Highly Efficient and Selective Photocatalytic CO2 Reduction by Iron and Cobalt Quaterpyridine Complexes: Difference between revisions

Revision as of 12:21, 11 August 2023

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Optimizations of conditions for Co(qpy)(H2O)2(ClO4)2 and Ru(bpy)3Cl2 (Molecular process, Photocatalytic CO2 conversion experiments)
Optimizations of conditions for Co(qpy)(H2O)2(ClO4)2 and purpurin (Molecular process, Photocatalytic CO2 conversion experiments)
Optimizations of conditions for Fe(qpy)(H2O)2(ClO4)2 (Molecular process, Photocatalytic CO2 conversion experiments)
Optimizations of conditions for Fe(qpy)(H2O)2(ClO4)2 and Ru(bpy)3Cl2 (Molecular process, Photocatalytic CO2 conversion experiments)

DOI	10.1021/jacs.6b06002
Authors	Zhenguo Guo, Siwei Cheng, Claudio Cometto, Elodie Anxolabéhère-Mallart, Siu-Mui Ng, Chi-Chiu Ko, Guijian Liu, Lingjing Chen, Marc Robert, Tai-Chu Lau,
Submitted	22.07.2016
Published online	26.07.2016
Licenses	-
Subjects	Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
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@@ Line 180: / Line 180: @@
 M  V30 40 2 33 36
 M  V30 41 1 33 37
+M  V30 END BOND
+M  V30 END CTAB
+M  END
+</chemform><chemform smiles="Cl([O-])(=O)(=O)=O.Cl([O-])(=O)(=O)=O.[Co+2]" inchi="1S/2ClHO4.Co/c2*2-1(3,4)5;/h2*(H,2,3,4,5);/q;;+2/p-2" inchikey="BSUSEPIPTZNHMN-UHFFFAOYSA-L" height="200px" width="300px" float="none">
+  -INDIGO-08112313202D
+  0  0  0  0  0  0  0  0  0  0 V3000
+M  V30 BEGIN CTAB
+M  V30 COUNTS 11 8 0 0 0
+M  V30 BEGIN ATOM
+M  V30 1 Cl 5.85991 -4.47939 0.0 0
+M  V30 2 O 5.02832 -4.47939 0.0 0
+M  V30 3 O 5.86723 -3.65532 0.0 0
+M  V30 4 O 6.74625 -4.48672 0.0 0
+M  V30 5 O 5.85991 -5.31088 0.0 0 CHG=-1
+M  V30 6 Cl 10.3764 -4.54882 0.0 0
+M  V30 7 O 9.53063 -4.54882 0.0 0
+M  V30 8 O 10.3839 -3.71065 0.0 0
+M  V30 9 O 11.1931 -4.55661 0.0 0
+M  V30 10 O 10.3764 -5.39468 0.0 0 CHG=-1
+M  V30 11 Co 7.8 -4.45 0.0 0 CHG=2
+M  V30 END ATOM
+M  V30 BEGIN BOND
+M  V30 1 2 1 2
+M  V30 2 2 1 3
+M  V30 3 2 1 4
+M  V30 4 1 1 5
+M  V30 5 2 6 7
+M  V30 6 2 6 8
+M  V30 7 2 6 9
+M  V30 8 1 6 10
 M  V30 END BOND
 M  V30 END CTAB
@@ Line 338: / Line 369: @@
 ==== Investigations ====
+{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Co(qpy)(H2O)2(ClO4)2 and Ru(bpy)3Cl2}}
-{{#experimentlist:|form=Cyclic_Voltammetry_experiments|name=Fe(qpy)(H2O)2(ClO4)2 and Ru(bpy)3Cl2}}