Phenoxazine-Sensitized CO2-to-CO Reduction with an Iron Porphyrin Catalyst: A Redox Properties-Catalytic Performance Study: Difference between revisions

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DOI 10.1002/cptc.202200009
Authors Martin Kientz, Grace Lowe, Blaine G. McCarthy, Garret M. Miyake, Julien Bonin, Marc Robert,
Submitted 11.03.2022
Published online 29.03.2022
Licenses http://creativecommons.org/licenses/by/4.0/, http://doi.wiley.com/10.1002/tdm_license_1.1,
Subjects Organic Chemistry, Physical and Theoretical Chemistry, Analytical Chemistry
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(Added molecule links and investigation)
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[[Category:Photocatalytic CO2 conversion to CO]]
[[Category:Photocatalytic CO2 conversion to CO]]
{{BaseTemplate}}
{{BaseTemplate}}
====Catalyst====
<chemform smiles="" inchi="" inchikey="MXOBCRHAQPLEER-YUTFXDKVSA-N" height="200px" width="300px" float="none"></chemform>{{#moleculelink:|link=MXOBCRHAQPLEER-YUTFXDKVSA-N|image=true}}
====Photosensitizer====
{{#moleculelink:|link=IGGSSEOAGCUGDJ-UHFFFAOYSA-N|image=true}} {{#moleculelink:|link=WKYXCCICHXAEHL-UHFFFAOYSA-N|image=true}}{{#moleculelink:|link=HDOFYEULLIFSQY-UHFFFAOYSA-N|image=true}}{{#moleculelink:|link=ZIGQSGYNHLDFOD-UHFFFAOYSA-N|image=true}}{{#moleculelink:|link=JUDLWUDCWSBXOA-UHFFFAOYSA-N|image=true}}{{#moleculelink:|link=JLXPQUVLGFUEHE-UHFFFAOYSA-N|image=true}}
====Investigation====
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}}
====Further Information====

Revision as of 09:17, 28 June 2023


Catalyst

Molecule with key MXOBCRHAQPLEER-YUTFXDKVSA-N does not exist.

Photosensitizer

3,7-Di((1,1'-biphenyl)-4-yl)-10-(naphthalen-1-yl)-10H-phenoxazine 1007611007621007634-[7-[4-(diphenylamino)phenyl]-10-naphthalen-2-yl-phenoxazin-3-yl]-N,N-diphenyl-aniline10-naphthalen-2-yl-3,7-di(pyren-1-yl)phenoxazine

Investigation

catcat conc [µM]PSPS conc [mM]e-De-D conc [M]solvent Aadditives.λexc [nm].TON COTON H2.
1.

[Fe(pTMAPP)Cl][PF6]4

0.002

Molecule:100493

0.2

BIH

0.005

MeCN

TFE> 40010325
2.

[Fe(pTMAPP)Cl][PF6]4

0.002

Molecule:100761

0.2

BIH

0.005

MeCN

TFE> 4008812
3.

[Fe(pTMAPP)Cl][PF6]4

0.002

Molecule:100762

0.2

BIH

0.005

MeCN

TFE> 400115
4.

[Fe(pTMAPP)Cl][PF6]4

0.002

Molecule:100763

0.2

BIH

0.005

MeCN

TFE> 40011212
5.

[Fe(pTMAPP)Cl][PF6]4

0.002

Molecule:100764

0.2

BIH

0.005

MeCN

TFE> 4003257
6.

[Fe(pTMAPP)Cl][PF6]4

0.002

Molecule:100765

0.2

BIH

0.005

MeCN

TFE> 40089
Investigation-Name: Table 1

Further Information

Investigations

  • Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)