Molecular Catalysis of the Electrochemical and Photochemical Reduction of CO2 with Earth-Abundant Metal Complexes. Selective Production of CO vs HCOOH by Switching of the Metal Center: Difference between revisions

Revision as of 10:20, 7 July 2023

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	solvent A	.	.	λexc [nm]	.	TON CO	TON HCOOH	.
1.	[Co(pabop)][ClO4]2	0.05	Ir(ppy)3	0.2	TEA	MeCN			>460		270
2.	[Fe(pabop)Cl2][CLO4]	0.05	Ir(ppy)3	0.2	TEA	MeCN			>420			5

Investigation-Name: Table 1

DOI	10.1021/jacs.5b06535
Authors	Lingjing Chen, Zhenguo Guo, Xi-Guang Wei, Charlotte Gallenkamp, Julien Bonin, Elodie Anxolabéhère-Mallart, Kai-Chung Lau, Tai-Chu Lau, Marc Robert,
Submitted	12.08.2015
Published online	19.08.2015
Licenses	-
Subjects	Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
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@@ Line 2: / Line 2: @@
 [[Category:Photocatalytic CO2 conversion to HCOOH]]
 {{BaseTemplate}}
-==== Investigation ====
-{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}}
-==== Catalyst ====
+====Catalyst====
 <chemform smiles="C1C2C(C)=N3[Fe+3]([Cl-])([Cl-])456N(CCN4CCN5CC3)=C(C)C(N=26)=CC=1.Cl([O-])(=O)(=O)=O" inchi="1S/C15H23N5.ClHO4.2ClH.Fe/c1-12-14-4-3-5-15(20-14)13(2)19-11-9-17-7-6-16-8-10-18-12;2-1(3,4)5;;;/h3-5,16-17H,6-11H2,1-2H3;(H,2,3,4,5);2*1H;/q;;;;+3/p-3/b18-12+,19-13+;;;;" inchikey="XTLBRFNUSVMBAM-DQIPMIPLSA-K" height="200px" width="300px" float="none">
    -INDIGO-05172314152D
@@ Line 157: / Line 155: @@
 </chemform>
-==== Photosensitizer ====
+====Photosensitizer====
 <chemform smiles="C1C=C2C3C=CC=CN=3[Ir]3(C4=CC=CC=C4C4=CC=CC=N43)3(C4=CC=CC=C4C4N3=CC=CC=4)C2=CC=1" inchi="1S/3C11H9N.Ir/c3*1-2-6-10(7-3-1)11-8-4-5-9-12-11;/h3*1-9H;" inchikey="UEEXRMUCXBPYOV-UHFFFAOYSA-N" height="200px" width="300px" float="none">
    -INDIGO-05172314172D
@@ Line 254: / Line 252: @@
 </chemform>
-==== Sacrificial electron donor ====
+====Investigation====
-<chemform smiles="" inchi="" inchikey="ZMANZCXQSJIPKH-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform>
+{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}}
+====Sacrificial electron donor====
+{{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=true}}