Visible light driven reduction of CO2 catalyzed by an abundant manganese catalyst with zinc porphyrin photosensitizer: Difference between revisions

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DOI 10.1016/j.apcata.2016.04.035
Authors Jun-Xiao Zhang, Chang-Ying Hu, Wei Wang, Hui Wang, Zhao-Yong Bian,
Submitted 08.05.2016
Licenses https://www.elsevier.com/tdm/userlicense/1.0/,
Subjects Process Chemistry and Technology, Catalysis
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(Added investigation)
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Line 65: Line 65:


==== Photosensitizer ====
==== Photosensitizer ====
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   -INDIGO-05172313292D
   -INDIGO-05172313542D


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  -INDIGO-05172313322D
 
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M  V30 END CTAB

Revision as of 12:54, 17 May 2023


Investigation

catcat conc [µM]PSPS conc [mM]e-De-D conc [M]solvent A..λexc [nm].TON COTON HCOOH.
1.

Mn(bpy)(CO)3Br

2

ZnTPP

0.5

TEA

0.1

MeCN

xenon lamp11919
2.

Mn(bpy)(CO)3Br

1.5

ZnTPP

0.5

TEA

0.1

MeCN

xenon lamp9718
3.

Mn(bpy)(CO)3Br

0.5

ZnTPP

0.25

TEA

0.1

MeCN

xenon lamp6416
4.

Mn(bpy)(CO)3Br

0.5

ZnTPP

0.5

TEA

0.1

MeCN

xenon lamp1210
5.

Mn(bpy)(CO)3Br

0.5

ZnTPP

1

TEA

0.1

MeCN

xenon lamp86
6.

Mn(bpy)(CO)3Br

0.5


TEA

0.1

MeCN

xenon lamp21
7.


ZnTPP

0.5

TEA

0.1

MeCN

xenon lamp
Investigation-Name: Table 1

Catalyst

Mn(bpy)(CO)3Br

Photosensitizer

ZnTPP

Sacrificial electron donor

TEA

Investigations

  • Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)
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