Highly Efficient and Selective Photocatalytic CO2 Reduction by Iron and Cobalt Quaterpyridine Complexes: Difference between revisions
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{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Co(qpy)(H2O)2(ClO4)2 and Ru(bpy)3Cl2}} | {{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Co(qpy)(H2O)2(ClO4)2 and Ru(bpy)3Cl2}} | ||
==== Sacrificial electron donor ==== | |||
<chemform smiles="C1C=CC2N(C)C(C3C=CC=CC=3)([H])N(C)C=2C=1" inchi="1S/C15H16N2/c1-16-13-10-6-7-11-14(13)17(2)15(16)12-8-4-3-5-9-12/h3-11,15H,1-2H3" inchikey="VDFIVJSRRJXMAU-UHFFFAOYSA-N" height="200px" width="300px" float="none"> | |||
-INDIGO-08112313242D | |||
0 0 0 0 0 0 0 0 0 0 0 V3000 | |||
M V30 BEGIN CTAB | |||
M V30 COUNTS 18 20 0 0 0 | |||
M V30 BEGIN ATOM | |||
M V30 1 C 5.13485 -5.37507 0.0 0 | |||
M V30 2 C 6.86515 -5.37459 0.0 0 | |||
M V30 3 C 6.00164 -4.87497 0.0 0 | |||
M V30 4 C 6.86515 -6.37553 0.0 0 | |||
M V30 5 C 5.13485 -6.38002 0.0 0 | |||
M V30 6 C 6.00382 -6.87503 0.0 0 | |||
M V30 7 N 7.81713 -5.06522 0.0 0 | |||
M V30 8 C 8.40549 -5.87499 0.0 0 | |||
M V30 9 N 7.81712 -6.6848 0.0 0 | |||
M V30 10 H 9.27151 -5.37499 0.0 0 | |||
M V30 11 C 9.27151 -6.37499 0.0 0 | |||
M V30 12 C 11.0018 -6.37334 0.0 0 | |||
M V30 13 C 10.138 -5.8743 0.0 0 | |||
M V30 14 C 11.0025 -7.37429 0.0 0 | |||
M V30 15 C 9.27219 -7.37994 0.0 0 | |||
M V30 16 C 10.1415 -7.87437 0.0 0 | |||
M V30 17 C 8.12611 -4.11415 0.0 0 | |||
M V30 18 C 8.12615 -7.63585 0.0 0 | |||
M V30 END ATOM | |||
M V30 BEGIN BOND | |||
M V30 1 2 3 1 | |||
M V30 2 2 4 2 | |||
M V30 3 1 1 5 | |||
M V30 4 1 2 3 | |||
M V30 5 2 5 6 | |||
M V30 6 1 6 4 | |||
M V30 7 1 2 7 | |||
M V30 8 1 7 8 | |||
M V30 9 1 8 9 | |||
M V30 10 1 9 4 | |||
M V30 11 1 8 10 | |||
M V30 12 1 8 11 | |||
M V30 13 2 13 11 | |||
M V30 14 2 14 12 | |||
M V30 15 1 11 15 | |||
M V30 16 1 12 13 | |||
M V30 17 2 15 16 | |||
M V30 18 1 16 14 | |||
M V30 19 1 7 17 | |||
M V30 20 1 9 18 | |||
M V30 END BOND | |||
M V30 END CTAB | |||
M END | |||
</chemform> | |||
Revision as of 12:24, 11 August 2023
====
====
Catalysts
[Fe(qpy)(H2O)2][ClO4]2
[Co(qpy)(H2O)2][ClO4]2
Co(ClO4)2
Photosensitizers
Investigations
Investigation-Name: Co(qpy)(H2O)2(ClO4)2 and Ru(bpy)3Cl2
Sacrificial electron donor
Investigations
- Optimizations of conditions for Co(qpy)(H2O)2(ClO4)2 and Ru(bpy)3Cl2 (Molecular process, Photocatalytic CO2 conversion experiments)
- Optimizations of conditions for Co(qpy)(H2O)2(ClO4)2 and purpurin (Molecular process, Photocatalytic CO2 conversion experiments)
- Optimizations of conditions for Fe(qpy)(H2O)2(ClO4)2 (Molecular process, Photocatalytic CO2 conversion experiments)
- Optimizations of conditions for Fe(qpy)(H2O)2(ClO4)2 and Ru(bpy)3Cl2 (Molecular process, Photocatalytic CO2 conversion experiments)
