Visible light driven reduction of CO2 catalyzed by an abundant manganese catalyst with zinc porphyrin photosensitizer: Difference between revisions

Revision as of 12:42, 17 May 2023

Investigation

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	λexc [nm]	TON CO	TON HCOOH
1.	Mn(bpy)(CO)3Br	2	ZnTPP	0.5	TEA	0.1	MeCN	xenon lamp	119	19
2.	Mn(bpy)(CO)3Br	1.5	ZnTPP	0.5	TEA	0.1	MeCN	xenon lamp	97	18
3.	Mn(bpy)(CO)3Br	0.5	ZnTPP	0.25	TEA	0.1	MeCN	xenon lamp	64	16
4.	Mn(bpy)(CO)3Br	0.5	ZnTPP	0.5	TEA	0.1	MeCN	xenon lamp	12	10
5.	Mn(bpy)(CO)3Br	0.5	ZnTPP	1	TEA	0.1	MeCN	xenon lamp	8	6
6.	Mn(bpy)(CO)3Br	0.5			TEA	0.1	MeCN	xenon lamp	2	1
7.			ZnTPP	0.5	TEA	0.1	MeCN	xenon lamp

Investigation-Name: Table 1

Investigations

Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)

DOI	10.1016/j.apcata.2016.04.035
Authors	Jun-Xiao Zhang, Chang-Ying Hu, Wei Wang, Hui Wang, Zhao-Yong Bian,
Submitted	08.05.2016
Licenses	https://www.elsevier.com/tdm/userlicense/1.0/,
Subjects	Process Chemistry and Technology, Catalysis
Go to literature page

