A Dinuclear Cobalt Cryptate as a Homogeneous Photocatalyst for Highly Selective and Efficient Visible-Light Driven CO2 Reduction to CO in CH3CN-H2O Solution: Difference between revisions

Revision as of 12:55, 28 July 2023

Catalyst

100776

Photosensitizer

[Ru(phen)3][PF6]2

Investigation

Investigations

Best result and control experiments (Molecular process, Photocatalytic CO2 conversion experiments)

DOI	10.1002/ange.201610607
Authors	Ting Ouyang, Hai‐Hua Huang, Jia‐Wei Wang, Di‐Chang Zhong, Tong‐Bu Lu,
Submitted	13.12.2016
Published online	13.12.2016
Licenses	http://onlinelibrary.wiley.com/termsAndConditions#vor, http://doi.wiley.com/10.1002/tdm_license_1.1,
Subjects	General Medicine
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@@ Line 2: / Line 2: @@
 [[Category:Photocatalytic CO2 conversion to CO]]
 {{BaseTemplate}}
+==== Catalyst ====
+<chemform smiles="[Co+](O)123N4CC5=CC(CN6[Co+2]78N9CCN7(CC6)CCN8CC6C=CC=C(C=6)CN1CCN2(CCN3CC1C=C(C9)C=CC=1)CC4)=CC=C5.Cl([O-])(=O)(=O)=O.Cl([O-])(=O)(=O)=O.Cl([O-])(=O)(=O)=O" inchi="1S/C36H54N8.3ClHO4.2Co.H2O/c1-4-31-22-32(5-1)26-38-11-17-44-19-13-40-28-34-7-2-6-33(23-34)27-39-12-18-43(16-10-37-25-31)20-14-41-29-35-8-3-9-36(24-35)30-42-15-21-44;3*2-1(3,4)5;;;/h1-9,22-24,37-42H,10-21,25-30H2;3*(H,2,3,4,5);;;1H2/q;;;;2*+2;/p-4" inchikey="PWANXUIOGIXQEQ-UHFFFAOYSA-J" height="200px" width="300px" float="none">
+  -INDIGO-07262317532D
+  0  0  0  0  0  0  0  0  0  0 V3000
+M  V30 BEGIN CTAB
+M  V30 COUNTS 62 69 0 0 0
+M  V30 BEGIN ATOM
+M  V30 1 Co 5.825 -5.75 0.0 0 CHG=1
+M  V30 2 N 4.825 -5.75 0.0 0
+M  V30 3 C 4.325 -4.88397 0.0 0
+M  V30 4 C 5.03211 -4.17687 0.0 0
+M  V30 5 N 6.03211 -4.17687 0.0 0
+M  V30 6 C 4.325 -6.61603 0.0 0
+M  V30 7 C 4.825 -7.48205 0.0 0
+M  V30 8 N 6.125 -7.45705 0.0 0
+M  V30 9 C 3.95897 -6.25 0.0 0
+M  V30 10 C 4.975 -6.75 0.0 0
+M  V30 11 N 6.4 -6.725 0.0 0
+M  V30 12 C 6.78395 -3.51752 0.0 0
+M  V30 13 C 7.73088 -3.53896 0.0 0
+M  V30 14 C 8.5946 -2.03965 0.0 0
+M  V30 15 C 7.73049 -2.53825 0.0 0
+M  V30 16 C 9.46178 -2.53954 0.0 0
+M  V30 17 C 8.60152 -4.04085 0.0 0
+M  V30 18 C 9.46436 -3.53523 0.0 0
+M  V30 19 C 10.4644 -3.53523 0.0 0
+M  V30 20 N 11.3304 -4.03523 0.0 0
+M  V30 21 C 7.27264 -7.21336 0.0 0
+M  V30 22 C 8.27264 -7.21336 0.0 0
+M  V30 23 C 6.725 -8.39808 0.0 0
