Molecular Catalysis of the Electrochemical and Photochemical Reduction of CO2 with Earth-Abundant Metal Complexes. Selective Production of CO vs HCOOH by Switching of the Metal Center: Difference between revisions
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==== Sacrificial electron donor ==== | ==== Sacrificial electron donor ==== | ||
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Revision as of 08:55, 19 May 2023
Investigation
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | solvent A | . | . | λexc [nm] | . | TON CO | TON HCOOH | . | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1. | 0.05 | 0.2 | >460 | 270 | |||||||||
| 2. | 0.05 | 0.2 | >420 | 5 |
Investigation-Name: Table 1
Catalyst
[Fe(pabop)Cl2][CLO4]
[Co(pabop)][ClO4]2
Photosensitizer
Sacrificial electron donor
Investigations
- Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)
