Nickel(II) pincer complexes demonstrate that the remote substituent controls catalytic carbon dioxide reduction: Difference between revisions
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{{#doiinfobox: 10.1039/c7cc09507d}} | {{#doiinfobox: 10.1039/c7cc09507d}} | ||
==== Investigation ==== | |||
==== Catalyst ==== | |||
<chemform smiles="" inchi="" inchikey="QFRHHPFUSKJYCI-UHFFFAOYSA-L" height="200px" width="300px" float="none"></chemform><chemform smiles="C1C2N3C=CN(C)C3[Ni](N#CC)3C4N(C(N=23)=CC=1)C=CN4C" inchi="1S/C13H17N5.C2H3N.Ni/c1-15-6-8-17(10-15)12-4-3-5-13(14-12)18-9-7-16(2)11-18;1-2-3;/h3-9H,10-11H2,1-2H3;1H3;" inchikey="WWQONKLZHTWXPP-UHFFFAOYSA-N" height="200px" width="300px" float="none"> | |||
-INDIGO-01272314332D | |||
0 0 0 0 0 0 0 0 0 0 0 V3000 | |||
M V30 BEGIN CTAB | |||
M V30 COUNTS 22 26 0 0 0 | |||
M V30 BEGIN ATOM | |||
M V30 1 C 6.95985 -3.47507 0.0 0 | |||
M V30 2 C 8.69015 -3.47459 0.0 0 | |||
M V30 3 C 7.82664 -2.97497 0.0 0 | |||
M V30 4 C 8.69015 -4.47553 0.0 0 | |||
M V30 5 C 6.95985 -4.48002 0.0 0 | |||
M V30 6 N 7.82882 -4.97503 0.0 0 | |||
M V30 7 N 6.02651 -5.12971 0.0 0 | |||
M V30 8 C 6.18292 -6.11739 0.0 0 | |||
M V30 9 N 5.29191 -6.57142 0.0 0 | |||
M V30 10 C 4.58481 -5.86432 0.0 0 | |||
M V30 11 C 5.03884 -4.9733 0.0 0 | |||
M V30 12 N 9.62349 -5.15472 0.0 0 | |||
M V30 13 C 10.6112 -4.9983 0.0 0 | |||
M V30 14 C 11.0652 -5.88932 0.0 0 | |||
M V30 15 N 10.3581 -6.59642 0.0 0 | |||
M V30 16 C 9.46708 -6.14239 0.0 0 | |||
M V30 17 C 5.13549 -7.55911 0.0 0 | |||
M V30 18 C 10.5145 -7.58411 0.0 0 | |||
M V30 19 Ni 7.85 -6.225 0.0 0 | |||
M V30 20 N 7.85 -7.225 0.0 0 | |||
M V30 21 C 7.85 -8.225 0.0 0 | |||
M V30 22 C 7.85 -9.225 0.0 0 | |||
M V30 END ATOM | |||
M V30 BEGIN BOND | |||
M V30 1 2 3 1 | |||
M V30 2 2 4 2 | |||
M V30 3 1 1 5 | |||
M V30 4 1 2 3 | |||
M V30 5 2 5 6 | |||
M V30 6 1 6 4 | |||
M V30 7 1 7 8 | |||
M V30 8 1 8 9 | |||
M V30 9 1 9 10 | |||
M V30 10 2 10 11 | |||
M V30 11 1 11 7 | |||
M V30 12 1 12 13 | |||
M V30 13 2 13 14 | |||
M V30 14 1 14 15 | |||
M V30 15 1 15 16 | |||
M V30 16 1 16 12 | |||
M V30 17 1 7 5 | |||
M V30 18 1 12 4 | |||
M V30 19 1 9 17 | |||
M V30 20 1 15 18 | |||
M V30 21 10 6 19 | |||
M V30 22 10 8 19 | |||
M V30 23 10 16 19 | |||
M V30 24 10 19 20 | |||
M V30 25 3 20 21 | |||
M V30 26 1 21 22 | |||
M V30 END BOND | |||
M V30 END CTAB | |||
M END | |||
</chemform> | |||
==== Photosensitizer ==== | |||
<chemform smiles="" inchi="" inchikey="UEEXRMUCXBPYOV-UHFFFAOYSA-N " height="200px" width="300px" float="none"></chemform> | |||
[[Category:Photocatalytic CO2 conversion to CO]] | [[Category:Photocatalytic CO2 conversion to CO]] |
Revision as of 14:34, 27 January 2023
Investigation
Catalyst
Photosensitizer
Investigations
- Photocatalytic CO2 reduction under varied conditions (Molecular process, Photocatalytic CO2 conversion experiments)