Visible-Light-Driven Photocatalytic CO2 Reduction by a Ni(II) Complex Bearing a Bioinspired Tetradentate Ligand for Selective CO Production: Difference between revisions

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DOI 10.1021/jacs.7b01956
Authors Dachao Hong, Yuto Tsukakoshi, Hiroaki Kotani, Tomoya Ishizuka, Takahiko Kojima,
Submitted 28.04.2017
Published online 04.05.2017
Licenses -
Subjects Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
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(Added molecules)
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{{#doiinfobox: 10.1021/jacs.7b01956}}
{{#doiinfobox: 10.1021/jacs.7b01956}}


==== Investigation ====
==== Catalyst====
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}}
{{#moleculelink:|link=YWLPEVCCGUVAOP-UHFFFAOYSA-N|image=true}}
 
==== Catalyst ====
<chemform smiles="" inchi="" inchikey="YWLPEVCCGUVAOP-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform>


==== Photosensitizer ====
====Photosensitizer====
<chemform smiles="C12C3=CC=CC=N3[Ru+2](N1=CC=CC=2)1(N2C=CC=CC=2C2N1=CC=CC=2)1N2C=CC=CC=2C2N1=CC=CC=2" inchi="1S/3C10H8N2.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;/h3*1-8H;/q;;;+2" inchikey="HNVRWFFXWFXICS-UHFFFAOYSA-N" height="200px" width="300px" float="none">
<chemform smiles="C12C3=CC=CC=N3[Ru+2](N1=CC=CC=2)1(N2C=CC=CC=2C2N1=CC=CC=2)1N2C=CC=CC=2C2N1=CC=CC=2" inchi="1S/3C10H8N2.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;/h3*1-8H;/q;;;+2" inchikey="HNVRWFFXWFXICS-UHFFFAOYSA-N" height="200px" width="300px" float="none">
   -INDIGO-02012310412D
   -INDIGO-02012310412D
Line 105: Line 102:
</chemform>
</chemform>


==== Sacrificial electron donor ====
====Investigation====
<chemform smiles="" inchi="" inchikey="VDFIVJSRRJXMAU-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform><chemform smiles="" inchi="" inchikey="ZMANZCXQSJIPKH-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform><chemform smiles="" inchi="" inchikey="GSEJCLTVZPLZKY-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform>
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}}
 
====Sacrificial electron donor====
{{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=true}}{{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=true}}{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=true}}
[[Category:Photocatalytic CO2 conversion to CO]]
[[Category:Photocatalytic CO2 conversion to CO]]

Revision as of 09:44, 7 July 2023


Catalyst

Molecule with key YWLPEVCCGUVAOP-UHFFFAOYSA-N does not exist.

Photosensitizer

Ru(bpy)3

Investigation

catcat conc [µM]PSPS conc [mM]e-De-D conc [M]solvent A...λexc [nm].TON CO.TON H2..
1.

[Ni(bpet)(MeCN)2][ClO4]2

0.03

Ru(bpy)3Cl2

0.5

BIH

0.1

DMA

4507136.9
2.

[Ni(bpet)(MeCN)2][ClO4]2

0.03

Ru(bpy)3Cl2

0.5

BIH

0.1

DMF

45015911
3.

[Ni(bpet)(MeCN)2][ClO4]2

0.03

Ru(bpy)3Cl2

0.5

BIH

0.1

DMA

450673.4
4.

[Ni(bpet)(MeCN)2][ClO4]2

0.03

Ru(bpy)3Cl2

0.5

BIH

0.1

MeCN

450
5.

[Ni(bpet)(MeCN)2][ClO4]2

0.03

Ru(bpy)3Cl2

0.5

TEA

0.1

DMA

450
6.

[Ni(bpet)(MeCN)2][ClO4]2

0.03

Ru(bpy)3Cl2

0.5

TEOA

0.1

DMA

4502.625.5
Investigation-Name: Table 1

Sacrificial electron donor

BIHTEATEOA

Investigations

  • Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)