Highly Efficient and Selective Photocatalytic CO2 Reduction by Iron and Cobalt Quaterpyridine Complexes: Difference between revisions

Revision as of 11:49, 11 August 2023

Catalyst

[Fe(qpy)(H2O)2][ClO4]2

Photosensitizer

Ru(bpy)3Cl2

Investigations

Optimizations of conditions for Co(qpy)(H2O)2(ClO4)2 and Ru(bpy)3Cl2 (Molecular process, Photocatalytic CO2 conversion experiments)
Optimizations of conditions for Co(qpy)(H2O)2(ClO4)2 and purpurin (Molecular process, Photocatalytic CO2 conversion experiments)
Optimizations of conditions for Fe(qpy)(H2O)2(ClO4)2 (Molecular process, Photocatalytic CO2 conversion experiments)
Optimizations of conditions for Fe(qpy)(H2O)2(ClO4)2 and Ru(bpy)3Cl2 (Molecular process, Photocatalytic CO2 conversion experiments)

DOI	10.1021/jacs.6b06002
Authors	Zhenguo Guo, Siwei Cheng, Claudio Cometto, Elodie Anxolabéhère-Mallart, Siu-Mui Ng, Chi-Chiu Ko, Guijian Liu, Lingjing Chen, Marc Robert, Tai-Chu Lau,
Submitted	22.07.2016
Published online	26.07.2016
Licenses	-
Subjects	Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
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@@ Line 2: / Line 2: @@
 [[Category:Photocatalytic CO2 conversion to CO]]
 {{BaseTemplate}}
+==== Catalyst ====
+<chemform smiles="C1C2C3C=CC=C4C5C=CC=C6C7C=CC=CN=7[Fe+2](O)(O)(N=34)(N=56)N=2C=CC=1.Cl([O-])(=O)(=O)=O.Cl([O-])(=O)(=O)=O" inchi="1S/C20H14N4.2ClHO4.Fe.2H2O/c1-3-13-21-15(7-1)17-9-5-11-19(23-17)20-12-6-10-18(24-20)16-8-2-4-14-22-16;2*2-1(3,4)5;;;/h1-14H;2*(H,2,3,4,5);;2*1H2/q;;;+2;;/p-2" inchikey="NLKWUAXOGCKGEY-UHFFFAOYSA-L" height="200px" width="300px" float="none">
+  -INDIGO-08112312452D
+  0  0  0  0  0  0  0  0  0  0 V3000
+M  V30 BEGIN CTAB
+M  V30 COUNTS 37 41 0 0 0
+M  V30 BEGIN ATOM
+M  V30 1 C 6.83485 -2.97507 0.0 0
+M  V30 2 C 8.56515 -2.97459 0.0 0
+M  V30 3 C 7.70164 -2.47497 0.0 0
+M  V30 4 C 8.56515 -3.97553 0.0 0
+M  V30 5 C 6.83485 -3.98002 0.0 0
+M  V30 6 N 7.70382 -4.47503 0.0 0
+M  V30 7 C 5.97028 -4.48253 0.0 0
+M  V30 8 C 5.1109 -5.98433 0.0 0
+M  V30 9 N 5.97356 -5.48323 0.0 0
+M  V30 10 C 4.24227 -5.48695 0.0 0
+M  V30 11 C 5.09818 -3.98316 0.0 0
+M  V30 12 C 4.23681 -4.49128 0.0 0
+M  V30 13 C 5.114 -6.98432 0.0 0
+M  V30 14 C 5.98521 -8.47929 0.0 0
+M  V30 15 N 5.98238 -7.48166 0.0 0
+M  V30 16 C 5.12026 -8.98303 0.0 0
+M  V30 17 C 4.24559 -7.49007 0.0 0