+M  V30 24 C 7.875 -8.42308 0.0 0
+M  V30 25 C 9.13637 -5.71405 0.0 0
+M  V30 26 C 8.27226 -6.21264 0.0 0
+M  V30 27 C 10.0035 -6.21394 0.0 0
+M  V30 28 C 9.14329 -7.71525 0.0 0
+M  V30 29 C 10.0061 -7.20962 0.0 0
+M  V30 30 C 9.6053 -8.42143 0.0 0
+M  V30 31 C 9.60597 -9.42237 0.0 0
+M  V30 32 C 7.87567 -9.42802 0.0 0
+M  V30 33 C 8.74498 -9.92245 0.0 0
+M  V30 34 C 11.0061 -7.20962 0.0 0
+M  V30 35 C 10.7053 -8.39643 0.0 0
+M  V30 36 N 11.4053 -7.60541 0.0 0
+M  V30 37 N 11.9632 -6.57752 0.0 0
+M  V30 38 C 8.74145 -7.92239 0.0 0
+M  V30 39 O 6.825 -5.75 0.0 0
+M  V30 40 C 12.3304 -4.03523 0.0 0
+M  V30 41 C 13.0375 -4.74233 0.0 0
+M  V30 42 N 12.5375 -5.60836 0.0 0
+M  V30 43 C 13.2375 -6.47438 0.0 0
+M  V30 44 C 12.8537 -7.51531 0.0 0
+M  V30 45 C 12.7132 -6.57752 0.0 0
+M  V30 46 C 13.4203 -5.84541 0.0 0
+M  V30 47 Co 11.5375 -5.60836 0.0 0 CHG=2
+M  V30 48 Cl 15.242 -2.4 0.0 0
+M  V30 49 O 16.108 -1.9 0.0 0
+M  V30 50 O 14.376 -1.9 0.0 0
+M  V30 51 O 15.242 -3.4 0.0 0
+M  V30 52 O 16.108 -2.9 0.0 0 CHG=-1
+M  V30 53 Cl 16.05 -5.25 0.0 0
+M  V30 54 O 16.916 -4.75 0.0 0
+M  V30 55 O 15.184 -4.75 0.0 0
+M  V30 56 O 16.05 -6.25 0.0 0
+M  V30 57 O 16.916 -5.75 0.0 0 CHG=-1
+M  V30 58 Cl 15.525 -7.875 0.0 0
+M  V30 59 O 16.391 -7.375 0.0 0
+M  V30 60 O 14.659 -7.375 0.0 0
+M  V30 61 O 15.525 -8.875 0.0 0
+M  V30 62 O 16.391 -8.375 0.0 0 CHG=-1
+M  V30 END ATOM
+M  V30 BEGIN BOND
+M  V30 1 10 1 2
+M  V30 2 1 2 3
+M  V30 3 1 3 4
+M  V30 4 1 4 5
+M  V30 5 1 2 6
+M  V30 6 1 6 7
+M  V30 7 1 7 8
+M  V30 8 1 2 9
+M  V30 9 1 9 10
+M  V30 10 1 10 11
+M  V30 11 10 5 1
+M  V30 12 10 1 11
+M  V30 13 10 1 8
+M  V30 14 1 5 12
+M  V30 15 1 12 13
+M  V30 16 2 15 13
+M  V30 17 2 16 14
+M  V30 18 1 13 17
+M  V30 19 1 14 15
+M  V30 20 2 17 18
+M  V30 21 1 18 16
+M  V30 22 1 18 19
+M  V30 23 1 19 20
+M  V30 24 1 11 21
+M  V30 25 1 21 22
+M  V30 26 1 8 23
+M  V30 27 1 23 24
+M  V30 28 2 26 22
+M  V30 29 2 27 25
+M  V30 30 1 22 28
+M  V30 31 1 25 26
+M  V30 32 2 28 29
+M  V30 33 1 29 27
+M  V30 34 2 31 30
+M  V30 35 1 24 32
+M  V30 36 2 32 33
+M  V30 37 1 33 31
+M  V30 38 1 29 34
+M  V30 39 1 30 35
+M  V30 40 1 35 36
+M  V30 41 1 34 37
+M  V30 42 1 30 38
+M  V30 43 2 38 24
+M  V30 44 1 1 39
+M  V30 45 1 20 40
+M  V30 46 1 40 41
+M  V30 47 1 41 42
+M  V30 48 1 42 43
+M  V30 49 1 43 44
+M  V30 50 1 36 44
