Nickel(II) pincer complexes demonstrate that the remote substituent controls catalytic carbon dioxide reduction: Difference between revisions

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DOI 10.1039/c7cc09507d
Authors Dalton B. Burks, Shakeyia Davis, Robert W. Lamb, Xuan Liu, Roberta R. Rodrigues, Nalaka P. Liyanage, Yujie Sun, Charles Edwin Webster, Jared H. Delcamp, Elizabeth T. Papish,
Submitted 13.03.2018
Published online 2018
Licenses http://rsc.li/journals-terms-of-use#chorus,
Subjects Materials Chemistry, Metals and Alloys, Surfaces, Coatings and Films, General Chemistry, Ceramics and Composites, Electronic, Optical and Magnetic Materials, Catalysis
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{{BaseTemplate}}
{{BaseTemplate}}
{{#doiinfobox: 10.1039/c7cc09507d}}
{{#doiinfobox: 10.1039/c7cc09507d}}
=== Investigation ===
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}}


=== Catalyst ===
===Catalyst===
<chemform smiles="" inchi="" inchikey="QFRHHPFUSKJYCI-UHFFFAOYSA-L" height="200px" width="300px" float="none"></chemform><chemform smiles="C1C2N3C=CN(C)C3[Ni](N#CC)3C4N(C(N=23)=CC=1)C=CN4C" inchi="1S/C13H17N5.C2H3N.Ni/c1-15-6-8-17(10-15)12-4-3-5-13(14-12)18-9-7-16(2)11-18;1-2-3;/h3-9H,10-11H2,1-2H3;1H3;" inchikey="WWQONKLZHTWXPP-UHFFFAOYSA-N" height="200px" width="300px" float="none">
{{#moleculelink:|link=QFRHHPFUSKJYCI-UHFFFAOYSA-L|image=true}}
<chemform smiles="C1C2N3C=CN(C)C3[Ni](N#CC)3C4N(C(N=23)=CC=1)C=CN4C" inchi="1S/C13H17N5.C2H3N.Ni/c1-15-6-8-17(10-15)12-4-3-5-13(14-12)18-9-7-16(2)11-18;1-2-3;/h3-9H,10-11H2,1-2H3;1H3;" inchikey="WWQONKLZHTWXPP-UHFFFAOYSA-N" height="200px" width="300px" float="none">
   -INDIGO-01272314332D
   -INDIGO-01272314332D


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</chemform>
</chemform>


=== Photosensitizer ===
===Photosensitizer ===
<chemform smiles="" inchi="" inchikey="UEEXRMUCXBPYOV-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform>
{{#moleculelink:|link=UEEXRMUCXBPYOV-UHFFFAOYSA-N|image=true}}
 
===Investigation ===
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}}


=== Sacrificial electron donor ===
===Sacrificial electron donor===
<chemform smiles="" inchi="" inchikey="VDFIVJSRRJXMAU-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform><chemform smiles="" inchi="" inchikey="ZMANZCXQSJIPKH-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform>
{{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=true}}{{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=true}}


=== Additives ===
===Additives===
<chemform smiles="C(F)(F)(F)S(=O)(=O)O" inchi="1S/CHF3O3S/c2-1(3,4)8(5,6)7/h(H,5,6,7)" inchikey="ITMCEJHCFYSIIV-UHFFFAOYSA-N" height="200px" width="300px" float="none">
<chemform smiles="C(F)(F)(F)S(=O)(=O)O" inchi="1S/CHF3O3S/c2-1(3,4)8(5,6)7/h(H,5,6,7)" inchikey="ITMCEJHCFYSIIV-UHFFFAOYSA-N" height="200px" width="300px" float="none">
   -INDIGO-05042311232D
   -INDIGO-05042311232D

Revision as of 09:22, 7 July 2023


Catalyst

Molecule with key QFRHHPFUSKJYCI-UHFFFAOYSA-L does not exist.

Photosensitizer

Molecule with key UEEXRMUCXBPYOV-UHFFFAOYSA-N does not exist.

Investigation

Investigation-Name: Table 1

Sacrificial electron donor

BIHTEA

Additives

TfOH

Investigations