Visible-Light-Driven Photocatalytic CO2 Reduction by a Ni(II) Complex Bearing a Bioinspired Tetradentate Ligand for Selective CO Production: Difference between revisions

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DOI 10.1021/jacs.7b01956
Authors Dachao Hong, Yuto Tsukakoshi, Hiroaki Kotani, Tomoya Ishizuka, Takahiko Kojima,
Submitted 28.04.2017
Published online 04.05.2017
Licenses -
Subjects Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
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==== Sacrificial electron donor ====
==== Sacrificial electron donor ====
<chemform smiles="" inchi="" inchikey="VDFIVJSRRJXMAU-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform><chemform smiles="C1C=CC2C3C=N([Mn]4(S(C)CCS4C)N4=CC(C([*])=C4)C=2C=1)C=C3[*]" inchi="" inchikey="" height="200px" width="300px" float="none" r1="Me,tBu" r2="OH,Cl">
<chemform smiles="" inchi="" inchikey="VDFIVJSRRJXMAU-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform>
  -INDIGO-02222313462D
 
  0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 COUNTS 25 29 0 0 0
M  V30 BEGIN ATOM
M  V30 1 C 3.71355 -5.05744 0.0 0
M  V30 2 C 5.31073 -5.16167 0.0 0
M  V30 3 C 4.55654 -4.63055 0.0 0
M  V30 4 C 5.2411 -6.16901 0.0 0
M  V30 5 C 3.64387 -6.02786 0.0 0
M  V30 6 C 4.43706 -6.58446 0.0 0
M  V30 7 C 6.24903 -4.74786 0.0 0
M  V30 8 C 6.14096 -6.64897 0.0 0
M  V30 9 N 7.66591 -6.54424 0.0 0
M  V30 10 C 6.84451 -6.13515 0.0 0
M  V30 11 C 7.50689 -7.54626 0.0 0
M  V30 12 C 6.40056 -7.5972 0.0 0
M  V30 13 C 7.67075 -3.93598 0.0 0
M  V30 14 C 6.58818 -3.81891 0.0 0
M  V30 15 N 7.76285 -4.93427 0.0 0
M  V30 16 C 6.91407 -5.32543 0.0 0
M  V30 17 Mn 8.586 -5.732 0.0 0
M  V30 18 S 9.22933 -6.53525 0.0 0
M  V30 19 S 9.32639 -4.91171 0.0 0
M  V30 20 C 10.2279 -5.27893 0.0 0
M  V30 21 C 10.1891 -6.21477 0.0 0
M  V30 22 C 8.95795 -7.47609 0.0 0
M  V30 23 C 9.10819 -3.90303 0.0 0
M  V30 24 R# 5.90056 -8.46322 0.0 0 RGROUPS=(1 2)
M  V30 25 R# 6.08818 -2.95288 0.0 0 RGROUPS=(1 1)
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 2 3 1
M  V30 2 2 4 2
M  V30 3 1 1 5
M  V30 4 1 2 3
M  V30 5 2 5 6
M  V30 6 1 6 4
M  V30 7 1 2 7
M  V30 8 1 4 8
M  V30 9 1 8 12
M  V30 10 2 9 10
M  V30 11 1 10 8
M  V30 12 1 11 9
M  V30 13 2 12 11
M  V30 14 1 7 16
M  V30 15 2 13 14
M  V30 16 1 14 7
M  V30 17 1 15 13
M  V30 18 2 16 15
M  V30 19 10 15 17
M  V30 20 10 9 17
M  V30 21 1 19 20
M  V30 22 1 20 21
M  V30 23 1 21 18
M  V30 24 1 18 22
M  V30 25 1 19 23
M  V30 26 10 19 17
M  V30 27 10 18 17
M  V30 28 1 12 24
M  V30 29 1 14 25
M  V30 END BOND
M  V30 END CTAB
M  END
</chemform>
[[Category:Photocatalytic CO2 conversion to CO]]
[[Category:Photocatalytic CO2 conversion to CO]]

Revision as of 14:32, 22 February 2023


Investigation

catcat conc [µM]PSPS conc [mM]e-De-D conc [M]solvent A...λexc [nm].TON CO.TON H2..
1.

[Ni(bpet)(MeCN)2][ClO4]2

0.03

Ru(bpy)3Cl2

0.5

BIH

0.1

DMA

4507136.9
2.

[Ni(bpet)(MeCN)2][ClO4]2

0.03

Ru(bpy)3Cl2

0.5

BIH

0.1

DMF

45015911
3.

[Ni(bpet)(MeCN)2][ClO4]2

0.03

Ru(bpy)3Cl2

0.5

BIH

0.1

DMA

450673.4
4.

[Ni(bpet)(MeCN)2][ClO4]2

0.03

Ru(bpy)3Cl2

0.5

BIH

0.1

MeCN

450
5.

[Ni(bpet)(MeCN)2][ClO4]2

0.03

Ru(bpy)3Cl2

0.5

TEA

0.1

DMA

450
6.

[Ni(bpet)(MeCN)2][ClO4]2

0.03

Ru(bpy)3Cl2

0.5

TEOA

0.1

DMA

4502.625.5
Investigation-Name: Table 1

Catalyst

Photosensitizer

Ru(bpy)3

Sacrificial electron donor

BIH

Investigations

  • Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)
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