Visible light driven reduction of CO2 catalyzed by an abundant manganese catalyst with zinc porphyrin photosensitizer: Difference between revisions

From ChemWiki
publication
About
DOI 10.1016/j.apcata.2016.04.035
Authors Jun-Xiao Zhang, Chang-Ying Hu, Wei Wang, Hui Wang, Zhao-Yong Bian,
Submitted 08.05.2016
Licenses https://www.elsevier.com/tdm/userlicense/1.0/,
Subjects Process Chemistry and Technology, Catalysis
Go to literature page
(Added molecules)
No edit summary
Line 64: Line 64:


==== Photosensitizer ====
==== Photosensitizer ====
<chemform smiles="C1=C2C(C3C=CC=CC=3)=C3C=CC4C(C5C=CC=CC=5)=C5C=CC6N5~[Zn]5(N7C(C=CC=7C=6C6C=CC=CC=6)=C(C6C=CC=CC=6)C(=C1)N2~5)N3=4" inchi="1S/C44H28N4.Zn/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36;/h1-28H;/q-2;+2/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-;" inchikey="XPVVGUHKLPZAEN-DAJBKUBHSA-N" height="200px" width="300px" float="none">
<chemform smiles="C1=C2C(C3C=CC=CC=3)=C3C=CC4C(C5C=CC=CC=5)=C5C=CC6[N-]5[Zn+2]5(N7C(C=CC=7C=6C6C=CC=CC=6)=C(C6C=CC=CC=6)C(=C1)[N-]25)N3=4" inchi="1S/C44H28N4.Zn/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36;/h1-28H;/q-2;+2/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-;" inchikey="XPVVGUHKLPZAEN-DAJBKUBHSA-N" height="200px" width="300px" float="none">
   -INDIGO-05172312002D
   -INDIGO-05172313292D


   0  0  0  0  0  0  0  0  0  0  0 V3000
   0  0  0  0  0  0  0  0  0  0  0 V3000
Line 72: Line 72:
M  V30 BEGIN ATOM
M  V30 BEGIN ATOM
M  V30 1 C 5.61254 -2.65652 0.0 0
M  V30 1 C 5.61254 -2.65652 0.0 0
M  V30 2 N 6.23398 -4.16313 0.0 0
M  V30 2 N 6.23398 -4.16313 0.0 0 CHG=-1
M  V30 3 C 6.44809 -3.19585 0.0 0
M  V30 3 C 6.44809 -3.19585 0.0 0
M  V30 4 C 5.21628 -4.18915 0.0 0
M  V30 4 C 5.21628 -4.18915 0.0 0
Line 91: Line 91:
M  V30 19 C 8.04901 -7.09996 0.0 0
M  V30 19 C 8.04901 -7.09996 0.0 0
M  V30 20 C 9.27506 -6.07169 0.0 0
M  V30 20 C 9.27506 -6.07169 0.0 0
M  V30 21 N 8.26216 -6.12245 0.0 0
M  V30 21 N 8.26216 -6.12245 0.0 0 CHG=-1
M  V30 22 C 9.67079 -6.976 0.0 0
M  V30 22 C 9.67079 -6.976 0.0 0
M  V30 23 C 8.91432 -7.63479 0.0 0
M  V30 23 C 8.91432 -7.63479 0.0 0
Line 119: Line 119:
M  V30 47 C 3.1754 -4.11278 0.0 0
M  V30 47 C 3.1754 -4.11278 0.0 0
M  V30 48 C 2.17535 -4.11924 0.0 0
M  V30 48 C 2.17535 -4.11924 0.0 0
M  V30 49 Zn 7.3 -5.15 0.0 0
M  V30 49 Zn 7.3 -5.15 0.0 0 CHG=2
M  V30 END ATOM
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 BEGIN BOND
Line 179: Line 179:
M  V30 56 1 48 46
M  V30 56 1 48 46
M  V30 57 10 11 49
M  V30 57 10 11 49
M  V30 58 8 2 49
M  V30 58 10 2 49
M  V30 59 10 15 49
M  V30 59 10 15 49
M  V30 60 8 21 49
M  V30 60 10 21 49
M  V30 END BOND
M  V30 END BOND
M  V30 END CTAB
M  V30 END CTAB

Revision as of 12:29, 17 May 2023


Investigation

Catalyst

Mn(bpy)(CO)3Br

Photosensitizer

ZnTPP

Sacrificial electron donor

TEA

Investigations

  • Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)
Retrieved from "https://chemwiki.scc.kit.edu/main/mediawiki/index.php?title=Visible_light_driven_reduction_of_CO2_catalyzed_by_an_abundant_manganese_catalyst_with_zinc_porphyrin_photosensitizer&oldid=3539"
Powered by MediaWiki
Powered by Semantic MediaWiki