Water-Assisted Highly Efficient Photocatalytic Reduction of CO2 to CO with Noble Metal-Free Bis(terpyridine)iron(II) Complexes and an Organic Photosensitizer: Difference between revisions

Latest revision as of 08:55, 15 May 2024

A photochemical reduction of CO₂ to CO was shown using the iron complexes 100947, 100948 and 100949 as catalysts in combination with the organic photosensitizer 4CzIPN. Turnover numbers (TONs) of 6320 and a selectivity of 99.4% for CO were reached in DMF/H₂O with catalyst 100949. The experiments were conducted under visible-light irradiation (λ = 440 nm) using TEA as sacrificial electron donor (see section SEDs below).

Advances and special progress[edit | edit source]

One of the highest TONs for CO₂ reduction with an organic thermally activated delayed fluorescence (TADF) compound as a photosensitizer was reported herein.

Additional remarks[edit | edit source]

The addition of water was found to strongly promote the catalytic reaction.

Content of the published article in detail[edit | edit source]

The article contains results for the reduction of CO₂ to CO under visible-light catalysis using the iron complex 100949 as a catalyst. The catalytic system performs best (referring to the TON of CO production) in DMF/H₂O.

Catalyst[edit | edit source]

100946 [Show R-Groups]

Photosensitizer[edit | edit source]

4CzIPN

Investigation[edit | edit source]

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	λexc [nm]	TON CO
1.	Molecule:100949	0.01	4CzIPN	0.05	TEA	0.28	DMF	420-650	6320
2.	Molecule:100948	0.01	4CzIPN	0.05	TEA	0.28	DMF	420-650	2780
3.	Molecule:100947	0.01	4CzIPN	0.05	TEA	0.28	DMF	420-650	4500
4.	Molecule:100949	0.01	Ru(bpy)3	0.05	TEA	0.28	DMF	420-650	19
5.	Molecule:100949	0.01	4CzIPN	0.05	TEA	0.28	MeCN	420-650	992

Investigation-Name: photocatalytic CO2 conversion

Sacrificial electron donor[edit | edit source]

In this study, the experiments were done with the sacrificial electron donor TEA (TEA).

Additives[edit | edit source]

In this study, no additives were tested.

Investigations

photocatalytic CO2 conversion (Molecular process, Photocatalytic CO2 conversion experiments)

DOI	10.1021/acs.inorgchem.0c03503
Authors	Yanan Wang, Ting Liu, Longxin Chen, Duobin Chao,
Submitted	21.02.2021
Published online	21.02.2021
Licenses	https://doi.org/10.15223/policy-029, https://doi.org/10.15223/policy-037, https://doi.org/10.15223/policy-045,
Subjects	-
Go to literature page

