Visible-Light-Driven Photocatalytic CO2 Reduction by a Ni(II) Complex Bearing a Bioinspired Tetradentate Ligand for Selective CO Production: Difference between revisions
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{{#doiinfobox: 10.1021/jacs.7b01956}} | {{#doiinfobox: 10.1021/jacs.7b01956}} | ||
==== Investigation ==== | |||
==== Catalyst ==== | |||
<chemform smiles="" inchi="" inchikey="YWLPEVCCGUVAOP-UHFFFAOYSA-N " height="200px" width="300px" float="none"></chemform> | |||
==== Photosensitizer ==== | |||
<chemform smiles="C12C3=CC=CC=N3[Ru+2](N1=CC=CC=2)1(N2C=CC=CC=2C2N1=CC=CC=2)1N2C=CC=CC=2C2N1=CC=CC=2" inchi="1S/3C10H8N2.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;/h3*1-8H;/q;;;+2" inchikey="HNVRWFFXWFXICS-UHFFFAOYSA-N" height="200px" width="300px" float="none"> | |||
-INDIGO-02012310412D | |||
0 0 0 0 0 0 0 0 0 0 0 V3000 | |||
M V30 BEGIN CTAB | |||
M V30 COUNTS 37 45 0 0 0 | |||
M V30 BEGIN ATOM | |||
M V30 1 C 10.5435 -4.92762 0.0 0 | |||
M V30 2 C 11.7491 -4.99092 0.0 0 | |||
M V30 3 C 11.2288 -4.73543 0.0 0 | |||
M V30 4 C 11.8152 -5.59773 0.0 0 | |||
M V30 5 N 10.1065 -5.76474 0.0 0 | |||
M V30 6 C 11.152 -6.14351 0.0 0 | |||
M V30 7 N 9.25866 -4.63911 0.0 0 | |||
M V30 8 C 9.63235 -3.30328 0.0 0 | |||
M V30 9 C 9.14128 -3.93512 0.0 0 | |||
M V30 10 C 10.2777 -3.25752 0.0 0 | |||
M V30 11 C 10.2001 -4.55637 0.0 0 | |||
M V30 12 C 10.6339 -3.773 0.0 0 | |||
M V30 13 C 5.94213 -3.03516 0.0 0 | |||
M V30 14 C 7.24168 -3.49305 0.0 0 | |||
M V30 15 C 6.59328 -2.8886 0.0 0 | |||
M V30 16 N 7.04427 -4.43995 0.0 0 | |||
M V30 17 C 5.69026 -3.59788 0.0 0 | |||
M V30 18 C 6.01761 -4.2224 0.0 0 | |||
M V30 19 C 4.16032 -4.25649 0.0 0 | |||
M V30 20 C 5.64012 -4.58942 0.0 0 | |||
M V30 21 C 4.8164 -4.06601 0.0 0 | |||
M V30 22 N 5.79253 -5.37659 0.0 0 | |||
M V30 23 C 3.99774 -4.91039 0.0 0 | |||
M V30 24 C 4.6602 -5.58382 0.0 0 | |||
M V30 25 C 5.61199 -8.17009 0.0 0 | |||
M V30 26 C 7.22575 -8.54472 0.0 0 | |||
M V30 27 N 6.81042 -7.59487 0.0 0 | |||
M V30 28 C 7.08099 -9.28642 0.0 0 | |||
M V30 29 C 5.63354 -9.26837 0.0 0 | |||
M V30 30 C 6.38037 -9.63065 0.0 0 | |||
M V30 31 C 8.04784 -8.35665 0.0 0 | |||
M V30 32 C 9.63143 -8.08568 0.0 0 | |||
M V30 33 N 8.65644 -7.66877 0.0 0 | |||
M V30 34 C 9.74901 -9.15397 0.0 0 | |||
M V30 35 C 8.28703 -9.41911 0.0 0 | |||
M V30 36 C 9.08273 -9.6819 0.0 0 | |||
M V30 37 Ru 7.90443 -6.04653 0.0 0 CHG=2 | |||
M V30 END ATOM | |||
M V30 BEGIN BOND | |||
M V30 1 2 3 1 | |||
M V30 2 2 4 2 | |||
M V30 3 1 1 5 | |||
M V30 4 1 2 3 | |||
M V30 5 2 5 6 | |||
M V30 6 1 6 4 | |||
M V30 7 2 9 7 | |||
M V30 8 2 10 8 | |||
M V30 9 1 7 11 | |||
M V30 10 1 8 9 | |||
M V30 11 2 11 12 | |||
M V30 12 1 12 10 | |||
M V30 13 2 15 13 | |||
M V30 14 2 16 14 | |||
M V30 15 1 13 17 | |||
M V30 16 1 14 15 | |||
M V30 17 2 17 18 | |||
M V30 18 1 18 16 | |||
M V30 19 2 21 19 | |||
M V30 20 2 22 20 | |||
M V30 21 1 19 23 | |||
M V30 22 1 20 21 | |||
M V30 23 2 23 24 | |||
M V30 24 1 24 22 | |||
M V30 25 2 27 25 | |||
M V30 26 2 28 26 | |||
M V30 27 1 25 29 | |||
M V30 28 1 26 27 | |||
M V30 29 2 29 30 | |||
M V30 30 1 30 28 | |||
M V30 31 2 33 31 | |||
M V30 32 2 34 32 | |||
M V30 33 1 31 35 | |||
M V30 34 1 32 33 | |||
M V30 35 2 35 36 | |||
M V30 36 1 36 34 | |||
M V30 37 1 26 31 | |||
M V30 38 1 20 18 | |||
M V30 39 1 11 1 | |||
M V30 40 10 16 37 | |||
M V30 41 10 22 37 | |||
M V30 42 10 27 37 | |||
M V30 43 10 33 37 | |||
M V30 44 10 5 37 | |||
M V30 45 10 7 37 | |||
M V30 END BOND | |||
M V30 END CTAB | |||
M END | |||
</chemform> | |||
==== Sacrificial electron donor ==== | |||
<chemform smiles="" inchi="" inchikey="VDFIVJSRRJXMAU-UHFFFAOYSA-N " height="200px" width="300px" float="none"></chemform> | |||
[[Category:Photocatalytic CO2 conversion to CO]] | [[Category:Photocatalytic CO2 conversion to CO]] |
Revision as of 10:41, 1 February 2023
Investigations
- Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)