13 1 12 10
-M  V30 14 2 16 14
+M  V30 14 2 15 13
-M  V30 15 1 13 17
+M  V30 15 2 16 14
-M  V30 16 1 14 15
+M  V30 16 1 13 17
-M  V30 17 2 17 18
+M  V30 17 1 14 15
-M  V30 18 1 18 16
+M  V30 18 2 17 18
-M  V30 19 2 21 19
+M  V30 19 1 18 16
-M  V30 20 2 22 20
+M  V30 20 1 17 19
-M  V30 21 1 19 23
+M  V30 21 2 21 19
-M  V30 22 1 20 21
+M  V30 22 2 22 20
-M  V30 23 2 23 24
+M  V30 23 1 19 23
-M  V30 24 1 24 22
+M  V30 24 1 20 21
-M  V30 25 2 27 25
+M  V30 25 2 23 24
-M  V30 26 2 28 26
+M  V30 26 1 24 22
-M  V30 27 1 25 29
+M  V30 27 2 27 25
-M  V30 28 1 26 27
+M  V30 28 2 28 26
-M  V30 29 2 29 30
+M  V30 29 1 25 29
-M  V30 30 1 30 28
+M  V30 30 1 26 27
-M  V30 31 2 33 31
+M  V30 31 2 29 30
-M  V30 32 2 34 32
+M  V30 32 1 30 28
-M  V30 33 1 31 35
+M  V30 33 1 27 31
-M  V30 34 1 32 33
+M  V30 34 2 33 31
-M  V30 35 2 35 36
+M  V30 35 2 34 32
-M  V30 36 1 36 34
+M  V30 36 1 31 35
-M  V30 37 1 26 31
+M  V30 37 1 32 33
-M  V30 38 1 20 18
+M  V30 38 2 35 36
-M  V30 39 1 11 1
+M  V30 39 1 36 34
-M  V30 40 10 16 37
+M  V30 40 10 35 37
-M  V30 41 10 22 37
+M  V30 41 10 6 37
-M  V30 42 10 27 37
+M  V30 42 10 37 11
-M  V30 43 10 33 37
+M  V30 43 10 13 37
-M  V30 44 10 5 37
+M  V30 44 10 37 23
-M  V30 45 10 7 37
+M  V30 45 10 26 37
 M  V30 END BOND
 M  V30 END CTAB

Visible-Light-Driven Photocatalytic CO2 Reduction by a Ni(II) Complex Bearing a Bioinspired Tetradentate Ligand for Selective CO Production: Difference between revisions

Revision as of 16:58, 27 November 2023

Contents

Catalyst

Photosensitizer

Investigation

Sacrificial electron donor

Investigations

Topics

Visible-Light-Driven Photocatalytic CO2 Reduction by a Ni(II) Complex Bearing a Bioinspired Tetradentate Ligand for Selective CO Production: Difference between revisions

Revision as of 16:58, 27 November 2023

Catalyst

Photosensitizer

Investigation

Sacrificial electron donor

Investigations

Current site

Topics