Exploring the Full Potential of Photocatalytic Carbon Dioxide Reduction Using a Dinuclear Re2Cl2 Complex Assisted by Various Photosensitizers: Difference between revisions

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(Added Investigation and dummy Table 1)
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=== Investigation ===
=== Investigation ===
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}}
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}}
{| class="wikitable"
|+
!
!1
!2
!3
!
!4
!5
!6
!7
!8
!9
!10
!11
!12
!13
|-
|PS
|100496
|100496
|100496
|100496
|100496
|100496
|100496
|100496
|
|100496
|100496
|100496
|100496
|100619
|-
|PS eq.
|1
|1
|1
|1
|1
|1
|1
|1
|
|0.1
|0.25
|0.5
|2
|1
|-
|e-D 1
|BIH
|
|
|
|
|
|
|
|
|
|
|
|
|
|-
|e-D 1 eq.
|
|100
|200
|200
|200
|400
|400
|1000
|200
|200
|200
|200
|1000
|200
|-
|e-D 2
|TEA
|
|
|
|
|
|
|
|
|
|
|
|
|
|-
|e-D 2 eq.
|5 % v/v
|100
|200
|200
|400
|200
|400
|1000
|200
|200
|200
|200
|100
|200
|-
|TON CO
|52
|78
|195
|154
|131
|134
|193
|255
|63
|124
|144
|149
|270
|169
|}
=== Photosensitizer ===
=== Photosensitizer ===
<chemform smiles="C1C(F)=C2C3N(~[Ir]4(~N5C(C6C~4=CC(F)=CC=6F)=CC=CC=5)4(~N5=C(C6C~4=CC(F)=CC=6F)C=CC=C5)~C2=CC=1F)=CC=CC=3" inchi="1S/3C11H7F2N.Ir/c3*12-8-4-5-9(10(13)7-8)11-3-1-2-6-14-11;/h3*1-7H;" inchikey="MOOGSZYNGDRAGN-UHFFFAOYSA-N" height="200px" width="300px" float="none">
<chemform smiles="C1C(F)=C2C3N(~[Ir]4(~N5C(C6C~4=CC(F)=CC=6F)=CC=CC=5)4(~N5=C(C6C~4=CC(F)=CC=6F)C=CC=C5)~C2=CC=1F)=CC=CC=3" inchi="1S/3C11H7F2N.Ir/c3*12-8-4-5-9(10(13)7-8)11-3-1-2-6-14-11;/h3*1-7H;" inchikey="MOOGSZYNGDRAGN-UHFFFAOYSA-N" height="200px" width="300px" float="none">

Revision as of 15:38, 19 January 2023

[EtF21]

Investigation

Investigation-Name: Table 1

Photosensitizer

Ir(dFppy)3 Ir(dFppy)3, Cu(xant)(bcp)

Catalyst

(Re(bpy)(CO)3Cl)2xant ? (Re2Cl2 in publication)

Literature

Investigations