Molecular Catalysis of the Electrochemical and Photochemical Reduction of CO2 with Earth-Abundant Metal Complexes. Selective Production of CO vs HCOOH by Switching of the Metal Center: Difference between revisions
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====Sacrificial electron donor==== | ====Sacrificial electron donor==== | ||
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Revision as of 16:53, 4 January 2024
Catalyst
[Fe(pabop)Cl2][CLO4]
[Co(pabop)][ClO4]2
Photosensitizer
Investigation
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | solvent A | . | . | λexc [nm] | . | TON CO | TON HCOOH | . | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1. | 50 | 0.2 | >460 | 270 | |||||||||
| 2. | 20 | 0.2 | >420 | 5 |
Investigation-Name: Table 1
Sacrificial electron donor
TEA
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Investigations
- Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)