+M  V30 18 C 4.25515 -8.4901 0.0 0
+M  V30 19 C 6.85288 -8.97643 0.0 0
+M  V30 20 C 8.58317 -8.96906 0.0 0
+M  V30 21 N 7.71768 -8.47288 0.0 0
+M  V30 22 C 8.58715 -9.97 0.0 0
+M  V30 23 C 6.85688 -9.98136 0.0 0
+M  V30 24 C 7.72781 -10.4729 0.0 0
+M  V30 25 Fe 7.72882 -6.42503 0.0 0 CHG=2
+M  V30 26 O 9.04485 -5.57503 0.0 0
+M  V30 27 O 9.11985 -7.27503 0.0 0
+M  V30 28 Cl 11.8 -4.275 0.0 0
+M  V30 29 O 10.8 -4.275 0.0 0
+M  V30 30 O 11.8088 -3.28407 0.0 0
+M  V30 31 O 12.8659 -4.28382 0.0 0
+M  V30 32 O 11.8 -5.275 0.0 0 CHG=-1
+M  V30 33 Cl 11.88 -7.54538 0.0 0
+M  V30 34 O 10.8629 -7.54538 0.0 0
+M  V30 35 O 11.889 -6.53745 0.0 0
+M  V30 36 O 12.8621 -7.55478 0.0 0
+M  V30 37 O 11.88 -8.56255 0.0 0 CHG=-1
+M  V30 END ATOM
+M  V30 BEGIN BOND
+M  V30 1 2 3 1
+M  V30 2 2 4 2
+M  V30 3 1 1 5
+M  V30 4 1 2 3
+M  V30 5 2 5 6
+M  V30 6 1 6 4
+M  V30 7 1 5 7
+M  V30 8 2 9 7
+M  V30 9 2 10 8
+M  V30 10 1 7 11
+M  V30 11 1 8 9
+M  V30 12 2 11 12
+M  V30 13 1 12 10
+M  V30 14 1 8 13
+M  V30 15 2 15 13
+M  V30 16 2 16 14
+M  V30 17 1 13 17
+M  V30 18 1 14 15
+M  V30 19 2 17 18
+M  V30 20 1 18 16
+M  V30 21 1 14 19
+M  V30 22 2 21 19
+M  V30 23 2 22 20
+M  V30 24 1 19 23
+M  V30 25 1 20 21
+M  V30 26 2 23 24
+M  V30 27 1 24 22
+M  V30 28 10 6 25
+M  V30 29 10 25 21
+M  V30 30 10 15 25
+M  V30 31 10 25 9
+M  V30 32 10 25 26
+M  V30 33 10 25 27
+M  V30 34 2 28 29
+M  V30 35 2 28 30
+M  V30 36 2 28 31
+M  V30 37 1 28 32
+M  V30 38 2 33 34
+M  V30 39 2 33 35
+M  V30 40 2 33 36
+M  V30 41 1 33 37
+M  V30 END BOND
+M  V30 END CTAB
+M  END
+</chemform>
+==== Photosensitizer ====
+<chemform smiles="C1C2C3C=CC=CN=3[Ru+2]3(N4C=CC=CC=4C4N3=CC=CC=4)3(N4C=CC=CC=4C4N3=CC=CC=4)N=2C=CC=1.[Cl-].[Cl-]" inchi="1S/3C10H8N2.2ClH.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;;;/h3*1-8H;2*1H;/q;;;;;+2/p-2" inchikey="SJFYGUKHUNLZTK-UHFFFAOYSA-L" height="200px" width="300px" float="none">
+  -INDIGO-08112312492D
+  0  0  0  0  0  0  0  0  0  0 V3000
+M  V30 BEGIN CTAB
+M  V30 COUNTS 39 45 0 0 0
+M  V30 BEGIN ATOM
+M  V30 1 C 7.18485 -2.40007 0.0 0
+M  V30 2 C 8.91515 -2.39959 0.0 0
+M  V30 3 C 8.05164 -1.89997 0.0 0
+M  V30 4 C 8.91515 -3.40053 0.0 0
+M  V30 5 C 7.18485 -3.40502 0.0 0
+M  V30 6 N 8.05382 -3.90003 0.0 0
+M  V30 7 C 6.32028 -3.90753 0.0 0
+M  V30 8 C 5.4609 -5.40933 0.0 0