+M  V30 51 1 37 45
+M  V30 52 1 45 46
+M  V30 53 1 46 42
+M  V30 54 10 42 47
+M  V30 55 10 20 47
+M  V30 56 10 47 37
+M  V30 57 10 47 36
+M  V30 58 2 48 49
+M  V30 59 2 48 50
+M  V30 60 2 48 51
+M  V30 61 1 48 52
+M  V30 62 2 53 54
+M  V30 63 2 53 55
+M  V30 64 2 53 56
+M  V30 65 1 53 57
+M  V30 66 2 58 59
+M  V30 67 2 58 60
+M  V30 68 2 58 61
+M  V30 69 1 58 62
+M  V30 END BOND
+M  V30 END CTAB
+M  END
+</chemform>
+==== Photosensitizer ====
+<chemform smiles="C1=CC=N2[Ru+2]3(N4=CC=CC5C=CC6=C(C=54)N3=CC=C6)3(N4=CC=CC5C=CC6=C(C=54)N3=CC=C6)N3=CC=CC4C=CC1=C2C=43.[P-](F)(F)(F)(F)(F)F.[P-](F)(F)(F)(F)(F)F" inchi="1S/3C12H8N2.2F6P.Ru/c3*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;2*1-7(2,3,4,5)6;/h3*1-8H;;;/q;;;2*-1;+2" inchikey="YRYUXGTVQZIGNQ-UHFFFAOYSA-N" height="200px" width="300px" float="none">
+  -INDIGO-07262318002D
+  0  0  0  0  0  0  0  0  0  0 V3000
+M  V30 BEGIN CTAB
+M  V30 COUNTS 57 66 0 0 0
+M  V30 BEGIN ATOM
+M  V30 1 C 4.68485 -4.10007 0.0 0
+M  V30 2 C 6.41515 -4.09959 0.0 0
+M  V30 3 C 5.55164 -3.59997 0.0 0
+M  V30 4 N 6.41515 -5.10053 0.0 0
+M  V30 5 C 4.68485 -5.10502 0.0 0
+M  V30 6 C 5.55382 -5.60003 0.0 0
+M  V30 7 C 5.5532 -2.6054 0.0 0
+M  V30 8 C 6.4177 -2.10702 0.0 0
+M  V30 9 C 7.2831 -3.59922 0.0 0
+M  V30 10 C 7.27797 -2.60224 0.0 0
+M  V30 11 C 8.13649 -2.1014 0.0 0
+M  V30 12 C 9.00281 -2.59531 0.0 0
+M  V30 13 N 8.15289 -4.09511 0.0 0
+M  V30 14 C 9.01012 -3.58727 0.0 0
+M  V30 15 C 11.8953 -4.00653 0.0 0
+M  V30 16 C 11.0287 -5.50858 0.0 0
+M  V30 17 C 11.895 -5.00946 0.0 0
+M  V30 18 N 10.1599 -5.007 0.0 0
+M  V30 19 C 11.0231 -3.50294 0.0 0
+M  V30 20 C 10.158 -4.00911 0.0 0
+M  V30 21 C 12.7575 -5.50921 0.0 0
+M  V30 22 C 12.7568 -6.50928 0.0 0
+M  V30 23 C 11.028 -6.51265 0.0 0
+M  V30 24 C 11.8959 -7.0078 0.0 0
+M  V30 25 C 11.9004 -8.00392 0.0 0
+M  V30 26 C 11.0376 -8.50834 0.0 0
+M  V30 27 N 10.1618 -7.01909 0.0 0
+M  V30 28 C 10.173 -8.01759 0.0 0
+M  V30 29 C 8.20163 -10.1467 0.0 0
+M  V30 30 C 7.33414 -8.64517 0.0 0
+M  V30 31 C 7.33321 -9.64502 0.0 0
+M  V30 32 N 8.20291 -8.14359 0.0 0
+M  V30 33 C 9.07387 -9.64315 0.0 0
+M  V30 34 C 9.06806 -8.64087 0.0 0
+M  V30 35 C 6.4692 -10.142 0.0 0
+M  V30 36 C 5.60343 -9.64145 0.0 0
+M  V30 37 C 6.46491 -8.14258 0.0 0
+M  V30 38 C 5.60216 -8.64663 0.0 0
+M  V30 39 C 4.73725 -8.15245 0.0 0
