Visible light driven reduction of CO2 catalyzed by an abundant manganese catalyst with zinc porphyrin photosensitizer: Difference between revisions

Revision as of 11:01, 17 May 2023

Investigation

Investigations

Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)

DOI	10.1016/j.apcata.2016.04.035
Authors	Jun-Xiao Zhang, Chang-Ying Hu, Wei Wang, Hui Wang, Zhao-Yong Bian,
Submitted	08.05.2016
Licenses	https://www.elsevier.com/tdm/userlicense/1.0/,
Subjects	Process Chemistry and Technology, Catalysis
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@@ Line 3: / Line 3: @@
 [[Category:Photocatalytic CO2 conversion to HCOOH]]
 {{BaseTemplate}}
+==== Investigation ====
+==== Catalyst ====
+<chemform smiles="C1C=C2C3C=CC=CN=3[Mn+]([Br-])([C-]#[O+])([C-]#[O+])([C-]#[O+])N2=CC=1" inchi="1S/C10H8N2.3CO.BrH.Mn/c1-3-7-11-9(5-1)10-6-2-4-8-12-10;3*1-2;;/h1-8H;;;;1H;/q;;;;;+1/p-1" inchikey="ZUZWBGQHMPVNDY-UHFFFAOYSA-M" height="200px" width="300px" float="none">
+  -INDIGO-05172311492D
+  0  0  0  0  0  0  0  0  0  0 V3000
+M  V30 BEGIN CTAB
+M  V30 COUNTS 20 22 0 0 0
+M  V30 BEGIN ATOM
+M  V30 1 C 5.25985 -3.0 0.0 0
+M  V30 2 C 6.99015 -2.99959 0.0 0
+M  V30 3 C 6.12664 -2.49997 0.0 0
+M  V30 4 N 6.99015 -4.00053 0.0 0
+M  V30 5 C 5.25985 -4.00502 0.0 0
+M  V30 6 C 6.12882 -4.50003 0.0 0
+M  V30 7 C 6.12882 -5.50003 0.0 0
+M  V30 8 C 6.9954 -6.99769 0.0 0
+M  V30 9 N 6.99566 -6.0 0.0 0
+M  V30 10 C 6.12889 -7.49875 0.0 0
+M  V30 11 C 5.25885 -6.00309 0.0 0
+M  V30 12 C 5.26531 -7.00314 0.0 0
+M  V30 13 Mn 7.8 -5.075 0.0 0 CHG=1
+M  V30 14 C 7.8 -6.075 0.0 0 CHG=-1
+M  V30 15 C 8.66603 -5.575 0.0 0 CHG=-1
+M  V30 16 C 8.50711 -4.36789 0.0 0 CHG=-1
+M  V30 17 Br 7.8 -4.075 0.0 0 CHG=-1
+M  V30 18 O 7.8 -7.075 0.0 0 CHG=1
+M  V30 19 O 9.53205 -6.075 0.0 0 CHG=1
+M  V30 20 O 9.21421 -3.66079 0.0 0 CHG=1
+M  V30 END ATOM
+M  V30 BEGIN BOND
+M  V30 1 2 3 1
+M  V30 2 2 4 2
+M  V30 3 1 1 5
+M  V30 4 1 2 3
+M  V30 5 2 5 6
+M  V30 6 1 6 4
+M  V30 7 1 6 7
+M  V30 8 2 9 7
+M  V30 9 2 10 8
+M  V30 10 1 7 11
+M  V30 11 1 8 9
+M  V30 12 2 11 12
+M  V30 13 1 12 10
+M  V30 14 10 4 13
+M  V30 15 10 9 13
+M  V30 16 10 13 14
+M  V30 17 10 13 15
+M  V30 18 10 13 16
+M  V30 19 10 13 17
+M  V30 20 3 14 18
+M  V30 21 3 15 19
+M  V30 22 3 16 20
+M  V30 END BOND
+M  V30 END CTAB
+M  END
+</chemform>
+==== Photosensitizer ====
+<chemform smiles="C1=C2C(C3C=CC=CC=3)=C3C=CC4C(C5C=CC=CC=5)=C5C=CC6N5~[Zn]5(N7C(C=CC=7C=6C6C=CC=CC=6)=C(C6C=CC=CC=6)C(=C1)N2~5)N3=4" inchi="1S/C44H28N4.Zn/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36;/h1-28H;/q-2;+2/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-;" inchikey="XPVVGUHKLPZAEN-DAJBKUBHSA-N" height="200px" width="300px" float="none">
+  -INDIGO-05172312002D
+  0  0  0  0  0  0  0  0  0  0 V3000
+M  V30 BEGIN CTAB
+M  V30 COUNTS 49 60 0 0 0
+M  V30 BEGIN ATOM
+M  V30 1 C 5.61254 -2.65652 0.0 0
+M  V30 2 N 6.23398 -4.16313 0.0 0
+M  V30 3 C 6.44809 -3.19585 0.0 0
+M  V30 4 C 5.21628 -4.18915 0.0 0
+M  V30 5 C 4.84504 -3.2858 0.0 0
+M  V30 6 C 7.38981 -2.75305 0.0 0
+M  V30 7 C 8.26724 -3.24384 0.0 0
+M  V30 8 C 9.86373 -3.47337 0.0 0
+M  V30 9 C 9.17288 -2.77554 0.0 0
+M  V30 10 C 9.37127 -4.35416 0.0 0
+M  V30 11 N 8.39033 -4.21187 0.0 0
+M  V30 12 C 4.67846 -4.98275 0.0 0
