Visible-Light-Driven Photocatalytic CO2 Reduction by a Ni(II) Complex Bearing a Bioinspired Tetradentate Ligand for Selective CO Production: Difference between revisions

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DOI 10.1021/jacs.7b01956
Authors Dachao Hong, Yuto Tsukakoshi, Hiroaki Kotani, Tomoya Ishizuka, Takahiko Kojima,
Submitted 28.04.2017
Published online 04.05.2017
Licenses -
Subjects Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
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==== Catalyst====
==== Catalyst====
{{#moleculelink:|link=YWLPEVCCGUVAOP-UHFFFAOYSA-N|image=true}}
{{#moleculelink:|link=SOBXSEUOEROXNJ-UHFFFAOYSA-L|image=true}}


====Photosensitizer====
====Photosensitizer====

Revision as of 13:55, 28 November 2023


Catalyst

[Ni(bpet)(MeCN)2][ClO4]2

Photosensitizer

Ru(bpy)3Cl2

Investigation

catcat conc [µM]PSPS conc [mM]e-De-D conc [M]solvent A...λexc [nm].TON CO.TON H2..
1.

[Ni(bpet)(MeCN)2][ClO4]2

0.03

Ru(bpy)3Cl2

0.5

BIH

0.1

DMA

4507136.9
2.

[Ni(bpet)(MeCN)2][ClO4]2

0.03

Ru(bpy)3Cl2

0.5

BIH

0.1

DMF

45015911
3.

[Ni(bpet)(MeCN)2][ClO4]2

0.03

Ru(bpy)3Cl2

0.5

BIH

0.1

DMA

450673.4
4.

[Ni(bpet)(MeCN)2][ClO4]2

0.03

Ru(bpy)3Cl2

0.5

BIH

0.1

MeCN

450
5.

[Ni(bpet)(MeCN)2][ClO4]2

0.03

Ru(bpy)3Cl2

0.5

TEA

0.1

DMA

450
6.

[Ni(bpet)(MeCN)2][ClO4]2

0.03

Ru(bpy)3Cl2

0.5

TEOA

0.1

DMA

4502.625.5
Investigation-Name: Table 1

Sacrificial electron donor

BIHTEATEOA

Investigations

  • Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)