+M  V30 40 C 4.73181 -7.15303 0.0 0
+M  V30 41 N 6.45946 -7.13916 0.0 0
+M  V30 42 C 5.58912 -6.64962 0.0 0
+M  V30 43 Ru 8.15618 -6.05053 0.0 0 CHG=2
+M  V30 44 P 15.092 -3.15 0.0 0 CHG=-1
+M  V30 45 F 15.958 -2.65 0.0 0
+M  V30 46 F 14.226 -2.65 0.0 0
+M  V30 47 F 15.092 -4.15 0.0 0
+M  V30 48 F 15.958 -3.65 0.0 0
+M  V30 49 F 15.092 -2.15 0.0 0
+M  V30 50 F 14.226 -3.65 0.0 0
+M  V30 51 P 15.65 -6.15 0.0 0 CHG=-1
+M  V30 52 F 16.516 -5.65 0.0 0
+M  V30 53 F 14.784 -5.65 0.0 0
+M  V30 54 F 15.65 -7.15 0.0 0
+M  V30 55 F 16.516 -6.65 0.0 0
+M  V30 56 F 15.65 -5.15 0.0 0
+M  V30 57 F 14.784 -6.65 0.0 0
+M  V30 END ATOM
+M  V30 BEGIN BOND
+M  V30 1 1 3 1
+M  V30 2 1 4 2
+M  V30 3 2 1 5
+M  V30 4 2 2 3
+M  V30 5 1 5 6
+M  V30 6 2 6 4
+M  V30 7 2 8 7
+M  V30 8 1 2 9
+M  V30 9 1 7 3
+M  V30 10 2 9 10
+M  V30 11 1 10 8
+M  V30 12 2 12 11
+M  V30 13 1 9 13
+M  V30 14 1 11 10
+M  V30 15 2 13 14
+M  V30 16 1 14 12
+M  V30 17 1 17 15
+M  V30 18 1 18 16
+M  V30 19 2 15 19
+M  V30 20 2 16 17
+M  V30 21 1 19 20
+M  V30 22 2 20 18
+M  V30 23 2 22 21
+M  V30 24 1 16 23
+M  V30 25 1 21 17
+M  V30 26 2 23 24
+M  V30 27 1 24 22
+M  V30 28 2 26 25
+M  V30 29 1 23 27
+M  V30 30 1 25 24
+M  V30 31 2 27 28
+M  V30 32 1 28 26
+M  V30 33 1 31 29
+M  V30 34 1 32 30
+M  V30 35 2 29 33
+M  V30 36 2 30 31
+M  V30 37 1 33 34
+M  V30 38 2 34 32
+M  V30 39 2 36 35
+M  V30 40 1 30 37
+M  V30 41 1 35 31
+M  V30 42 2 37 38
+M  V30 43 1 38 36
+M  V30 44 2 40 39
+M  V30 45 1 37 41
+M  V30 46 1 39 38
+M  V30 47 2 41 42
+M  V30 48 1 42 40
+M  V30 49 10 4 43
+M  V30 50 10 43 13
+M  V30 51 10 43 18
+M  V30 52 10 43 27
+M  V30 53 10 43 32
+M  V30 54 10 43 41
+M  V30 55 1 44 45
+M  V30 56 1 44 46
+M  V30 57 1 44 47
+M  V30 58 1 44 48
+M  V30 59 1 44 49
+M  V30 60 1 44 50
+M  V30 61 1 51 52
+M  V30 62 1 51 53
+M  V30 63 1 51 54
+M  V30 64 1 51 55
+M  V30 65 1 51 56
+M  V30 66 1 51 57
+M  V30 END BOND
+M  V30 END CTAB
+M  END
+</chemform>
+==== Investigation ====

A Dinuclear Cobalt Cryptate as a Homogeneous Photocatalyst for Highly Selective and Efficient Visible-Light Driven CO2 Reduction to CO in CH3CN-H2O Solution: Difference between revisions

Revision as of 12:55, 28 July 2023

Catalyst

Photosensitizer

Investigation

Investigations

Current site

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