@@ Line 5: / Line 5: @@
 ==== Investigation ====
+{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}}
 ==== Catalyst ====
@@ Line 182: / Line 183: @@
 M  V30 59 10 15 49
 M  V30 60 10 21 49
+M  V30 END BOND
+M  V30 END CTAB
+M  END
+</chemform><chemform smiles="C1=C2C(C3C=CC=CC=3)=C3N4[Zn+2]56[N-]7C(=C(C8C=CC=CC=8)C=4C=C3)C=CC7=C(C3C=CC=CC=3)C3=N5C(=C(C4C=CC=CC=4)C(=C1)[N-]26)C=C3" inchi="1S/C44H28N4.Zn/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36;/h1-28H;/q-2;+2/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-;" inchikey="XPVVGUHKLPZAEN-DAJBKUBHSA-N" height="200px" width="300px" float="none">
+  -INDIGO-05172313322D
+  0  0  0  0  0  0  0  0  0  0 V3000
+M  V30 BEGIN CTAB
+M  V30 COUNTS 49 60 0 0 0
+M  V30 BEGIN ATOM
+M  V30 1 C 4.26444 -2.19264 0.0 0
+M  V30 2 N 4.95066 -3.60797 0.0 0 CHG=-1
+M  V30 3 C 5.13521 -2.6936 0.0 0
+M  V30 4 C 3.97264 -3.70955 0.0 0
+M  V30 5 C 3.534 -2.85356 0.0 0
+M  V30 6 C 8.00662 -2.02009 0.0 0
+M  V30 7 C 8.51658 -3.52705 0.0 0
+M  V30 8 C 8.82814 -2.59525 0.0 0
+M  V30 9 N 7.4976 -3.55292 0.0 0
+M  V30 10 C 7.19098 -2.61274 0.0 0
+M  V30 11 N 5.15903 -5.24596 0.0 0
+M  V30 12 C 4.67909 -6.74346 0.0 0
+M  V30 13 C 5.47557 -6.15555 0.0 0
+M  V30 14 C 3.86667 -6.18575 0.0 0
+M  V30 15 C 4.14196 -5.291 0.0 0
+M  V30 16 N 7.74715 -5.30724 0.0 0 CHG=-1
+M  V30 17 C 9.09989 -6.11388 0.0 0
+M  V30 18 C 8.67727 -5.20374 0.0 0
+M  V30 19 C 8.35684 -6.73786 0.0 0
+M  V30 20 C 7.47905 -6.1624 0.0 0
+M  V30 21 C 3.54011 -4.53811 0.0 0
+M  V30 22 C 6.51552 -6.63012 0.0 0
+M  V30 23 C 9.15199 -4.36492 0.0 0
+M  V30 24 C 6.13275 -2.19316 0.0 0
+M  V30 25 C 6.51552 -7.63012 0.0 0
+M  V30 26 C 7.38209 -9.12778 0.0 0
+M  V30 27 C 7.38235 -8.13015 0.0 0
+M  V30 28 C 6.51559 -9.62883 0.0 0
+M  V30 29 C 5.64555 -8.13318 0.0 0
+M  V30 30 C 5.65201 -9.13323 0.0 0
+M  V30 31 C 2.54011 -4.53811 0.0 0
+M  V30 32 C 1.04245 -5.40469 0.0 0
+M  V30 33 C 2.04009 -5.40495 0.0 0
+M  V30 34 C 0.541399 -4.53818 0.0 0
+M  V30 35 C 2.03706 -3.66814 0.0 0
+M  V30 36 C 1.037 -3.67461 0.0 0
+M  V30 37 C 10.152 -4.36492 0.0 0
+M  V30 38 C 11.6496 -3.49834 0.0 0
+M  V30 39 C 10.652 -3.49808 0.0 0
+M  V30 40 C 12.1507 -4.36485 0.0 0
+M  V30 41 C 10.655 -5.23489 0.0 0
+M  V30 42 C 11.6551 -5.22843 0.0 0
+M  V30 43 C 6.13275 -1.19316 0.0 0
+M  V30 44 C 5.26618 0.304505 0.0 0
+M  V30 45 C 5.26592 -0.693131 0.0 0
+M  V30 46 C 6.13268 0.805557 0.0 0
+M  V30 47 C 7.00272 -0.690101 0.0 0
+M  V30 48 C 6.99626 0.309953 0.0 0
+M  V30 49 Zn 6.4 -4.475 0.0 0 CHG=2
+M  V30 END ATOM
+M  V30 BEGIN BOND
+M  V30 1 1 1 5
+M  V30 2 1 2 3
+M  V30 3 2 3 1
+M  V30 4 1 4 2
+M  V30 5 2 5 4
+M  V30 6 1 6 10
+M  V30 7 1 7 8
+M  V30 8 2 8 6
+M  V30 9 2 9 7
+M  V30 10 1 10 9
+M  V30 11 1 11 15
+M  V30 12 1 12 13
+M  V30 13 2 13 11
+M  V30 14 2 14 12
+M  V30 15 1 15 14
+M  V30 16 1 16 20
+M  V30 17 1 17 18
+M  V30 18 1 18 16
+M  V30 19 2 19 17
+M  V30 20 1 20 19
+M  V30 21 1 4 21
+M  V30 22 2 21 15
+M  V30 23 1 13 22
+M  V30 24 2 22 20
+M  V30 25 2 18 23
+M  V30 26 1 23 7
+M  V30 27 2 10 24
+M  V30 28 1 24 3
+M  V30 29 1 22 25
+M  V30 30 2 27 25
+M  V30 31 2 28 26
+M  V30 32 1 25 29
+M  V30 33 1 26 27
+M  V30 34 2 29 30
+M  V30 35 1 30 28
+M  V30 36 1 21 31
+M  V30 37 2 33 31
+M  V30 38 2 34 32
+M  V30 39 1 31 35
+M  V30 40 1 32 33
+M  V30 41 2 35 36
+M  V30 42 1 36 34
+M  V30 43 1 23 37
+M  V30 44 2 39 37
+M  V30 45 2 40 38
+M  V30 46 1 37 41
+M  V30 47 1 38 39
+M  V30 48 2 41 42
+M  V30 49 1 42 40
+M  V30 50 1 24 43
+M  V30 51 2 45 43
+M  V30 52 2 46 44
+M  V30 53 1 43 47
+M  V30 54 1 44 45
+M  V30 55 2 47 48
+M  V30 56 1 48 46
+M  V30 57 10 2 49
+M  V30 58 10 11 49
+M  V30 59 10 16 49
+M  V30 60 10 9 49
 M  V30 END BOND
 M  V30 END CTAB

Visible light driven reduction of CO2 catalyzed by an abundant manganese catalyst with zinc porphyrin photosensitizer: Difference between revisions

Revision as of 12:42, 17 May 2023

Contents

Investigation

Catalyst

Photosensitizer

Sacrificial electron donor

Investigations

Topics

Visible light driven reduction of CO2 catalyzed by an abundant manganese catalyst with zinc porphyrin photosensitizer: Difference between revisions

Revision as of 12:42, 17 May 2023

Investigation

Catalyst

Photosensitizer

Sacrificial electron donor

Investigations

Current site

Topics