@@ Line 2: / Line 2: @@
 [[Category:Photocatalytic CO2 conversion to CO]][[Category:Publication]]
 {{BaseTemplate}}
+===Abstract===
+====Summary====
+A photochemical reduction of CO<sub>2</sub> to CO was shown using the iron complexes {{#moleculelink: |link=VCSOHGDMTDAXCJ-UHFFFAOYSA-N|image=false|width=300|height=200}}, {{#moleculelink: |link=GNLSTNFUDXOKCD-UHFFFAOYSA-N|image=false|width=300|height=200}} and {{#moleculelink: |link=DJDQCCRAAYOAPK-UHFFFAOYSA-N|image=false|width=300|height=200}} as catalysts in combination with the organic photosensitizer {{#moleculelink:|link=PRWATGACIORDEL-UHFFFAOYSA-N|image=false|width=300|height=200}}. Turnover numbers (TONs) of 6320 and a selectivity of 99.4% for CO were reached in DMF/H<sub>2</sub>O with catalyst {{#moleculelink: |link=DJDQCCRAAYOAPK-UHFFFAOYSA-N|image=false|width=300|height=200}}. The experiments were conducted under visible-light irradiation (λ = 440 nm) using TEA as sacrificial electron donor (see section SEDs below).
+====Advances and special progress====
+One of the highest TONs for CO<sub>2</sub> reduction with an organic thermally activated delayed fluorescence (TADF) compound as a photosensitizer was reported herein.
+====Additional remarks====
+The addition of water was found to strongly promote the catalytic reaction.
+===Content of the published article in detail===
+The article contains results for the reduction of CO<sub>2</sub> to CO under visible-light catalysis using the iron complex {{#moleculelink: |link=DJDQCCRAAYOAPK-UHFFFAOYSA-N|image=false|width=300|height=200}} as a catalyst. The catalytic system performs best (referring to the TON of CO production) in DMF/H<sub>2</sub>O.
+====Catalyst====
+<chemform smiles="C1C=CN2~[Fe]34(~N5C=CC=CC=5C5N~3=C(C=C(C3C=CC([*])=CC=3)C=5)C3C=CC=CN=3~4)3~N4=CC=CC=C4C4C=C(C5C=CC([*])=CC=5)C=C(N=4~3)C=2C=1" inchi="" inchikey="" height="200px" width="300px" float="none" r1="H,Cl,NMe2">
+  -INDIGO-05142416252D
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+M  V30 5 C 5.63485 -5.15502 0.0 0
+M  V30 6 C 6.50382 -5.65003 0.0 0
+M  V30 7 C 8.23141 -3.64999 0.0 0
+M  V30 8 C 9.09513 -2.15069 0.0 0
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+M  V30 15 C 11.6996 -3.64164 0.0 0
+M  V30 16 C 12.5641 -5.14163 0.0 0
+M  V30 17 N 10.8338 -5.14728 0.0 0
+M  V30 18 C 11.7032 -5.64171 0.0 0
+M  V30 19 Fe 9.125 -5.95 0.0 0
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+M  V30 30 C 8.30733 -9.15464 0.0 0
+M  V30 31 C 9.17663 -9.64907 0.0 0
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+M  V30 36 C 11.7735 -8.14977 0.0 0
+M  V30 37 C 12.6364 -7.64414 0.0 0
+M  V30 38 C 9.09493 -1.15069 0.0 0
+M  V30 39 C 9.18116 -10.6491 0.0 0
+M  V30 40 C 10.0477 -12.1467 0.0 0
+M  V30 41 C 10.048 -11.1491 0.0 0
+M  V30 42 C 9.18123 -12.6478 0.0 0
+M  V30 43 C 8.31119 -11.1521 0.0 0
+M  V30 44 C 8.31765 -12.1522 0.0 0
+M  V30 45 C 8.22835 0.346977 0.0 0
+M  V30 46 C 8.22809 -0.650659 0.0 0
+M  V30 47 C 9.09486 0.848029 0.0 0
+M  V30 48 C 9.9649 -0.647629 0.0 0
+M  V30 49 C 9.95844 0.352425 0.0 0
+M  V30 50 R# 9.09323 1.84803 0.0 0 RGROUPS=(1 1)
+M  V30 51 R# 9.18286 -13.6478 0.0 0 RGROUPS=(1 1)
+M  V30 END ATOM
+M  V30 BEGIN BOND
+M  V30 1 2 3 1
+M  V30 2 2 4 2
+M  V30 3 1 1 5
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+M  V30 42 1 31 39
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+M  V30 52 1 45 46
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+M  V30 54 1 49 47
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+M  V30 57 8 4 19
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+M  V30 END BOND
+M  V30 END CTAB
+M  END
+</chemform>
+====Photosensitizer====
+<chemform smiles="" inchi="" inchikey="PRWATGACIORDEL-UHFFFAOYSA-N" height="200px" width="300px" float="none"></chemform>
+====Investigation====
+{{#experimentlist:|form=Photocatalytic_CO2_conversion_experiments|name=photocatalytic CO2 conversion|importFile=}}
+====Sacrificial electron donor====
+In this study, the experiments were done with the sacrificial electron donor TEA ({{#moleculelink:|link=ZMANZCXQSJIPKH-UHFFFAOYSA-N|image=false|width=300|height=200}}).
+====Additives====
+In this study, no additives were tested.

Water-Assisted Highly Efficient Photocatalytic Reduction of CO2 to CO with Noble Metal-Free Bis(terpyridine)iron(II) Complexes and an Organic Photosensitizer: Difference between revisions

Latest revision as of 08:55, 15 May 2024

Contents

Abstract[edit | edit source]

Summary[edit | edit source]

Advances and special progress[edit | edit source]

Additional remarks[edit | edit source]

Content of the published article in detail[edit | edit source]

Catalyst[edit | edit source]

Photosensitizer[edit | edit source]

Investigation[edit | edit source]

Sacrificial electron donor[edit | edit source]

Additives[edit | edit source]

Investigations

Topics

Water-Assisted Highly Efficient Photocatalytic Reduction of CO2 to CO with Noble Metal-Free Bis(terpyridine)iron(II) Complexes and an Organic Photosensitizer: Difference between revisions

Latest revision as of 08:55, 15 May 2024

Abstract[edit | edit source]

Summary[edit | edit source]

Advances and special progress[edit | edit source]

Additional remarks[edit | edit source]

Content of the published article in detail[edit | edit source]

Catalyst[edit | edit source]

Photosensitizer[edit | edit source]

Investigation[edit | edit source]

Sacrificial electron donor[edit | edit source]

Additives[edit | edit source]

Investigations

Current site

Topics