Visible-Light-Driven Photocatalytic CO2 Reduction by a Ni(II) Complex Bearing a Bioinspired Tetradentate Ligand for Selective CO Production: Difference between revisions

Revision as of 13:47, 22 February 2023

Investigation

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	λexc [nm]	TON CO	TON H2
1.	[Ni(bpet)(MeCN)2][ClO4]2	0.03	Ru(bpy)3Cl2	0.5	BIH	0.1	DMA	450	713	6.9
2.	[Ni(bpet)(MeCN)2][ClO4]2	0.03	Ru(bpy)3Cl2	0.5	BIH	0.1	DMF	450	159	11
3.	[Ni(bpet)(MeCN)2][ClO4]2	0.03	Ru(bpy)3Cl2	0.5	BIH	0.1	DMA	450	67	3.4
4.	[Ni(bpet)(MeCN)2][ClO4]2	0.03	Ru(bpy)3Cl2	0.5	BIH	0.1	MeCN	450
5.	[Ni(bpet)(MeCN)2][ClO4]2	0.03	Ru(bpy)3Cl2	0.5	TEA	0.1	DMA	450
6.	[Ni(bpet)(MeCN)2][ClO4]2	0.03	Ru(bpy)3Cl2	0.5	TEOA	0.1	DMA	450	2.6	25.5

Investigation-Name: Table 1

Catalyst

Photosensitizer

Ru(bpy)3

Sacrificial electron donor

BIH

Investigations

Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)

DOI	10.1021/jacs.7b01956
Authors	Dachao Hong, Yuto Tsukakoshi, Hiroaki Kotani, Tomoya Ishizuka, Takahiko Kojima,
Submitted	28.04.2017
Published online	04.05.2017
Licenses	-
Subjects	Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
Go to literature page

@@ Line 106: / Line 106: @@
 ==== Sacrificial electron donor ====
-<chemform smiles="" inchi="" inchikey="VDFIVJSRRJXMAU-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform>
+<chemform smiles="" inchi="" inchikey="VDFIVJSRRJXMAU-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform><chemform smiles="C1C=CC2C3C=N([Mn]4(S(C)CCS4C)N4=CC(C([*])=C4)C=2C=1)C=C3[*]" inchi="" inchikey="" height="200px" width="300px" float="none" r1="Me,tBu" r2="OH,Cl">
+  -INDIGO-02222313462D
+  0  0  0  0  0  0  0  0  0  0 V3000
+M  V30 BEGIN CTAB
+M  V30 COUNTS 25 29 0 0 0
+M  V30 BEGIN ATOM
+M  V30 1 C 3.71355 -5.05744 0.0 0
+M  V30 2 C 5.31073 -5.16167 0.0 0
+M  V30 3 C 4.55654 -4.63055 0.0 0
+M  V30 4 C 5.2411 -6.16901 0.0 0
+M  V30 5 C 3.64387 -6.02786 0.0 0
+M  V30 6 C 4.43706 -6.58446 0.0 0
+M  V30 7 C 6.24903 -4.74786 0.0 0
+M  V30 8 C 6.14096 -6.64897 0.0 0
+M  V30 9 N 7.66591 -6.54424 0.0 0
+M  V30 10 C 6.84451 -6.13515 0.0 0
+M  V30 11 C 7.50689 -7.54626 0.0 0
+M  V30 12 C 6.40056 -7.5972 0.0 0
+M  V30 13 C 7.67075 -3.93598 0.0 0
+M  V30 14 C 6.58818 -3.81891 0.0 0
+M  V30 15 N 7.76285 -4.93427 0.0 0
+M  V30 16 C 6.91407 -5.32543 0.0 0
+M  V30 17 Mn 8.586 -5.732 0.0 0
+M  V30 18 S 9.22933 -6.53525 0.0 0
+M  V30 19 S 9.32639 -4.91171 0.0 0
+M  V30 20 C 10.2279 -5.27893 0.0 0
+M  V30 21 C 10.1891 -6.21477 0.0 0
+M  V30 22 C 8.95795 -7.47609 0.0 0
+M  V30 23 C 9.10819 -3.90303 0.0 0
+M  V30 24 R# 5.90056 -8.46322 0.0 0 RGROUPS=(1 2)
+M  V30 25 R# 6.08818 -2.95288 0.0 0 RGROUPS=(1 1)
+M  V30 END ATOM
+M  V30 BEGIN BOND
+M  V30 1 2 3 1
+M  V30 2 2 4 2
+M  V30 3 1 1 5
+M  V30 4 1 2 3
+M  V30 5 2 5 6
+M  V30 6 1 6 4
+M  V30 7 1 2 7
+M  V30 8 1 4 8
+M  V30 9 1 8 12
+M  V30 10 2 9 10
+M  V30 11 1 10 8
+M  V30 12 1 11 9
+M  V30 13 2 12 11
+M  V30 14 1 7 16
+M  V30 15 2 13 14
+M  V30 16 1 14 7
+M  V30 17 1 15 13
+M  V30 18 2 16 15
+M  V30 19 10 15 17
+M  V30 20 10 9 17
+M  V30 21 1 19 20
+M  V30 22 1 20 21
+M  V30 23 1 21 18
+M  V30 24 1 18 22
+M  V30 25 1 19 23
+M  V30 26 10 19 17
+M  V30 27 10 18 17
+M  V30 28 1 12 24
+M  V30 29 1 14 25
+M  V30 END BOND
+M  V30 END CTAB
+M  END
+</chemform>
 [[Category:Photocatalytic CO2 conversion to CO]]

Visible-Light-Driven Photocatalytic CO2 Reduction by a Ni(II) Complex Bearing a Bioinspired Tetradentate Ligand for Selective CO Production: Difference between revisions

Revision as of 13:47, 22 February 2023

Contents

Investigation

Catalyst

Photosensitizer

Sacrificial electron donor

Investigations

Topics

Visible-Light-Driven Photocatalytic CO2 Reduction by a Ni(II) Complex Bearing a Bioinspired Tetradentate Ligand for Selective CO Production: Difference between revisions

Revision as of 13:47, 22 February 2023

Investigation

Catalyst

Photosensitizer

Sacrificial electron donor

Investigations

Current site

Topics