Highly Efficient and Selective Photocatalytic CO2 Reduction by Iron and Cobalt Quaterpyridine Complexes: Difference between revisions
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{{#doiinfobox: 10.1021/jacs.6b06002}} | |||
{{BaseTemplate}} | [[Category:Photocatalytic CO2 conversion to CO]] | ||
{{BaseTemplate}} | |||
==== Catalysts ==== | ==== Catalysts ==== | ||
<chemform smiles="C1C2C3C=CC=C4C5C=CC=C6C7C=CC=CN=7[Fe+2](O)(O)(N=34)(N=56)N=2C=CC=1.Cl([O-])(=O)(=O)=O.Cl([O-])(=O)(=O)=O" inchi="1S/C20H14N4.2ClHO4.Fe.2H2O/c1-3-13-21-15(7-1)17-9-5-11-19(23-17)20-12-6-10-18(24-20)16-8-2-4-14-22-16;2*2-1(3,4)5;;;/h1-14H;2*(H,2,3,4,5);;2*1H2/q;;;+2;;/p-2" inchikey="NLKWUAXOGCKGEY-UHFFFAOYSA-L" height="200px" width="300px" float="none"> | <chemform smiles="C1C2C3C=CC=C4C5C=CC=C6C7C=CC=CN=7[Fe+2](O)(O)(N=34)(N=56)N=2C=CC=1.Cl([O-])(=O)(=O)=O.Cl([O-])(=O)(=O)=O" inchi="1S/C20H14N4.2ClHO4.Fe.2H2O/c1-3-13-21-15(7-1)17-9-5-11-19(23-17)20-12-6-10-18(24-20)16-8-2-4-14-22-16;2*2-1(3,4)5;;;/h1-14H;2*(H,2,3,4,5);;2*1H2/q;;;+2;;/p-2" inchikey="NLKWUAXOGCKGEY-UHFFFAOYSA-L" height="200px" width="300px" float="none"> | ||
Revision as of 12:33, 11 August 2023
Catalysts
[Fe(qpy)(H2O)2][ClO4]2
[Co(qpy)(H2O)2][ClO4]2
Co(ClO4)2
Photosensitizers
Investigations
Investigation-Name: Co(qpy)(H2O)2(ClO4)2 and Ru(bpy)3Cl2
Sacrificial electron donor
Investigations
- Optimizations of conditions for Co(qpy)(H2O)2(ClO4)2 and Ru(bpy)3Cl2 (Molecular process, Photocatalytic CO2 conversion experiments)
- Optimizations of conditions for Co(qpy)(H2O)2(ClO4)2 and purpurin (Molecular process, Photocatalytic CO2 conversion experiments)
- Optimizations of conditions for Fe(qpy)(H2O)2(ClO4)2 (Molecular process, Photocatalytic CO2 conversion experiments)
- Optimizations of conditions for Fe(qpy)(H2O)2(ClO4)2 and Ru(bpy)3Cl2 (Molecular process, Photocatalytic CO2 conversion experiments)