+M  V30 9 N 6.32356 -4.90824 0.0 0
+M  V30 10 C 4.59227 -4.91195 0.0 0
+M  V30 11 C 5.44818 -3.40816 0.0 0
+M  V30 12 C 4.58681 -3.91628 0.0 0
+M  V30 13 C 5.464 -6.40932 0.0 0
+M  V30 14 C 6.33521 -7.90429 0.0 0
+M  V30 15 N 6.33238 -6.90666 0.0 0
+M  V30 16 C 5.47026 -8.40803 0.0 0
+M  V30 17 C 4.59559 -6.91507 0.0 0
+M  V30 18 C 4.60515 -7.9151 0.0 0
+M  V30 19 C 7.20288 -8.40143 0.0 0
+M  V30 20 C 8.93317 -8.39406 0.0 0
+M  V30 21 N 8.06768 -7.89788 0.0 0
+M  V30 22 C 8.93715 -9.39499 0.0 0
+M  V30 23 C 7.20688 -9.40636 0.0 0
+M  V30 24 C 8.07781 -9.89792 0.0 0
+M  V30 25 C 9.79743 -7.89102 0.0 0
+M  V30 26 C 10.6559 -6.38869 0.0 0
+M  V30 27 N 9.79354 -6.89032 0.0 0
+M  V30 28 C 11.5248 -6.88554 0.0 0
+M  V30 29 C 10.6698 -8.38985 0.0 0
+M  V30 30 C 11.5309 -7.8812 0.0 0
+M  V30 31 C 10.6522 -5.3887 0.0 0
+M  V30 32 C 9.78004 -3.89427 0.0 0
+M  V30 33 N 9.78349 -4.8919 0.0 0
+M  V30 34 C 10.6447 -3.39 0.0 0
+M  V30 35 C 11.5203 -4.88241 0.0 0
+M  V30 36 C 11.5101 -3.88239 0.0 0
+M  V30 37 Ru 8.05382 -5.85003 0.0 0 CHG=2
+M  V30 38 Cl 10.05 -2.325 0.0 0 CHG=-1
+M  V30 39 Cl 3.975 -5.9 0.0 0 CHG=-1
+M  V30 END ATOM
+M  V30 BEGIN BOND
+M  V30 1 2 3 1
+M  V30 2 2 4 2
+M  V30 3 1 1 5
+M  V30 4 1 2 3
+M  V30 5 2 5 6
+M  V30 6 1 6 4
+M  V30 7 1 5 7
+M  V30 8 2 9 7
+M  V30 9 2 10 8
+M  V30 10 1 7 11
+M  V30 11 1 8 9
+M  V30 12 2 11 12
+M  V30 13 1 12 10
+M  V30 14 2 15 13
+M  V30 15 2 16 14
+M  V30 16 1 13 17
+M  V30 17 1 14 15
+M  V30 18 2 17 18
+M  V30 19 1 18 16
+M  V30 20 1 14 19
+M  V30 21 2 21 19
+M  V30 22 2 22 20
+M  V30 23 1 19 23
+M  V30 24 1 20 21
+M  V30 25 2 23 24
+M  V30 26 1 24 22
+M  V30 27 2 27 25
+M  V30 28 2 28 26
+M  V30 29 1 25 29
+M  V30 30 1 26 27
+M  V30 31 2 29 30
+M  V30 32 1 30 28
+M  V30 33 1 26 31
+M  V30 34 2 33 31
+M  V30 35 2 34 32
+M  V30 36 1 31 35
+M  V30 37 1 32 33
+M  V30 38 2 35 36
+M  V30 39 1 36 34
+M  V30 40 10 6 37
+M  V30 41 10 37 9
+M  V30 42 10 15 37
+M  V30 43 10 37 21
+M  V30 44 10 27 37
+M  V30 45 10 37 33
+M  V30 END BOND
+M  V30 END CTAB
+M  END
+</chemform>

Highly Efficient and Selective Photocatalytic CO2 Reduction by Iron and Cobalt Quaterpyridine Complexes: Difference between revisions

Revision as of 11:49, 11 August 2023

Catalyst

Photosensitizer

Investigations

Current site

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