Phenoxazine-Sensitized CO2-to-CO Reduction with an Iron Porphyrin Catalyst: A Redox Properties-Catalytic Performance Study: Difference between revisions
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[[Category:Photocatalytic CO2 conversion to CO]] | [[Category:Photocatalytic CO2 conversion to CO]] | ||
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====Catalyst==== | |||
<chemform smiles="" inchi="" inchikey="MXOBCRHAQPLEER-YUTFXDKVSA-N" height="200px" width="300px" float="none"></chemform>{{#moleculelink:|link=MXOBCRHAQPLEER-YUTFXDKVSA-N|image=true}} | |||
====Photosensitizer==== | |||
{{#moleculelink:|link=IGGSSEOAGCUGDJ-UHFFFAOYSA-N|image=true}} {{#moleculelink:|link=WKYXCCICHXAEHL-UHFFFAOYSA-N|image=true}}{{#moleculelink:|link=HDOFYEULLIFSQY-UHFFFAOYSA-N|image=true}}{{#moleculelink:|link=ZIGQSGYNHLDFOD-UHFFFAOYSA-N|image=true}}{{#moleculelink:|link=JUDLWUDCWSBXOA-UHFFFAOYSA-N|image=true}}{{#moleculelink:|link=JLXPQUVLGFUEHE-UHFFFAOYSA-N|image=true}} | |||
====Investigation==== | |||
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}} | |||
====Further Information==== |
Revision as of 09:17, 28 June 2023
Catalyst
Molecule with key MXOBCRHAQPLEER-YUTFXDKVSA-N does not exist.
Photosensitizer
3,7-Di((1,1'-biphenyl)-4-yl)-10-(naphthalen-1-yl)-10H-phenoxazine 1007611007621007634-[7-[4-(diphenylamino)phenyl]-10-naphthalen-2-yl-phenoxazin-3-yl]-N,N-diphenyl-aniline10-naphthalen-2-yl-3,7-di(pyren-1-yl)phenoxazine
Investigation
cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | solvent A | additives | . | λexc [nm] | . | TON CO | TON H2 | . | |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1. | 0.002 | 0.2 | 0.005 | TFE | > 400 | 103 | 25 | |||||||
2. | 0.002 | 0.2 | 0.005 | TFE | > 400 | 88 | 12 | |||||||
3. | 0.002 | 0.2 | 0.005 | TFE | > 400 | 115 | ||||||||
4. | 0.002 | 0.2 | 0.005 | TFE | > 400 | 112 | 12 | |||||||
5. | 0.002 | 0.2 | 0.005 | TFE | > 400 | 32 | 57 | |||||||
6. | 0.002 | 0.2 | 0.005 | TFE | > 400 | 89 |
Investigation-Name: Table 1
Further Information
Investigations
- Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)