+M  V30 13 C 5.09553 -5.85045 0.0 0
+M  V30 14 C 6.19158 -6.99506 0.0 0
+M  V30 15 N 6.09375 -6.01034 0.0 0
+M  V30 16 C 5.28627 -7.42502 0.0 0
+M  V30 17 C 4.60036 -6.68583 0.0 0
+M  V30 18 C 7.09741 -7.53612 0.0 0
+M  V30 19 C 8.04901 -7.09996 0.0 0
+M  V30 20 C 9.27506 -6.07169 0.0 0
+M  V30 21 N 8.26216 -6.12245 0.0 0
+M  V30 22 C 9.67079 -6.976 0.0 0
+M  V30 23 C 8.91432 -7.63479 0.0 0
+M  V30 24 C 9.80967 -5.22464 0.0 0
+M  V30 25 C 7.09741 -8.53612 0.0 0
+M  V30 26 C 7.96399 -10.0338 0.0 0
+M  V30 27 C 7.96425 -9.03614 0.0 0
+M  V30 28 C 7.09748 -10.5348 0.0 0
+M  V30 29 C 6.22744 -9.03917 0.0 0
+M  V30 30 C 6.2339 -10.0392 0.0 0
+M  V30 31 C 10.8097 -5.22464 0.0 0
+M  V30 32 C 12.3073 -4.35806 0.0 0
+M  V30 33 C 11.3097 -4.3578 0.0 0
+M  V30 34 C 12.8084 -5.22457 0.0 0
+M  V30 35 C 11.3127 -6.09461 0.0 0
+M  V30 36 C 12.3128 -6.08815 0.0 0
+M  V30 37 C 7.38981 -1.75305 0.0 0
+M  V30 38 C 6.52324 -0.255388 0.0 0
+M  V30 39 C 6.52298 -1.25302 0.0 0
+M  V30 40 C 7.38974 0.245664 0.0 0
+M  V30 41 C 8.25978 -1.24999 0.0 0
+M  V30 42 C 8.25332 -0.24994 0.0 0
+M  V30 43 C 3.67846 -4.98275 0.0 0
+M  V30 44 C 2.1808 -5.84933 0.0 0
+M  V30 45 C 3.17843 -5.84959 0.0 0
+M  V30 46 C 1.67975 -4.98282 0.0 0
+M  V30 47 C 3.1754 -4.11278 0.0 0
+M  V30 48 C 2.17535 -4.11924 0.0 0
+M  V30 49 Zn 7.3 -5.15 0.0 0
+M  V30 END ATOM
+M  V30 BEGIN BOND
+M  V30 1 1 1 5
+M  V30 2 1 2 3
+M  V30 3 2 3 1
+M  V30 4 1 4 2
+M  V30 5 2 5 4
+M  V30 6 1 3 6
+M  V30 7 2 6 7
+M  V30 8 1 7 11
+M  V30 9 2 8 9
+M  V30 10 1 9 7
+M  V30 11 1 10 8
+M  V30 12 2 11 10
+M  V30 13 1 4 12
+M  V30 14 2 12 13
+M  V30 15 1 13 17
+M  V30 16 2 14 15
+M  V30 17 1 15 13
+M  V30 18 1 16 14
+M  V30 19 2 17 16
+M  V30 20 1 14 18
+M  V30 21 2 18 19
+M  V30 22 1 19 23
+M  V30 23 1 20 21
+M  V30 24 1 21 19
+M  V30 25 1 22 20
+M  V30 26 2 23 22
+M  V30 27 1 10 24
+M  V30 28 2 24 20
+M  V30 29 1 18 25
+M  V30 30 2 27 25
+M  V30 31 2 28 26
+M  V30 32 1 25 29
+M  V30 33 1 26 27
+M  V30 34 2 29 30
+M  V30 35 1 30 28
+M  V30 36 1 24 31
+M  V30 37 2 33 31
+M  V30 38 2 34 32
+M  V30 39 1 31 35
+M  V30 40 1 32 33
+M  V30 41 2 35 36
+M  V30 42 1 36 34
+M  V30 43 1 6 37
+M  V30 44 2 39 37
+M  V30 45 2 40 38
+M  V30 46 1 37 41
+M  V30 47 1 38 39
+M  V30 48 2 41 42
+M  V30 49 1 42 40
+M  V30 50 1 12 43
+M  V30 51 2 45 43
+M  V30 52 2 46 44
+M  V30 53 1 43 47
+M  V30 54 1 44 45
+M  V30 55 2 47 48
+M  V30 56 1 48 46
+M  V30 57 10 11 49
+M  V30 58 8 2 49
+M  V30 59 10 15 49
+M  V30 60 8 21 49
+M  V30 END BOND
+M  V30 END CTAB
+M  END
+</chemform>
+==== Sacrificial electron donor ====
+<chemform smiles="" inchi="" inchikey="ZMANZCXQSJIPKH-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform>

Visible light driven reduction of CO2 catalyzed by an abundant manganese catalyst with zinc porphyrin photosensitizer: Difference between revisions

Revision as of 11:01, 17 May 2023

Contents

Investigation

Catalyst

Photosensitizer

Sacrificial electron donor

Investigations

Topics

Visible light driven reduction of CO2 catalyzed by an abundant manganese catalyst with zinc porphyrin photosensitizer: Difference between revisions

Revision as of 11:01, 17 May 2023

Investigation

Catalyst

Photosensitizer

Sacrificial electron donor

Investigations

Current site

Topics