Phenoxazine-Sensitized CO2-to-CO Reduction with an Iron Porphyrin Catalyst: A Redox Properties-Catalytic Performance Study: Difference between revisions

Revision as of 17:30, 27 November 2023

Catalyst

Photosensitizer

3,7-Di((1,1'-biphenyl)-4-yl)-10-(naphthalen-1-yl)-10H-phenoxazine 100761 100762 100763 4-[7-[4-(diphenylamino)phenyl]-10-naphthalen-2-yl-phenoxazin-3-yl]-N,N-diphenyl-aniline 10-naphthalen-2-yl-3,7-di(pyren-1-yl)phenoxazine

Investigation

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	additives	λexc [nm]	TON CO	TON H2
1.	[Fe(pTMAPP)Cl][PF6]4	0.002	Molecule:100493	0.2	BIH	0.005	MeCN	TFE	> 400	103	25
2.	[Fe(pTMAPP)Cl][PF6]4	0.002	Molecule:100761	0.2	BIH	0.005	MeCN	TFE	> 400	88	12
3.	[Fe(pTMAPP)Cl][PF6]4	0.002	Molecule:100762	0.2	BIH	0.005	MeCN	TFE	> 400	115
4.	[Fe(pTMAPP)Cl][PF6]4	0.002	Molecule:100763	0.2	BIH	0.005	MeCN	TFE	> 400	112	12
5.	[Fe(pTMAPP)Cl][PF6]4	0.002	Molecule:100764	0.2	BIH	0.005	MeCN	TFE	> 400	32	57
6.	[Fe(pTMAPP)Cl][PF6]4	0.002	Molecule:100765	0.2	BIH	0.005	MeCN	TFE	> 400	89

Investigation-Name: Table 1

Further Information

Investigations

Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)

DOI	10.1002/cptc.202200009
Authors	Martin Kientz, Grace Lowe, Blaine G. McCarthy, Garret M. Miyake, Julien Bonin, Marc Robert,
Submitted	11.03.2022
Published online	29.03.2022
Licenses	http://creativecommons.org/licenses/by/4.0/, http://doi.wiley.com/10.1002/tdm_license_1.1,
Subjects	Organic Chemistry, Physical and Theoretical Chemistry, Analytical Chemistry
Go to literature page

Phenoxazine-Sensitized CO2-to-CO Reduction with an Iron Porphyrin Catalyst: A Redox Properties-Catalytic Performance Study: Difference between revisions

Revision as of 17:30, 27 November 2023

Contents

Catalyst

Photosensitizer

Investigation

Further Information

Investigations

Topics

@@ Line 4: / Line 4: @@
 ====Catalyst====
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+M  V30 44 C 5.49908 -2.20731 0.0 0
+M  V30 45 C 6.16725 -2.96668 0.0 0
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+M  V30 47 C 7.47266 -1.8083 0.0 0
+M  V30 48 C 6.81208 -1.05868 0.0 0
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+M  V30 55 C 5.94743 0.103565 0.0 0
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+M  V30 57 C 14.6931 0.0707503 0.0 0
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+M  V30 63 C 5.36796 -10.4383 0.0 0
+M  V30 64 C 4.08094 -8.98368 0.0 0
+M  V30 65 Fe 9.41933 -5.27583 0.0 0 CHG=3
+M  V30 66 Cl 8.71222 -4.56872 0.0 0 CHG=-1
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+M  V30 94 F 3.40353 -0.83125 0.0 0
+M  V30 END ATOM
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+M  V30 END BOND
+M  V30 END CTAB
+M  END
+</chemform>
 ====Photosensitizer====

Phenoxazine-Sensitized CO2-to-CO Reduction with an Iron Porphyrin Catalyst: A Redox Properties-Catalytic Performance Study: Difference between revisions

Revision as of 17:30, 27 November 2023

Catalyst

Photosensitizer

Investigation

Further Information

Investigations

Current site

Topics