Visible-Light-Driven Photocatalytic CO2 Reduction by a Ni(II) Complex Bearing a Bioinspired Tetradentate Ligand for Selective CO Production: Difference between revisions
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{{#doiinfobox: 10.1021/jacs.7b01956}} | {{#doiinfobox: 10.1021/jacs.7b01956}} | ||
==== | ==== Catalyst==== | ||
{{# | {{#moleculelink:|link=YWLPEVCCGUVAOP-UHFFFAOYSA-N|image=true}} | ||
==== Photosensitizer ==== | ====Photosensitizer==== | ||
<chemform smiles="C12C3=CC=CC=N3[Ru+2](N1=CC=CC=2)1(N2C=CC=CC=2C2N1=CC=CC=2)1N2C=CC=CC=2C2N1=CC=CC=2" inchi="1S/3C10H8N2.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;/h3*1-8H;/q;;;+2" inchikey="HNVRWFFXWFXICS-UHFFFAOYSA-N" height="200px" width="300px" float="none"> | <chemform smiles="C12C3=CC=CC=N3[Ru+2](N1=CC=CC=2)1(N2C=CC=CC=2C2N1=CC=CC=2)1N2C=CC=CC=2C2N1=CC=CC=2" inchi="1S/3C10H8N2.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;/h3*1-8H;/q;;;+2" inchikey="HNVRWFFXWFXICS-UHFFFAOYSA-N" height="200px" width="300px" float="none"> | ||
-INDIGO-02012310412D | -INDIGO-02012310412D | ||
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</chemform> | </chemform> | ||
==== Sacrificial electron donor ==== | ====Investigation==== | ||
{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=Table 1}} | |||
====Sacrificial electron donor==== | |||
{{#moleculelink:|link=VDFIVJSRRJXMAU-UHFFFAOYSA-N|image=true}}{{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=true}}{{#moleculelink:|link=GSEJCLTVZPLZKY-UHFFFAOYSA-N|image=true}} | |||
[[Category:Photocatalytic CO2 conversion to CO]] | [[Category:Photocatalytic CO2 conversion to CO]] | ||
Revision as of 09:44, 7 July 2023
Catalyst
Molecule with key YWLPEVCCGUVAOP-UHFFFAOYSA-N does not exist.
Photosensitizer
Investigation
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | solvent A | . | . | . | λexc [nm] | . | TON CO | . | TON H2 | . | . | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1. | 0.03 | 0.5 | 0.1 | 450 | 713 | 6.9 | |||||||||||
| 2. | 0.03 | 0.5 | 0.1 | 450 | 159 | 11 | |||||||||||
| 3. | 0.03 | 0.5 | 0.1 | 450 | 67 | 3.4 | |||||||||||
| 4. | 0.03 | 0.5 | 0.1 | 450 | |||||||||||||
| 5. | 0.03 | 0.5 | 0.1 | 450 | |||||||||||||
| 6. | 0.03 | 0.5 | 0.1 | 450 | 2.6 | 25.5 |
Investigation-Name: Table 1
Sacrificial electron donor
Investigations
- Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)
